The number of ions from the following that are expected to behave as oxidising agent is :

$$\mathrm{Sn}^{4+}, \mathrm{Sn}^{2+}, \mathrm{Pb}^{2+}, \mathrm{Tl}^{3+}, \mathrm{Pb}^{4+}, \mathrm{Tl}^{+}$$

The correct arrangement for decreasing order of electrophilic substitution for above compounds is :

During the detection of acidic radical present in a salt, a student gets a pale yellow precipitate soluble with difficulty in $$\mathrm{NH}_4 \mathrm{OH}$$ solution when sodium carbonate extract was first acidified with dil. $$\mathrm{HNO}_3$$ and then $$\mathrm{AgNO}_3$$ solution was added. This indicates presence of :

Consider the given reaction, identify the major product P.

Match List I with List II.

	LIST I Reaction		LIST II Type of redox reaction
A.	$$ \mathrm{N}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{NO}_{(\mathrm{g})} $$	I.	Decomposition
B.	$$ 2 \mathrm{~Pb}\left(\mathrm{NO}_3\right)_{2(\mathrm{~s})} \rightarrow 2 \mathrm{PbO}_{(\mathrm{s})}+4 \mathrm{NO}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} $$	II.	Displacement
C.	$$ 2 \mathrm{Na}_{(\mathrm{s})}+2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} \rightarrow 2 \mathrm{NaOH}_{(\mathrm{aq} .)}+\mathrm{H}_{2(\mathrm{~g})} $$	III.	Disproportionation
D.	$$ 2 \mathrm{NO}_{2(\mathrm{~g})}+2^{-} \mathrm{OH}(\text { aq. }) \rightarrow \mathrm{NO}_{2(\mathrm{aq} .)}^{-}+\mathrm{NO}_{3(\text { aq. })}^{-}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{l})} $$	IV.	Combination

Choose the correct answer from the options given below :

Identify the product A in the following reaction.

The correct statement among the following, for a "chromatography" purification method is :

Consider the above chemical reaction. Product "A" is :

How can an electrochemical cell be converted into an electrolytic cell ?

Given below are two statements :

Statement I : $$\mathrm{PF}_5$$ and $$\mathrm{BrF}_5$$ both exhibit $$\mathrm{sp}^3 \mathrm{~d}$$ hybridisation.

Statement II : Both $$\mathrm{SF}_6$$ and $$[\mathrm{Co}(\mathrm{NH}_3)_6]^{3+}$$ exhibit $$\mathrm{sp}^3 \mathrm{~d}^2$$ hybridisation.

In the light of the above statements, choose the correct answer from the options given below :

Match List I with List II.

	LIST I Tetrahedral Complex		LIST II Electronic configuration
A.	$$ \mathrm{TiCl}_4 $$	I.	$$ \mathrm{e}^2, \mathrm{t}_2^0 $$
B.	$$ \left[\mathrm{FeO}_4\right]^{2-} $$	II.	$$ \mathrm{e^4, t_2^3} $$
C.	$$ \left[\mathrm{FeCl}_4\right]^{-} $$	III.	$$ \mathrm{e}^0, \mathrm{t}_2^0 $$
D.	$$ \left[\mathrm{CoCl}_4\right]^{2-} $$	IV.	$$ \mathrm{e}^2, \mathrm{t}_2^3 $$

Choose the correct answer from the options given below :

Molality $$(\mathrm{m})$$ of $$3 \mathrm{M}$$ aqueous solution of $$\mathrm{NaCl}$$ is : (Given : Density of solution $$=1.25 \mathrm{~g} \mathrm{~mL}^{-1}$$, Molar mass in $$\mathrm{g} \mathrm{~mol}^{-1}: \mathrm{Na}-23, \mathrm{Cl}-35.5$$)

Evaluate the following statements related to group 14 elements for their correctness.

(A) Covalent radius decreases down the group from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ in a regular manner.

(B) Electronegativity decreases from $$\mathrm{C}$$ to $$\mathrm{Pb}$$ down the group gradually.

(C) Maximum covalance of $$\mathrm{C}$$ is 4 whereas other elements can expand their covalance due to presence of d orbitals.

(D) Heavier elements do not form $$\mathrm{p} \pi-\mathrm{p} \pi$$ bonds.

(E) Carbon can exhibit negative oxidation states.

Choose the correct answer from the options given below :

Arrange the following elements in the increasing order of number of unpaired electrons in it.

(A) $$\mathrm{Sc}$$

(B) $$\mathrm{Cr}$$

(C) $$\mathrm{V}$$

(D) $$\mathrm{Ti}$$

(E) $$\mathrm{Mn}$$

Choose the correct answer from the options given below :

The major products formed :

A and B respectively are :

The incorrect statements regarding enzymes are :

(A) Enzymes are biocatalysts.

