JEE Advance - Chemistry (2022 - Paper 2 Online)

1

Concentration of $\mathrm{H}_{2} \mathrm{SO}_{4}$ and $\mathrm{Na}_{2} \mathrm{SO}_{4}$ in a solution is $1 \mathrm{M}$ and $1.8 \times 10^{-2} \mathrm{M}$, respectively. Molar solubility of $\mathrm{PbSO}_{4}$ in the same solution is $\mathrm{X} \times 10^{-\mathrm{Y}} \mathrm{M}$ (expressed in scientific notation). The value of $Y$ is ________.

[Given: Solubility product of $\mathrm{PbSO}_{4}\left(K_{s p}\right)=1.6 \times 10^{-8}$. For $\mathrm{H}_{2} \mathrm{SO}_{4}, K_{a l}$ is very large and $\left.K_{a 2}=1.2 \times 10^{-2}\right]$

Answer
6
2
An aqueous solution is prepared by dissolving $0.1 \mathrm{~mol}$ of an ionic salt in $1.8 \mathrm{~kg}$ of water at $35^{\circ} \mathrm{C}$. The salt remains $90 \%$ dissociated in the solution. The vapour pressure of the solution is $59.724 \mathrm{~mm}$ of Hg. Vapor pressure of water at $35{ }^{\circ} \mathrm{C}$ is $60.000 \mathrm{~mm}$ of $\mathrm{Hg}$. The number of ions present per formula unit of the ionic salt is _________.
Answer
5
3
Consider the strong electrolytes $Z_{m} X_{n}, U_{m} Y_{p}$ and $V_{m} X_{n}$. Limiting molar conductivity ( $\Lambda^{0}$ ) of $\mathrm{U}_{\mathrm{m}} \mathrm{Y}_{\mathrm{p}}$ and $\mathrm{V}_{\mathrm{m}} \mathrm{X}_{\mathrm{n}}$ are 250 and $440 \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}$, respectively. The value of $(\mathrm{m}+\mathrm{n}+\mathrm{p})$ is

Given:

Ion $\mathrm{Z}^{\mathrm{n}+}$ $\mathrm{U}^{\mathrm{p}+}$ $\mathrm{V}^{\mathrm{n}+}$ $\mathrm{X}^{\mathrm{m}-}$ $\mathrm{Y}^{\mathrm{m}-}$
$\lambda^{0}\left(\mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}\right)$ $50.0$ $25.0$ $100.0$ $80.0$ $100.0$

$\lambda^{0}$ is the limiting molar conductivity of ions

The plot of molar conductivity ( $\Lambda$ ) of $\mathrm{Z}_{\mathrm{m}} \mathrm{X}_{\mathrm{n}} v s\, \mathrm{c}^{1 / 2}$ is given below.

JEE Advanced 2022 Paper 2 Online Chemistry - Electrochemistry Question 6 English
Answer
7
4
The reaction of $\mathrm{Xe}$ and $\mathrm{O}_{2}{F}_{2}$ gives a $\mathrm{Xe}$ compound $\mathbf{P}$. The number of moles of $\mathrm{HF}$ produced by the complete hydrolysis of $1 \mathrm{~mol}$ of $\mathbf{P}$ is __________.
Answer
4
5
Thermal decomposition of $\mathrm{AgNO}_{3}$ produces two paramagnetic gases. The total number of electrons present in the antibonding molecular orbitals of the gas that has the higher number of unpaired electrons is ____________.
Answer
6
6
The number of isomeric tetraenes (NOT containing $s p$-hybridized carbon atoms) that can be formed from the following reaction sequence is ___________.

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 5 English
Answer
2
7
The number of $-\mathrm{CH}_{2}-$ (methylene) groups in the product formed from the following reaction sequence is _________.

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 4 English
Answer
0
8
The total number of chiral molecules formed from one molecule of $\mathbf{P}$ on complete ozonolysis $\left(\mathrm{O}_{3}, \mathrm{Zn} / \mathrm{H}_{2} \mathrm{O}\right)$ is _________.

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 3 English
Answer
2
9
To check the principle of multiple proportions, a series of pure binary compounds $\left(\mathrm{P}_{\mathrm{m}} \mathrm{Q}_{\mathrm{n}}\right)$ were analyzed and their composition is tabulated below. The correct option(s) is(are)

Compound Weight % of $\mathrm{P}$ Weight % of $\mathrm{Q}$
1 50 50
2 44.4 55.6
3 40 60
Answer
B
C
10
The correct option(s) about entropy (S) is(are)

$[\mathrm{R}=$ gas constant, $\mathrm{F}=$ Faraday constant, $\mathrm{T}=$ Temperature $]$
Answer
B
C
D
11
The compound(s) which react(s) with $\mathrm{NH}_{3}$ to give boron nitride (BN) is(are)
Answer
A
B
C
12
The correct option(s) related to the extraction of iron from its ore in the blast furnace operating in the temperature range $900-1500 \mathrm{~K}$ is(are)
Answer
A
B
C
13
Considering the following reaction sequence, the correct statement(s) is(are)

JEE Advanced 2022 Paper 2 Online Chemistry - Hydrocarbons Question 2 English
Answer
A
C
14
Among the following, the correct statement(s) about polymers is(are)
Answer
B
C
15
Atom $\mathrm{X}$ occupies the fcc lattice sites as well as alternate tetrahedral voids of the same lattice. The packing efficiency (in %) of the resultant solid is closest to
Answer
(B)
35
16
The reaction of $\mathrm{HClO}_{3}$ with $\mathrm{HCl}$ gives a paramagnetic gas, which upon reaction with $\mathrm{O}_{3}$ produces
Answer
(C)
$\mathrm{Cl}_{2} \mathrm{O}_{6}$
17
The reaction of $\mathrm{Pb}\left(\mathrm{NO}_{3}\right)_{2}$ and $\mathrm{NaCl}$ in water produces a precipitate that dissolves upon the addition of $\mathrm{HCl}$ of appropriate concentration. The dissolution of the precipitate is due to the formation of
Answer
(C)
$\left[\mathrm{PbCl}_{4}\right]^{2-}$
18
Treatment of D-glucose with aqueous $\mathrm{NaOH}$ results in a mixture of monosaccharides, which are
Answer
(C)
JEE Advanced 2022 Paper 2 Online Chemistry - Biomolecules Question 7 English Option 3