Given below are two statements :

Statement (I) : Neopentane forms only one monosubstituted derivative.

Statement (II) : Melting point of neopentane is higher than n-pentane.

In the light of the above statements, choose the most appropriate answer from the options given below :

Match List - I with List - II.

List - I (Reaction)		List - II (Name of reaction)
(A)		(I)	Lucas reaction
(B)	$$ \mathrm{ArN}_2^{+} \mathrm{X}^{-} \xrightarrow[\mathrm{HCl}]{\mathrm{Cu}} \mathrm{ArCl}+\mathrm{N}_2 \uparrow+\mathrm{CuX} $$	(II)	Finkelstein reaction
(C)	$$ \mathrm{C}_2 \mathrm{H}_5 \mathrm{Br}+\mathrm{NaI} \xrightarrow[\text { Acetone }]{\text { Dry }} \mathrm{C}_2 \mathrm{H}_5 \mathrm{I}+\mathrm{NaBr} $$	(III)	Fittig reaction
(D)	$$ \mathrm{CH}_3 \mathrm{C}(\mathrm{OH})\left(\mathrm{CH}_3\right) \mathrm{CH}_3 \xrightarrow[\mathrm{ZnCl}_2]{\mathrm{HCl}} \mathrm{CH}_3 \mathrm{C}(\mathrm{Cl})\left(\mathrm{CH}_3\right) \mathrm{CH}_3 $$	(IV)	Gatterman reaction

$$ \text { Choose the correct answer from the options given below : } $$

Electronic configuration of four elements A, B, C and D are given below :

(A) $1 s^2 2 s^2 2 p^3$

(B) $1 s^2 2 s^2 2 p^4$

(C) $1 s^2 2 s^2 2 p^5$

(D) $1 s^2 2 s^2 2 p^2$

Which of the following is the correct order of increasing electronegativity (Pauling's scale)?

A tetrapeptide, " $x$ " on complete hydrolysis produced glycine (Gly), alanine (Ala), valine (Val), leucine (Leu) in equimolar proportion each. The number of tetrapeptides (sequences) possible involving each of these amino acids is :

Which among the following molecules is (a) involved in $\mathrm{sp}^3 \mathrm{~d}$ hybridization, (b) has different bond lengths and (c) has lone pair of electrons on the central atom?

In 3,3-dimethylhex-1-en-4-yne, there are _________$\mathrm{sp}^3$,_________$\mathrm{sp}^2$ and_________ sp hybridised carbon atoms respectively.

In Dumas' method for estimation of nitrogen, 0.5 gram of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound (Aqueous tension at $300 \mathrm{~K}=15 \mathrm{~mm} \mathrm{Hg}$ ) is___________%.

Which of the following statements are true?

(A) The subsidiary quantum number $l$ describes the shape of the orbital occupied by the electron.

(B) is the boundary surface diagram of the $2 \mathrm{p}_x$ orbital.

(C) The + and - signs in the wave function of the $2 p_x$ orbital refer to charge.

(D) The wave function of $2 \mathrm{p}_x$ orbital is zero everywhere in the $x y$ plane.

Choose the correct answer from the options given below :

Arrange the following in order of magnitude of work done by the system/on the system at constant temperature.

(a) $\left|w_{\text {reversible }}\right|$ for expansion in infinite stages.

(b) $\left|w_{\text {irreversible }}\right|$ for expansion in single stage.

(c) $\left|\mathrm{w}_{\text {reversible }}\right|$ for compression in infinite stages.

(d) $\left|w_{\text {irreversible }}\right|$ for compression in single stage.

Choose the correct answer from the options given below :

When a concentrated solution of sulphanilic acid and 1-naphthylamine is treated with nitrous acid $(273 \mathrm{~K})$ and acidified with acetic acid, the mass $(\mathrm{g})$ of 0.1 mole of product formed is :

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{~N}: 14, \mathrm{O}: 16, \mathrm{~S}: 32$ )

Which of the following graphs correctly represents the variation of thermodynamic properties of Haber's process?

Reactant A converts to product D through the given mechanism (with the net evolution of heat):

A → B     slow;     ΔH = +ve

B → C     fast;     ΔH = -ve

C → D     fast;     ΔH = -ve

Which of the following represents the above reaction mechanism?

Formation of $\mathrm{Na}_4\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]$, a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of :

Consider the following reactions. From these reactions which reaction will give carboxylic acid as a major product ?