(B) Enzymes are non-specific and can catalyse different kinds of reactions.

(C) Most Enzymes are globular proteins.

(D) Enzyme - oxidase catalyses the hydrolysis of maltose into glucose.

Choose the correct answer from the option given below :

The ratio $$\frac{K_P}{K_C}$$ for the reaction :

$$\mathrm{CO}_{(\mathrm{g})}+\frac{1}{2} \mathrm{O}_{2(\mathrm{~g})} \rightleftharpoons \mathrm{CO}_{2(\mathrm{~g})}$$ is :

The correct IUPAC name of $$[\mathrm{PtBr}_2(\mathrm{PMe}_3)_2]$$ is :

The incorrect statement regarding the geometrical isomers of 2-butene is :

Consider the following reactions

The number of protons that do not involve in hydrogen bonding in the product B is _________.

For the reaction at $$298 \mathrm{~K}, 2 \mathrm{~A}+\mathrm{B} \rightarrow \mathrm{C}, \Delta \mathrm{H}=400 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and $$\Delta S=0.2 \mathrm{~kJ} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$$. The reaction will become spontaneous above __________ $$\mathrm{K}$$.

Number of carbocations from the following that are not stabilized by hyperconjugation is _______.

When '$$x$$' $$\times 10^{-2} \mathrm{~mL}$$ methanol (molar mass $$=32 \mathrm{~g}$$' density $$=0.792 \mathrm{~g} / \mathrm{cm}^3$$) is added to $$100 \mathrm{~mL}$$. water (density $$=1 \mathrm{~g} / \mathrm{cm}^3$$), the following diagram is obtained.

$$x=$$ ________ (nearest integer).

[Given : Molal freezing point depression constant of water at $$273.15 \mathrm{~K}$$ is $$1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$]

For hydrogen atom, energy of an electron in first excited state is $$-3.4 \mathrm{~eV}, \mathrm{K} . \mathrm{E}$$. of the same electron of hydrogen atom is $$x \mathrm{~eV}$$. Value of $$x$$ is _________ $$\times 10^{-1} \mathrm{~eV}$$. (Nearest integer)

Consider the two different first order reactions given below

$$\begin{aligned} & \mathrm{A}+\mathrm{B} \rightarrow \mathrm{C} \text { (Reaction 1) } \\ & \mathrm{P} \rightarrow \mathrm{Q} \text { (Reaction 2) } \end{aligned}$$

The ratio of the half life of Reaction 1 : Reaction 2 is $$5: 2$$ If $$t_1$$ and $$t_2$$ represent the time taken to complete $$2 / 3^{\text {rd }}$$ and $$4 / 5^{\text {th }}$$ of Reaction 1 and Reaction 2 , respectively, then the value of the ratio $$t_1: t_2$$ is _________ $$\times 10^{-1}$$ (nearest integer). [Given : $$\log _{10}(3)=0.477$$ and $$\log _{10}(5)=0.699$$]

An amine $$(\mathrm{X})$$ is prepared by ammonolysis of benzyl chloride. On adding p-toluenesulphonyl chloride to it the solution remains clear. Molar mass of the amine $$(\mathrm{X})$$ formed is _________ $$\mathrm{g} \mathrm{mol}^{-1}$$.

(Given molar mass in $$\mathrm{gmol}^{-1} \mathrm{C}: 12, \mathrm{H}: 1, \mathrm{O}: 16, \mathrm{~N}: 14$$)

Among $$\mathrm{VO}_2^{+}, \mathrm{MnO}_4^{-}$$ and $$\mathrm{Cr}_2 \mathrm{O}_7^{2-}$$, the spin-only magnetic moment value of the species with least oxidising ability is __________ BM (Nearest integer).

(Given atomic member $$\mathrm{V}=23, \mathrm{Mn}=25, \mathrm{Cr}=24$$)

The ratio of number of oxygen atoms to bromine atoms in the product Q is _________ $$\times 10^{-1}$$.

Total number of species from the following with central atom utilising $$\mathrm{sp}^2$$ hybrid orbitals for bonding is ________.

$$\mathrm{NH}_3, \mathrm{SO}_2, \mathrm{SiO}_2, \mathrm{BeCl}_2, \mathrm{C}_2 \mathrm{H}_2, \mathrm{C}_2 \mathrm{H}_4, \mathrm{BCl}_3, \mathrm{HCHO}, \mathrm{C}_6 \mathrm{H}_6, \mathrm{BF}_3, \mathrm{C}_2 \mathrm{H}_4 \mathrm{Cl}_2$$