JEE Advance - Chemistry (2013 - Paper 2 Offline)

1
The carbon–based reduction method is NOT used for the extraction of
Answer
C
D
2
In the nuclear transmutation

9Be4 + X $$\to$$ 8Be4 + Y

(X, Y) is (are) :
Answer
A
B
3
The standard reduction potential data at 25oC is given below:
Eo (Fe3+ , Fe2+) = +0.77V;
Eo (Fe2+ , Fe) = -0.44V;
Eo (Cu2+ , Cu) = +0.34V;
Eo (Cu+ , Cu) = +0.52V;
Eo [O2(g) + 4H+ + 4e- $$\to$$ 2H2O] = +1.23V;
Eo [O2(g) + 2H2O + 4e- $$\to$$ 4OH-] = +0.40 V
Eo (Cr3+ , Cr) = -0.74V;
Eo (Cr2+ , Cr) = -0.91V;

Match Eo of the redox pair in List – I with the values given in List – II and select the correct answer using the code given below the lists:

List - I
P. Eo (Fe3+ , Fe)
Q. Eo (4H2O $$\leftrightharpoons$$ 4H+ + 4OH-)
R. Eo (Cu2+ + Cu $$\to$$ 2Cu+)
S. Eo (Cr3+, Cr2+)

List - II
1. -0.18 V
2. -0.4 V
3. -0.04 V
4. -0.83 V
Answer
(D)
P - 3; Q - 4; R - 1; S - 2
4
An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List – I. The variation in conductivity of these reactions in List – II. Match List – I with List – II and select the correct answer using the code given below the lists:

List - I
P. $$\mathop {(C{}_2{H_5}){}_3N}\limits_X $$ + $$\mathop {C{H_3}COOH}\limits_Y $$
Q. $$\mathop {KI(0.1M)}\limits_X $$ + $$\mathop {AgN{O_3}(0.01M)}\limits_Y $$
R. $$\mathop {C{H_3}COOH}\limits_X $$ + $$\mathop {KOH}\limits_Y $$
S. $$\mathop {NaOH}\limits_X $$ + $$\mathop {HI}\limits_Y $$

List - II
1. Conductivity decreases then increases
2. Conductivity decreases then does not change much
3. Conductivity increases then does not change much
4. Conductivity does not change much then increases
Answer
(A)
P - 3; Q - 4; R - 2; S - 1
5
The thermal dissociation equilibrium of CaCO3(s) is studied under different conditions

CaCO3(s) $$\leftrightharpoons$$ CaO(s) + CO2(g).

For this equilibrium, the correct statement(s) is (are)
Answer
A
B
D
6
The Ksp of Ag2CrO4 is 1.1 $$\times$$ 10-12 at 298 K. The solubility (in mol/L) of Ag2CrO4 in a 0.1 M AgNO3 solution is
Answer
(B)
1.1 $$\times$$ 10-10
7

In the following reaction, the product/products formed is/are

JEE Advanced 2013 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 13 English

Answer
B
D
8

The major product(s) of the following reaction is(are)

JEE Advanced 2013 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 12 English

Answer
(B)
Q
9

After completion of the reactions (I and II), the organic compound(s) in the reaction mixtures is(are)

JEE Advanced 2013 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 38 English

Answer
(C)
Reaction I : T, U, acetone and Reaction II : P
10
The correct statement(s) about O3 is(are)
Answer
A
C
D
11
The precipitate P contains
Answer
(A)
Pb2+
12
The coloured solution S contains
Answer
(D)
$$N{a_2}Cr{O_4}$$
13
Compounds formed from P and Q are, respectively,
Answer
(B)
Optically inactive S and optically inactive pair (T, U).
14

In the following reaction sequences V and W are, respectively,

JEE Advanced 2013 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 37 English

Answer
(A)
JEE Advanced 2013 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 37 English Option 1
15
The succeeding operations that enable this transformation of states are
Answer
(C)
Heating, cooling, cooling, heating.
16
The pair of isochoric processes among the transformation of states is
Answer
(B)
L to M and N to K
17
P and Q, respectively, are the sodium salts of
Answer
(A)
Hypochlorous and chloric acids.
18
R, S and T respectively, are
Answer
(A)
SO2Cl2, PCl5 and H3PO4
19

The unbalanced chemical reactions given in List I show missing reagent or condition (?) which are provided in List II. Match List I with List II and select the correct answer using the code given below the lists :

List I List II
P. $$Pb{O_2} + {H_2}S{O_4}\buildrel ? \over
\longrightarrow PbS{O_4} + {O_2} + Other\,products$$
1. NO
Q. $$N{a_2}{S_2}{O_3} + {H_2}O\buildrel ? \over
\longrightarrow NaHS{O_4} + Other\,products$$
2. $${I_2}$$
R. $${N_2}{H_4}\buildrel ? \over
\longrightarrow {N_2} + Other\,products$$
3. Warm
S. $$Xe{F_2}\buildrel ? \over
\longrightarrow Xe + Other\,products$$
4. $$C{l_2}$$

Answer
(D)
P-3, Q-4, R-2, S-1
20

Match the chemical conversions in List I with the appropriate reagents in List II and select the correct answer using the code given below the lists :

JEE Advanced 2013 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 14 English

Answer
(A)
P-2, Q-3, R-1, S-4