(A) $\quad \mathrm{R}-\mathrm{C} \equiv \mathrm{N} \xrightarrow[\text { mild condition }]{\text { (i) } \stackrel{+}{\mathrm{H}} / \mathrm{H}_2 \mathrm{O}}$

(B) $\quad \mathrm{R}-\mathrm{MgX} \xrightarrow[\text { (ii) } \mathrm{H}_3 \mathrm{O}^{+}]{\text {(i) } \mathrm{CO}_2}$

(C) $\mathrm{R}-\mathrm{C} \equiv \mathrm{N} \xrightarrow[\text { (ii) } \mathrm{H}_3 \mathrm{O}^{+}]{\text {(i) } \mathrm{SnCl}_2 / \mathrm{HCl}}$

(D) $\quad \mathrm{R} \cdot \mathrm{CH}_2 \cdot \mathrm{OH} \xrightarrow{\mathrm{PCC}}$

(E)

Choose the correct answer from the options given below :

The nature of oxide $\left(\mathrm{TeO}_2\right)$ and hydride $\left(\mathrm{TeH}_2\right)$ formed by Te , respectively are :

' $x$ ' g of NaCl is added to water in a beaker with a lid. The temperature of the system is raised from $1^{\circ} \mathrm{C}$ to $25^{\circ} \mathrm{C}$. Which out of the following plots, is best suited for the change in the molarity $(\mathrm{M})$ of the solution with respect to temperature ?

[Consider the solubility of NaCl remains unchanged over the temperature range]

The type of hybridization and the magnetic property of $\left[\mathrm{MnCl}_6\right]^{3-}$ are,

$$ \text { Match List - I with List - II. } $$

List - I (Purification technique)		List - II (Mixture of organic compounds)
(A)	$$ \text { Distillation (simple) } $$	(I)	Diesel + Petrol
(B)	$$ \text { Fractional distillation } $$	(II)	Aniline + Water
(C)	$$ \text { Distillation under reduced pressure } $$	(III)	Chloroform + Aniline
(D)	$$ \text { Steam distillation } $$	(IV)	Glycerol + Spent-lye

$$ \text { Choose the correct answer from the options given below : } $$

The d-orbital electronic configuration of the complex among $\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+},\left[\mathrm{CoF}_6\right]^{3-}$, $\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$ and $\left[\mathrm{Zn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$ that has the highest CFSE is :

Consider the following chemical equilibrium of the gas phase reaction at a constant temperature : $\mathrm{A}(\mathrm{g}) \rightleftharpoons \mathrm{B}(\mathrm{g})+\mathrm{C}(\mathrm{g})$

If $p$ being the total pressure, $K_p$ is the pressure equilibrium constant and $\alpha$ is the degree of dissociation, then which of the following is true at equilibrium?

For the reaction $\mathrm{A} \rightarrow \mathrm{B}$ the following graph was obtained. The time required (in seconds) for the concentration of A to reduce to $2.5 \mathrm{~g} \mathrm{~L}^{-1}$ (if the initial concentration of A was $50 \mathrm{~g} \mathrm{~L}^{-1}$ ) is $\qquad$ . (Nearest integer)

Given : $\log 2=0.3010$

When 1 g each of compounds AB and $\mathrm{AB}_2$ are dissolved in 15 g of water separately, they increased the boiling point of water by 2.7 K and 1.5 K respectively. The atomic mass of A (in $a m u$ ) is____________ $\times 10^{-1}$ (Nearest integer)

(Given : Molal boiling point elevation constant is $0.5 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$ )

The spin-only magnetic moment value of $\mathrm{M}^{\mathrm{n}+}$ ion formed among $\mathrm{Ni}, \mathrm{Zn}, \mathrm{Mn}$ and Cu that has the least enthalpy of atomisation is_________ . (in nearest integer) Here n is equal to the number of diamagnetic complexes among $\mathrm{K}_2\left[\mathrm{NiCl}_4\right],\left[\mathrm{Zn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_2$, $\mathrm{K}_3\left[\mathrm{Mn}(\mathrm{CN})_6\right]$ and $\left[\mathrm{Cu}\left(\mathrm{PPh}_3\right)_3 \mathrm{I}\right]$

$0.2 \%(\mathrm{w} / \mathrm{v})$ solution of NaOH is measured to have resistivity $870.0 \mathrm{~m} \Omega \mathrm{~m}$. The molar conductivity of the solution will be__________$\times 10^2 \mathrm{mS} \mathrm{dm}^2 \mathrm{~mol}^{-1}$. (Nearest integer)

Consider the above sequence of reactions. 151 g of 2-bromopentane is made to react. Yield of major product P is $80 \%$ whereas Q is $100 \%$.

Mass of product Q obtained is________ g.

(Given molar mass in $\mathrm{g} \mathrm{mol}^{-1} \mathrm{H}: 1, \mathrm{C}: 12, \mathrm{O}: 16, \mathrm{Br}: 80$ )