JEE MAIN - Chemistry (2025 - 24th January Evening Shift - No. 11)

Which of the following mixing of 1 M base and 1 M acid leads to the largest increase in temperature?
50 mL HCl and 20 mL NaOH
30 mL HCl and 30 mL NaOH
$45 \mathrm{~mL} \mathrm{~CH}_3 \mathrm{COOH}$ and 25 mL NaOH
$30 \mathrm{~mL} \mathrm{~CH}_3 \mathrm{COOH}$ and 30 mL NaOH

Explanation

Higher the number of milli moles of acid or base reacted higher will be temperature rise.

Option (4) $n_{\text {acid }}$ or $n_{\text {base }}$ reacted $=30 \mathrm{~m} \mathrm{~mol}$

Option (2) $n_{\text {acid }}$ or $n_{\text {base }}$ reacted $=30 \mathrm{~m} \mathrm{~mol}$

but less energy will be released by neutralisation

reaction of weak acid hence option (2) can not be correct.

Option (3) $\Rightarrow 20 \mathrm{~m} \mathrm{~mol}$

Option (4) $\Rightarrow 25 \mathrm{~m} \mathrm{~mol}$

Hence Correct Option (1)

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