The major product 'P' for the following sequence of reactions is :

The magnetic behaviour of $$\mathrm{Li_2O,Na_2O_2}$$ and $$\mathrm{KO_2}$$, respectively, are :

Compound that will give positive Lassaigne's test for both nitrogen and halogen is :

Identify the correct order for the given property for following compounds.

Choose the correct answer from the option given below :

The bond dissociation energy is highest for

Number of cyclic tripeptides formed with 2 amino acids A and B is :

The shortest wavelength of hydrogen atom in Lyman series is $$\lambda$$. The longest wavelength is Balmer series of He$$^+$$ is

Match List I with List II

	List I		List II
	Reaction		Reagents
(A)	Hoffmann Degradation	(I)	$$\mathrm{Conc. KOH}$$, $$\Delta$$
(B)	Clemenson reduction	(II)	$$\mathrm{CHCl_3,NaOH/H_3O}$$$$^ \oplus $$
(C)	Cannizaro reaction	(III)	$$\mathrm{Br_2,NaOH}$$
(D)	Reimer-Tiemann Reaction	(IV)	$$\mathrm{Zn-Hg/HCl}$$

Choose the correct answer from the options given below :

The increasing order of $$\mathrm{pK_a}$$ for the following phenols is

(A) 2, 4 - Dinitrophenol

(B) 4 - Nitrophenol

(C) 2, 4, 5 - Trimethylphenol

(D) Phenol

(E) 3-Chlorophenol

Choose the correct answer from the option given below :

Chiral complex from the following is :

Here en = ethylene diamine

The standard electrode potential $$\mathrm{(M^{3+}/M^{2+})}$$ for V, Cr, Mn & Co are $$-$$0.26 V, $$-$$0.41 V, + 1.57 V and + 1.97 V, respectively. The metal ions which can liberate $$\mathrm{H_2}$$ from a dilute acid are :

Following chromatogram was developed by adsorption of compound 'A' on a 6 cm TLC glass plate. Retardation factor of the compound 'A' is _________ $$\times 10^{-1}$$.

Millimoles of calcium hydroxide required to produce 100 mL of the aqueous solution of pH 12 is $$x\times10^{-1}$$. The value of $$x$$ is ___________ (Nearest integer).

Assume complete dissociation.

For certain chemical reaction $$X\to Y$$, the rate of formation of product is plotted against the time as shown in the figure. The number of $$\mathrm{\underline {correct} }$$ statement/s from the following is ___________.

(A) Over all order of this reaction is one.

(B) Order of this reaction can't be determined.

(C) In region I and III, the reaction is of first and zero order respectively.

(D) In region-II, the reaction is of first order.

(E) In region-II, the order of reaction is in the range of 0.1 to 0.9.

The number of molecules or ions from the following, which do not have odd number of electrons are _________.

(A) NO$$_2$$

(B) ICl$$_4^ - $$

(C) BrF$$_3$$

(D) ClO$$_2$$

(E) NO$$_2^ + $$

(F) NO

Following figure shows dependence of molar conductance of two electrolytes on concentration. $$\Lambda \mathop m\limits^o $$ is the limiting molar conductivity.

The number of $$\mathrm{\underline {incorrect} }$$ statement(s) from the following is ___________

(A) $$\Lambda \mathop m\limits^o $$ for electrolyte A is obtained by extrapolation

(B) For electrolyte B, $$\Lambda \mathop m\limits $$ vs $$\sqrt c$$ graph is a straight line with intercept equal to $$\Lambda \mathop m\limits^o $$

(C) At infinite dilution, the value of degree of dissociation approaches zero for electrolyte B.

(D) $$\Lambda \mathop m\limits^o $$ for any electrolyte A and B can be calculated using $$\lambda^\circ$$ for individual ions

Solid Lead nitrate is dissolved in 1 litre of water. The solution was found to boil at 100.15$$^\circ$$C. When 0.2 mol of NaCl is added to the resulting solution, it was observed that the solution froze at $$-0.8^\circ$$ C. The solubility product of PbCl$$_2$$ formed is __________ $$\times$$ 10$$^{-6}$$ at 298 K. (Nearest integer)

Given : $$\mathrm{K_b=0.5}$$ K kg mol$$^{-1}$$ and $$\mathrm{K_f=1.8}$$ K kg mol$$^{-1}$$. Assume molality to the equal to molarity in all cases.

Water decomposes at 2300 K

$$\mathrm{H_2O(g)\to H_2(g)+\frac{1}{2}O_2(g)}$$

The percent of water decomposing at 2300 K and 1 bar is ___________ (Nearest integer).

Equilibrium constant for the reaction is $$2\times10^{-3}$$ at 2300 K.

Consider the following reaction approaching equilibrium at 27$$^\circ$$C and 1 atm pressure

$$\mathrm{A+B}$$ $$\mathrel{\mathop{\kern0pt\rightleftharpoons} \limits_{{k_r} = {{10}^2}}^{{k_f} = {{10}^3}}} $$ $$\mathrm{C+D}$$

The standard Gibb's energy change $$\mathrm{(\Delta_r G^\theta)}$$ at 27$$^\circ$$C is ($$-$$) ___________ kJ mol$$^{-1}$$ (Nearest integer).

(Given : $$\mathrm{R=8.3~J~K^{-1}~mol^{-1}}$$ and $$\mathrm{\ln 10=2.3}$$)

The sum of bridging carbonyls in $$\mathrm{W(CO)_6}$$ and $$\mathrm{Mn_2(CO)_{10}}$$ is ____________.

17 mg of a hydrocarbon (M.F. $$\mathrm{C_{10}H_{16}}$$) takes up 8.40 mL of the H$$_2$$ gas measured at 0$$^\circ$$C and 760 mm of Hg. Ozonolysis of the same hydrocarbon yields

The number of double bond/s present in the hydrocarbon is ___________.