JEE MAIN - Chemistry (2025 - 2nd April Evening Shift - No. 16)

' $x$ ' g of NaCl is added to water in a beaker with a lid. The temperature of the system is raised from $1^{\circ} \mathrm{C}$ to $25^{\circ} \mathrm{C}$. Which out of the following plots, is best suited for the change in the molarity $(\mathrm{M})$ of the solution with respect to temperature ?

[Consider the solubility of NaCl remains unchanged over the temperature range]

JEE Main 2025 (Online) 2nd April Evening Shift Chemistry - Solutions Question 9 English Option 1
JEE Main 2025 (Online) 2nd April Evening Shift Chemistry - Solutions Question 9 English Option 2
JEE Main 2025 (Online) 2nd April Evening Shift Chemistry - Solutions Question 9 English Option 3
JEE Main 2025 (Online) 2nd April Evening Shift Chemistry - Solutions Question 9 English Option 4

Explanation

When $x$ grams of NaCl are added to water in a beaker and the temperature is increased from $1^{\circ} \mathrm{C}$ to $25^{\circ} \mathrm{C}$, the molarity of the solution changes due to the volumetric changes of water.

Temperature from $1^{\circ} \mathrm{C}$ to $4^{\circ} \mathrm{C}$:

Water is densest at $4^{\circ} \mathrm{C}$.

As the temperature increases from $1^{\circ} \mathrm{C}$ to $4^{\circ} \mathrm{C}$, the water volume decreases due to increased density.

This decrease in volume results in an increase in molarity because molarity is inversely proportional to the solution's volume.

Temperature from $4^{\circ} \mathrm{C}$ to $25^{\circ} \mathrm{C}$:

Beyond $4^{\circ} \mathrm{C}$, water expands with an increase in temperature.

Therefore, as temperature rises to $25^{\circ} \mathrm{C}$, the volume of the water increases.

The dilution leads to a decrease in molarity, since molarity is inversely proportional to volume.

Thus, the molarity first increases as temperature rises to $4^{\circ} \mathrm{C}$, but then decreases as it continues to $25^{\circ} \mathrm{C}$. The graphical representation of this relationship would exhibit an initial increase in molarity, followed by a decrease, correlating with changes in the volume of water due to temperature variations.

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