JEE Advance - Chemistry (2017 - Paper 1 Offline)

1
The color of the $${X_2}$$ molecules of group $$17$$ elements changes gradually from yellow to violet down the group. This is due to
Answer
C
D
2
For the synthesis of benzoic acid, the only CORRECT combination is
Answer
(A)
(II) (i) (S)
3
The correct statement(s) about the oxoacids, $$HCl{O_4}$$ and $$HClO$$ is (are)
Answer
A
B
D
4
An ideal gas is expanded from $$\left( {{p_1},{V_1},{T_1}} \right)$$ to $$\left( {{p_2},{V_2},{T_2}} \right)$$ under different conditions. The correct statement(s) among the following is (are)
Answer
A
B
C
5
Addition of excess aqueous ammonia to a pink colored aqueous solution of $$MC{l_2},6{H_2}O\left( X \right)$$ and $$N{H_4}Cl$$ gives an octahedral complex $$Y$$ in the presence of air. In aqueous solution, complex $$Y$$ behaves as $$1:3$$ electrolyte. The reaction of $$X$$ with excess $$HCl$$ at room temperature results in the formation of a blue colored complex $$Z.$$ The calculated spin only magnetic moment of $$X$$ and $$Z$$ is $$3.87$$ $$B.M.,$$ whereas it is zero for complex $$Y.$$ Among the following options, which statement(s) is (are) correct?
Answer
B
C
D
6
The conductance of a $$0.0015$$ $$M$$ aqueous solution of a weak monobasic acid was determined by using a conductivity cell consisting of platinized $$Pt$$ electrodes. The distance between the electrodes is $$120$$ $$cm$$ with an area of cross section of $$1$$ $$c{m^2}.$$ The conductance of this solution was found to be $$5 \times {10^{ - 7}}S.$$ The $$pH$$ of the solution is $$4.$$ The value of limiting molar conductivity $$\left( {\Lambda _m^o} \right)$$ of this weak monobasic acid in aqueous solution is $$Z \times {10^2}S$$ $$c{m^2}$$ $$mo{l^{ - 1}}.$$ The value of $$Z$$ is
Answer
6
7
A crystalline solid of a pure substance has a face-centered cubic structure with a cell edge of $$400$$ $$pm.$$ If the density of the substance in the crystal is $$8$$ $$g\,c{m^{ - 3}},$$ then the number of atoms present in $$256$$ $$g$$ of the crystal is $$N \times {10^{24}}.$$ The value of $$N$$ is
Answer
2
8
The sum of the number of lone pairs of electrons on each central atom in the following species is

$${[TeB{r_6}]^{2 - }},{\left[ {Br{F_2}} \right]^ + },SNF_3,$$ and $${\left[ {Xe{F_3}} \right]^ - }$$

(Atomic numbers: $$N = 7,F = 9,$$ $$S = 16,Br = 35,$$ $$Te = 52,Xe = 54$$)
Answer
6
9
Among $${H_2},H{e_2}^ + ,L{i_2},$$ $$B{e_2},{B_2},{C_2},{N_2},O_2^ - $$ and $${F_2},$$ the number of diamagnetic species is

(Atomic numbers : $$H = 1,He = 2,$$ $$Li = 3,Be = 4,$$ $$B = 5,C = 6,$$ $$N = 7,$$ $$O = 8,F = 9$$)
Answer
6
10
For the synthesis of benzoic acid, the only CORRECT combination is
Answer
(A)
(II) (i) (S)
11
The IUPAC name(s) of the following compound is (are)

JEE Advanced 2017 Paper 1 Offline Chemistry - Basics of Organic Chemistry Question 38 English
Answer
A
B
12
The correct statements(s) for the following addition reactions is (are)

JEE Advanced 2017 Paper 1 Offline Chemistry - Basics of Organic Chemistry Question 37 English
Answer
B
D
13
The IUPAC name(s) of the following compound is (are)

JEE Advanced 2017 Paper 1 Offline Chemistry - Basics of Organic Chemistry Question 38 English
Answer
A
B
14
The only CORRECT combination in which the reaction proceeds through radical mechanism is :
Answer
(D)
(I) (ii) (R)
15
The only CORRECT combination that gives two different carboxylic acids is :
Answer
(C)
(III) (iii) (P)
16
For $$H{e^ + }$$ ion, the only INCORRECT combination is
Answer
(C)
(I) (iii) (R)
17
For hydrogen atom, the only CORRECT combination is :
Answer
(A)
(I) (i) (S)
18
For the given orbital in Column 1, the only CORRECT combination for any hydrogen-like species is :
Answer
(C)
(II) (ii) (P)