Match the LIST-I with LIST-II

Choose the correct answer from the options given below:

Match the LIST-I with LIST-II

Choose the correct answer from the options given below:

Correct statements for an element with atomic number 9 are:

A. There can be 5 electrons for which $m_s = +\frac{1}{2}$ and 4 electrons for which $m_s = -\frac{1}{2}$.

B. There is only one electron in $p_z$ orbital.

C. The last electron goes to orbital with $n = 2$ and $l = 1$.

D. The sum of angular nodes of all the atomic orbitals is 1.

Choose the correct answer from the options given below:

The freezing point depression of a 0.1 m aqueous solution of a monobasic weak acid HA is 0.20 °C. The dissociation constant for the acid is

Given: $K_f$(H₂O) = 1.8 K kg mol⁻¹, molality ≡ molarity

What is the correct IUPAC name of the compound?

'P' is

The number of species from the following that are involved in sp³d² hybridization is :

[Co(NH₃)₆]³⁺, SF₆, [CrF₆]³⁻, [CoF₆]³⁻, [Mn(CN)₆]³⁻, and [MnCl₆]³⁻

Given below are two statements:

Statement I: H₂Se is more acidic than H₂Te

Statement II: H₂Se has higher bond enthalpy for dissociation than H₂Te

In the light of the above statements, choose the correct answer from the options given below:

$\mathrm{A} \xrightarrow[\text { (i) } \mathrm{H}_3 \mathrm{O}^{+}]{\text {(i) } \mathrm{NaH}} \mathrm{B} \xrightarrow[\text { (ii) } \mathrm{H}_2 \mathrm{SO}_4, \Delta]{\text { (i) } \mathrm{EOH}} \mathrm{C}$

' A ' shows positive Lassaign's test for N and its molar mass is 121 .

' B ' gives effervescence with aq $\mathrm{NaHCO}_3$.

'C' gives fruity smell.

Identify $\mathrm{A}, \mathrm{B}$ and C from the following.

Given below are two statements:

Statement I: A homoleptic octahedral complex, formed using monodentate ligands, will not show stereoisomerism.

Statement II: cis- and trans- platin are heteroleptic complexes of Pd.

In the light of the above statements, choose the correct answer from the options given below:

Choose the correct set of reagents for the following conversion.

Which one of the following reactions will not lead to the desired ether formation in major proportion?

(iso- $\mathrm{Bu} \Rightarrow$ isobutyl, sec $-\mathrm{Bu} \Rightarrow$ sec-butyl, $\mathrm{nPr} \Rightarrow \mathrm{n}$-propyl, $$ { }^{\mathrm{t}} \mathrm{Bu} \Rightarrow \text { tert-butyl, } \mathrm{Et} \Rightarrow \text { ethyl) } $$

Match the LIST-I with LIST-II

Choose the correct answer from the options given below:

Choose the correct option for structures of $A$ and $B$, respectively

Consider the following half cell reaction

$$ \text{Cr}_2\text{O}_7^{2-} \, (\text{aq}) + 6\text{e}^- + 14\text{H}^+ \, (\text{aq}) \rightarrow 2\text{Cr}^{3+} \, (\text{aq}) + 7\text{H}_2\text{O} \, (\ell) $$

The reaction was conducted with the ratio of $$\frac{[\text{Cr}^{3+}]^2}{[\text{Cr}_2\text{O}_7^{2-}]} = 10^{-6}$$. The pH value at which the EMF of the half cell will become zero is __________.

(nearest integer value)

[Given: standard half cell reduction potential $$E^{\circ}_{\text{Cr}_2\text{O}_7^{2-}, \text{H}^+/\text{Cr}^{3+}} = 1.33\, \text{V}$$, $$\frac{2.303RT}{F} = 0.059\, \text{V}$$.]

The equilibrium constant for decomposition of $\text{H}_2\text{O(g)}$

$ \text{H}_2\text{O(g)} \rightleftharpoons \text{H}_2\text{(g)} + \frac{1}{2}\text{O}_2\text{(g)} \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $

is $8.0 \times 10^{-3}$ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($\alpha$) of water is _________ $\times 10^{-2}$ (nearest integer value).

[Assume $\alpha$ is negligible with respect to 1]

20 mL of sodium iodide solution gave 4.74 g silver iodide when treated with excess of silver nitrate solution. The molarity of the sodium iodide solution is _______ M. (Nearest Integer value)

(Given : Na = 23, I = 127, Ag = 108, N = 14, O = 16 g mol^-1)

Resonance in $\mathrm{X}_2 \mathrm{Y}$ can be represented as

The enthalpy of formation of $X_2Y$ $ \left(X = X(g) + \frac{1}{2} Y = Y(g) \rightarrow X_2Y(g) \right) $ is 80 kJ mol$^{-1}$. The magnitude of resonance energy of $X_2Y$ is __ kJ mol$^{-1}$ (nearest integer value).

Given: Bond energies of $X \equiv X$, $X = X$, $Y = Y$ and $X = Y$ are 940, 410, 500, and 602 kJ mol$^{-1}$ respectively.
valence $X$: 3, $Y$: 2