The successive 5 ionisation energies of an element are $800,2427,3658,25024$ and $32824 \mathrm{~kJ} / \mathrm{mol}$, respectively. By using the above values predict the group in which the above element is present :

Match List - I with List - II.

	List - I (Transition metal ion)		List - II (Spin only magnetic moment (B.M.))
(A)	$\mathrm{Ti}^{3+}$	(I)	3.87
(B)	$\mathrm{V}^{2+}$	(II)	0.00
(C)	$\mathrm{Ni}^{2+}$	(III)	1.73
(D)	$\mathrm{Sc}^{3+}$	(IV)	2.84

Choose the correct answer from the options given below :

$$ \begin{aligned} &\text { Find the compound ' } \mathrm{A} \text { ' from the following reaction sequences. }\\ &\mathrm{A} \xrightarrow{\text { aqua-regia }} \mathrm{B} \xrightarrow[\text { (2) } \mathrm{AcOH}]{\text { (1) } \mathrm{KNO}_2 \mid \mathrm{NH}_4 \mathrm{OH}} \text { yellow ppt } \end{aligned} $$

$$\begin{aligned} & \mathrm{S}(\mathrm{~g})+\frac{3}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{SO}_3(\mathrm{~g})+2 x \mathrm{kcal} \\ & \mathrm{SO}_2(\mathrm{~g})+\frac{1}{2} \mathrm{O}_2(\mathrm{~g}) \rightarrow \mathrm{SO}_3(\mathrm{~g})+y \mathrm{kcal} \end{aligned}$$

The heat of formation of $\mathrm{SO}_2(\mathrm{~g})$ is given by :

The structure of the major product formed in the following reaction is :

The elemental composition of a compound is $54.2 \% \mathrm{C}, 9.2 \% \mathrm{H}$ and $36.6 \% \mathrm{O}$. If the molar mass of the compound is $132 \mathrm{~g} \mathrm{~mol}^{-1}$, the molecular formula of the compound is : [Given : The relative atomic mass of $\mathrm{C}: \mathrm{H}: \mathrm{O}=12: 1: 16$ ]

Based on the data given below :

$$\begin{array}{ll} \mathrm{E}_{\mathrm{Cr}_2 \mathrm{O}_7^{2-} / \mathrm{Cr}^{3+}}^{\circ}=1.33 \mathrm{~V} & \mathrm{E}_{\mathrm{Cl}_2 / \mathrm{Cl}^{(-)}}^{\circ}=1.36 \mathrm{~V} \\ \mathrm{E}_{\mathrm{MnO}_4^{-} / \mathrm{Mn}^{2+}}^0=1.51 \mathrm{~V} & \mathrm{E}_{\mathrm{Cr}^{3+} / \mathrm{Cr}}^{\circ}=-0.74 \mathrm{~V} \end{array}$$

the strongest reducing agent is :

For reaction

The correct order of set of reagents for the above conversion is :

Given below are two statements :

Statement (I) : The first ionization energy of Pb is greater than that of Sn .

Statement (II) : The first ionization energy of Ge is greater than that of Si .

In the light of the above statements, choose the correct answer from the options given below :

Match List - I with List - II.

	List - I		List - II
(A)	Adenine	(I)
(B)	Cytosine	(II)
(C)	Thymine	(III)
(D)	Uracil	(IV)

Choose the correct answer from the options given below :

Which of the following mixing of 1 M base and 1 M acid leads to the largest increase in temperature?

In the given structure, number of sp and $\mathrm{sp}^2$ hybridized carbon atoms present respectively are :

The conditions and consequence that favours the $t_{2 \mathrm{~g}}{ }^3 \mathrm{e}_{\mathrm{g}}{ }^1$ configuration in a metal complex are :

For the reaction,

$$\mathrm{H}_2(\mathrm{~g})+\mathrm{I}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{HI}(\mathrm{~g})$$

Attainment of equilibrium is predicted correctly by :

Given below are two statements :

Statement (I) : is valid for first order reaction.

Statement (II) : is valid for first order reaction.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements :

Statement (I) : Experimentally determined oxygen-oxygen bond lengths in the $\mathrm{O}_3$ are found to be same and the bond length is greater than that of a $\mathrm{O}=\mathrm{O}$ (double bond) but less than that of a single $(\mathrm{O}-\mathrm{O})$ bond.

Statement (II) : The strong lone pair-lone pair repulsion between oxygen atoms is solely responsible for the fact that the bond length in ozone is smaller than that of a double bond $(\mathrm{O}=\mathrm{O})$ but more than that of a single bond $(\mathrm{O}-\mathrm{O})$.

In the light of the above statements, choose the correct answer from the options given below :

Match List - I with List - II.

	List - I		List - II
(A)		(I)	Etard reaction
(B)		(II)	Gatterman-Koch reaction
(C)		(III)	Rosenmund reduction
(D)		(IV)	Stephen reaction

Choose the correct answer from the options given below :

When Ethane-1,2-diamine is added progressively to an aqueous solution of Nickel (II) chloride, the sequence of colour change observed will be:

For hydrogen atom, the orbital/s with lowest energy is/are :

(A) $\mathrm{4 s}$

(B) $3 \mathrm{p}_x$

(C) $3 \mathrm{~d}_{x^2-y^2}$

(D) $3 \mathrm{~d}_{z^2}$

(E) $4 \mathrm{p}_z$

Choose the correct answer from the options given below :

Identify correct statement/s :

(A) $-\mathrm{OCH}_3$ and $-\mathrm{NHCOCH}_3$ are activating group.

(B) $\quad-\mathrm{CN}$ and -OH are meta directing group.

(C) -CN and $-\mathrm{SO}_3 \mathrm{H}$ are meta directing group.

(D) Activating groups act as ortho - and para directing groups.

(E) Halides are activating groups.

Choose the correct answer from the options given below :

Consider a complex reaction taking place in three steps with rate constants $\mathrm{k}_1, \mathrm{k}_2$ and $\mathrm{k}_3$ respectively. The overall rate constant $k$ is given by the expression $k=\sqrt{\frac{k_1 k_3}{k_2}}$. If the activation energies of the three steps are 60, 30 and $10 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively, then the overall energy of activation in $\mathrm{kJ} \mathrm{mol}^{-1}$ is _________ . (Nearest integer)

The hydrocarbon $(\mathrm{X})$ with molar mass $80 \mathrm{~g} \mathrm{~mol}^{-1}$ and $90 \%$ carbon has _______ degree of unsaturation.

In Carius method of estimation of halogen, 0.25 g of an organic compound gave 0.15 g of silver bromide ( AgBr ). The percentage of Bromine in the organic compound is ________ $\times 10^{-1} \%$ (Nearest integer).

(Given : Molar mass of Ag is 108 and Br is $80 \mathrm{~g} \mathrm{~mol}^{-1}$ )

The observed and normal molar masses of compound $\mathrm{MX}_2$ are 65.6 and 164 respectively. The percent degree of ionisation of $\mathrm{MX}_2$ is __________%. (Nearest integer)

The possible number of stereoisomers for 5-phenylpent-4-en-2-ol is ________.