JEE MAIN - Chemistry (2024 - 27th January Evening Shift)

1
Identity the incorrect pair from the following :
Answer
(D)
Wacker process - $$\mathrm{Pt} \mathrm{Cl}_2$$
2

The order of relative stability of the contributing structure is :

JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Basics of Organic Chemistry Question 64 English

Choose the correct answer from the options given below :

Answer
(B)
I > II > III
3

Major product formed in the following reaction is a mixture of :

JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 24 English

Answer
(D)
JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 24 English Option 4
4

Given below are two statements :

Statement (I) : Oxygen being the first member of group 16 exhibits only -2 oxidation state.

Statement (II) : Down the group 16 stability of +4 oxidation state decreases and +6 oxidation state increases.

In the light of the above statements, choose the most appropriate answer from the options given below :

Answer
(B)
Both Statement I and Statement II are incorrect
5
The technique used for purification of steam volatile water immiscible substances is :
Answer
(D)
Steam distillation
6
Which structure of protein remains intact after coagulation of egg white on boiling?
Answer
(B)
Primary
7

Identify B formed in the reaction.

$$\mathrm{Cl}-\left(\mathrm{CH}_2\right)_4-\mathrm{Cl} \xrightarrow{\text { excess } \mathrm{NH}_3} \mathrm{~A} \xrightarrow{\mathrm{NaOH}} \mathrm{B}+\mathrm{H}_2 \mathrm{O}+\mathrm{NaCl}$$

Answer
(D)
$$\mathrm{H}_2 \mathrm{N}-\left(\mathrm{CH}_2\right)_4-\mathrm{NH}_2$$
8
Identify from the following species in which $$\mathrm{d}^2 \mathrm{sp}^3$$ hybridization is shown by central atom :
Answer
(A)
$$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$$
9
Phenolic group can be identified by a positive:
Answer
(B)
Phthalein dye test
10

Match List - I with List - II.

List - I
(Reaction)
List - II
(Reagent(s))
(A) JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 23 English 1 (I) $$\mathrm{Na_2Cr_2O_7,H_2SO_4}$$
(B) JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 23 English 2 (II) (i) $$\mathrm(NaOH)$$, (ii) $$\mathrm{CH_3Cl}$$
(C) JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 23 English 3 (III) (i) $$\mathrm{NaOH,CHCl_3}$$, (ii) $$\mathrm{NaOH}$$, (iii) $$\mathrm{HCl}$$
(D) JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 23 English 4 (IV) (i) $$\mathrm{NaOH}$$, (ii) $$\mathrm{CO_2}$$, (iii) $$\mathrm{HCl}$$

Choose the correct answer from the options given below :

Answer
(C)
$$\text { (A)-(IV), (B)-(III), (C)-(I), (D)-(II) }$$
11

Which among the following halide/s will not show $$\mathrm{S_N 1}$$ reaction:

(A) $$\mathrm{H}_2 \mathrm{C}=\mathrm{CH}-\mathrm{CH}_2 \mathrm{Cl}$$

(B) $$\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{Cl}$$

(C) JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Haloalkanes and Haloarenes Question 34 English 1

(D) JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Haloalkanes and Haloarenes Question 34 English 2

Choose the most appropriate answer from the options given below :

Answer
(C)
(B) only
12
Which of the following statements is not correct about rusting of iron?
Answer
(C)
Coating of iron surface by tin prevents rusting, even if the tin coating is peeling off.
13
Which of the following cannot function as an oxidising agent?
Answer
(C)
$$\mathrm{N}^{3-}$$
14

Given below are two statements :

Statement (I) : In the Lanthanoids, the formation $$\mathrm{Ce}^{+4}$$ is favoured by its noble gas configuration.

Statement (II) : $$\mathrm{Ce}^{+4}$$ is a strong oxidant reverting to the common +3 state.

