JEE Advance - Chemistry (2024 - Paper 2 Online)

1
According to Bohr's model, the highest kinetic energy is associated with the electron in the
Answer
(B)
first orbit of $\mathrm{He}^{+}$
2
In a metal deficient oxide sample, $\mathbf{M}_{\mathbf{x}} \mathbf{Y}_2 \mathbf{O}_4$ ( $\mathbf{M}$ and $\mathbf{Y}$ are metals), $\mathbf{M}$ is present in both +2 and +3 oxidation states and $\mathbf{Y}$ is in +3 oxidation state. If the fraction of $\mathbf{M}^{2+}$ ions present in $\mathbf{M}$ is $\frac{1}{3}$, the value of $\mathbf{X}$ is _______ .
Answer
(D)
0.75
3

In the following reaction sequence, the major product $\mathbf{Q}$ is

JEE Advanced 2024 Paper 2 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 9 English
Answer
(D)
JEE Advanced 2024 Paper 2 Online Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 9 English Option 4
4

The species formed on fluorination of phosphorus pentachloride in a polar organic solvent are

Answer
(B)
$\left[\mathrm{PCl}_4\right]^{+}\left[\mathrm{PCl}_4 \mathrm{~F}_2\right]^{-}$and $\left[\mathrm{PCl}_4\right]^{+}\left[\mathrm{PF}_6\right]^{-}$
5

An aqueous solution of hydrazine $\left(\mathrm{N}_2 \mathrm{H}_4\right)$ is electrochemically oxidized by $\mathrm{O}_2$, thereby releasing chemical energy in the form of electrical energy. One of the products generated from the electrochemical reaction is $\mathrm{N}_2(\mathrm{~g})$.

Choose the correct statement(s) about the above process

Answer
A
C
6

The option(s) with correct sequence of reagents for the conversion of $\mathbf{P}$ to $\mathbf{Q}$ is(are)

JEE Advanced 2024 Paper 2 Online Chemistry - Compounds Containing Nitrogen Question 4 English
Answer
C
D
7
The compound(s) having peroxide linkage is(are)
Answer
B
D
8
To form a complete monolayer of acetic acid on $1 \mathrm{~g}$ of charcoal, $100 \mathrm{~mL}$ of $0.5 \mathrm{M}$ acetic acid was used. Some of the acetic acid remained unadsorbed. To neutralize the unadsorbed acetic acid, 40 $\mathrm{mL}$ of $1 \mathrm{M} \mathrm{NaOH}$ solution was required. If each molecule of acetic acid occupies $\mathbf{P} \times 10^{-23} \mathrm{~m}^2$ surface area on charcoal, the value of $\mathbf{P}$ is _____.

[Use given data: Surface area of charcoal $=1.5 \times 10^2 \mathrm{~m}^2 \mathrm{~g}^{-1}$; Avogadro's number $\left(\mathrm{N}_{\mathrm{A}}\right)=6.0 \times 10^{23}$ $\left.\mathrm{mol}^{-1}\right]$
Answer
2500
9
Vessel-1 contains $\mathbf{w}_2 \mathrm{~g}$ of a non-volatile solute $\mathbf{X}$ dissolved in $\mathbf{w}_1 \mathrm{~g}$ of water. Vessel- 2 contains $\mathbf{w}_2 \mathrm{~g}$ of another non-volatile solute $\mathbf{Y}$ dissolved in $\mathbf{w}_1 \mathrm{~g}$ of water. Both the vessels are at the same temperature and pressure. The molar mass of $\mathbf{X}$ is $80 \%$ of that of $\mathbf{Y}$. The van't Hoff factor for $\mathbf{X}$ is 1.2 times of that of $\mathbf{Y}$ for their respective concentrations.

The elevation of boiling point for solution in Vessel-1 is ________ $\%$ of the solution in Vessel-2.
Answer
150
10

For a double strand DNA, one strand is given below:

JEE Advanced 2024 Paper 2 Online Chemistry - Biomolecules Question 1 English

The amount of energy required to split the double strand DNA into two single strands is _______ kcal $\operatorname{mol}^{-1}$.

[Given: Average energy per H-bond for A-T base pair $=1.0 ~\mathrm{kcal}~ \mathrm{mol}^{-1}$, G-C base pair $=1.5 ~\mathrm{kcal}$ $\mathrm{mol}^{-1}$, and A-U base pair $=1.25 ~\mathrm{kcal} ~\mathrm{mol}^{-1}$. Ignore electrostatic repulsion between the phosphate groups.]

Answer
41
11

A sample initially contains only U-238 isotope of uranium. With time, some of the U-238 radioactively decays into $\mathrm{Pb}-206$ while the rest of it remains undisintegrated.

When the age of the sample is $\mathbf{P} \times 10^8$ years, the ratio of mass of $\mathrm{Pb}-206$ to that of $\mathrm{U}-238$ in the sample is found to be 7. The value of $\mathbf{P}$ is _______.

[Given: Half-life of $\mathrm{U}-238$ is $4.5 \times 10^9$ years; $\log _e 2=0.693$ ]

Answer
143
Or +1 more
12
Among $\left[\mathrm{Co}(\mathrm{CN})_4\right]^{4-},\left[\mathrm{Co}(\mathrm{CO})_3(\mathrm{NO})\right], \mathrm{XeF}_4,\left[\mathrm{PCl}_4\right]^{+},\left[\mathrm{PdCl}_4\right]^{2-},\left[\mathrm{ICl}_4\right]^{-},\left[\mathrm{Cu}(\mathrm{CN})_4\right]^{3-}$ and $\mathrm{P}_4$ the total number of species with tetrahedral geometry is _______.
Answer
4
Or +1 more
13

An organic compound $\mathbf{P}$ having molecular formula $\mathrm{C}_6 \mathrm{H}_6 \mathrm{O}_3$ gives ferric chloride test and does not have intramolecular hydrogen bond. The compound $\mathbf{P}$ reacts with 3 equivalents of $\mathrm{NH}_2 \mathrm{OH}$ to produce oxime $\mathbf{Q}$. Treatment of $\mathbf{P}$ with excess methyl iodide in the presence of $\mathrm{KOH}$ produces compound $\mathbf{R}$ as the major product. Reaction of $\mathbf{R}$ with excess iso-butylmagnesium bromide followed by treatment with $\mathrm{H}_3 \mathrm{O}^{+}$gives compound $\mathbf{S}$ as the major product.

The total number of methyl $\left(-\mathrm{CH}_3\right)$ group(s) in compound $\mathbf{S}$ is ___.

Answer
2
Or +2 more
14
Sum of number of oxygen atoms in $\mathbf{S}$ and $\mathbf{T}$ is _______.
Answer
2
15
The molecular weight of $\mathbf{U}$ is ______ .
Answer
93018
16
The number of moles of potassium iodide required to produce two moles of $\mathbf{P}$ is _______.
Answer
2
17
The number of zinc ions present in the molecular formula of $\mathbf{Q}$ is _______.
Answer
3
Or +1 more