JEE Advance - Chemistry (2017 - Paper 1 Offline - No. 2)

Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively.

Column 1 Column 2 Column 3
(I) Toluene (i) NaOH/Br2 (P) Condensation
(II) Acetophenone (ii) Br2/hv (Q) Carboxylation
(III) Benzaldehyde (iii) (CH3CO)2O/
CH3COOK
(R) Substitution
(IV) Phenol (iv) NaOH/CO2 (S) Haloform
Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively.

Column 1 Column 2 Column 3
(I) Toluene (i) NaOH/Br2 (P) Condensation
(II) Acetophenone (ii) Br2/hv (Q) Carboxylation
(III) Benzaldehyde (iii) (CH3CO)2O/
CH3COOK
(R) Substitution
(IV) Phenol (iv) NaOH/CO2 (S) Haloform
Columns 1, 2 and 3 contain starting materials, reaction conditions, and type of reactions, respectively.

Column 1 Column 2 Column 3
(I) Toluene (i) NaOH/Br2 (P) Condensation
(II) Acetophenone (ii) Br2/hv (Q) Carboxylation
(III) Benzaldehyde (iii) (CH3CO)2O/
CH3COOK
(R) Substitution
(IV) Phenol (iv) NaOH/CO2 (S) Haloform
For the synthesis of benzoic acid, the only CORRECT combination is
(II) (i) (S)
(IV) (ii) (P)
(I) (iv) (Q)
(III) (iv) (R)

Explanation

The synthesis involving benzoic acid is

JEE Advanced 2017 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 63 English Explanation

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