In the light of the above statements, choose the most appropriate answer from the options given below :

Answer
(C)
Both Statement I and Statement II are true
15
Choose the correct option having all the elements with $$\mathrm{d}^{10}$$ electronic configuration from the following :
Answer
(B)
$${ }^{29} \mathrm{Cu},{ }^{30} \mathrm{Zn},{ }^{48} \mathrm{Cd},{ }^{47} \mathrm{Ag}$$
16
The incorrect statement regarding conformations of ethane is :
Answer
(C)
Eclipsed conformation is the most stable conformation.
17

The final product A, formed in the following reaction sequence is:

JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Hydrocarbons Question 31 English

Answer
(C)
$$\mathrm{Ph}-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{CH}_2-\mathrm{OH}$$
18
Bond line formula of HOCH(CN)$$_2$$ is :
Answer
(D)
JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Basics of Organic Chemistry Question 62 English Option 4
19
The quantity which changes with temperature is :
Answer
(B)
Molarity
20
The molecular formula of second homologue in the homologous series of mono carboxylic acids is
Answer
(A)
$$\mathrm{C}_2 \mathrm{H}_4 \mathrm{O}_2$$
21
1 mole of $$\mathrm{PbS}$$ is oxidised by "$$\mathrm{X}$$" moles of $$\mathrm{O}_3$$ to get "$$\mathrm{Y}$$" moles of $$\mathrm{O}_2$$. $$\mathrm{X}+\mathrm{Y}=$$ _________.
Answer
8
22

The Spin only magnetic moment value of square planar complex $$\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}\left(\mathrm{NH}_2 \mathrm{CH}_3\right)\right] \mathrm{Cl}$$ is _________ B.M. (Nearest integer)

(Given atomic number for $$\mathrm{Pt}=78$$)

Answer
0
23

Total number of compounds with Chiral carbon atoms from following is _________.

JEE Main 2024 (Online) 27th January Evening Shift Chemistry - Basics of Organic Chemistry Question 63 English

Answer
5
24
Time required for completion of $$99.9 \%$$ of a First order reaction is ________ times of half life $$\left(t_{1 / 2}\right)$$ of the reaction.
Answer
10
25

The hydrogen electrode is dipped in a solution of $$\mathrm{pH}=3$$ at $$25^{\circ} \mathrm{C}$$. The potential of the electrode will be _________ $$\times 10^{-2} \mathrm{~V}$$.

$$\left(\frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.059 \mathrm{~V}\right)$$

Answer
18
26
The number of non-polar molecules from the following is _________. $$\mathrm{HF}, \mathrm{H}_2 \mathrm{O}, \mathrm{SO}_2, \mathrm{H}_2, \mathrm{CO}_2, \mathrm{CH}_4, \mathrm{NH}_3, \mathrm{HCl}, \mathrm{CHCl}_3, \mathrm{BF}_3$$
Answer
4
27

$$9.3 \mathrm{~g}$$ of aniline is subjected to reaction with excess of acetic anhydride to prepare acetanilide. The mass of acetanilide produced if the reaction is $$100 \%$$ completed is _________ $$\times 10^{-1} \mathrm{~g}$$.

(Given molar mass in $$\mathrm{g} \mathrm{~mol}^{-1}$$

$$\begin{aligned} & \mathrm{N}: 14, \mathrm{O}: 16, \\ & \mathrm{C}: 12, \mathrm{H}: 1 \text { ) } \end{aligned}$$

Answer
135
28
Volume of $$3 \mathrm{M} \mathrm{~NaOH}$$ (formula weight $$40 \mathrm{~g} \mathrm{~mol}^{-1}$$ ) which can be prepared from $$84 \mathrm{~g}$$ of $$\mathrm{NaOH}$$ is __________ $$\times 10^{-1} \mathrm{dm}^3$$.
Answer
7
29
Total number of ions from the following with noble gas configuration is _________.

$$\mathrm{Sr}^{2+}(z=38), \mathrm{Cs}^{+}(z=55), \mathrm{La}^{2+}(z=57), \mathrm{Pb}^{2+}(z=82), \mathrm{Yb}^{2+}(z=70)$$ and $$\mathrm{Fe}^{2+}(z=26)$$
Answer
2
30
For a certain thermochemical reaction $$\mathrm{M} \rightarrow \mathrm{N}$$ at $$\mathrm{T}=400 \mathrm{~K}, \Delta \mathrm{H}^{\ominus}=77.2 \mathrm{~kJ} \mathrm{~mol}^{-1}, \Delta \mathrm{S}=122 \mathrm{~JK}^{-1}, \log$$ equilibrium constant $$(\log K)$$ is __________ $$\times 10^{-1}$$.
Answer
37