JEE MAIN - Chemistry (2021 - 25th July Morning Shift)

1
Which one of the following species responds to an external magnetic field?
Answer
(A)
[Fe(H2O)6]3+
2
JEE Main 2021 (Online) 25th July Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 96 English
Consider the above reaction, the major product 'P' is :
Answer
(C)
JEE Main 2021 (Online) 25th July Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 96 English Option 3
3
The water soluble protein is :
Answer
(B)
Albumin
4

Consider the given reaction, the product 'X' is :
Answer
(D)
JEE Main 2021 (Online) 25th July Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 120 English Option 4
5
JEE Main 2021 (Online) 25th July Morning Shift Chemistry - Haloalkanes and Haloarenes Question 84 English
The given reaction can occur in the presence of :

(a) Bromine water

(b) Br2 in CS2, 273 K

(c) Br2/FeBr3

(d) Br2 in CHCl3, 273 K

Choose the correct answer from the options gien below :
Answer
(C)
(b), (c) and (d) only
6
Given below are two statements, one is labelled as Assertion (A) and other is labelled as Reason (R).

Assertion (A) : Gabriel phthalimide synthesis cannot be used to prepare aromatic primary amines.

Reason (R) : Aryl halides do not undergo nucleophilic substitution reaction.

In the light of the above statements, choose the correct answer from the options given below :
Answer
(C)
Both (A) and (R) true and (R) is correct explanation of (A).
7
For the following graphs,


Choose from the options given below, the correct one regarding order of reaction is :
Answer
(B)
(a) and (b) Zero order (e) First order
8
Which one of the products of the following reactions does not react with Hinsberg reagent to form sulphonamide?
Answer
(B)
JEE Main 2021 (Online) 25th July Morning Shift Chemistry - Compounds Containing Nitrogen Question 125 English Option 2
9
The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order:
Answer
(C)
Al3+ < Mg2+ < Na+ < K+
10
Which one of the following compounds of Group-14 elements is not known?
Answer
(C)
[SiCl6]2$$-$$
11
Which one among the following resonating structures is not correct?
Answer
(A)
JEE Main 2021 (Online) 25th July Morning Shift Chemistry - Basics of Organic Chemistry Question 143 English Option 1
12
The correct order of following 3d metal oxides, according to their oxidation numbers is :

(a) CrO3, (b) Fe2O3, (c) MnO2, (d) V2O5, (e) Cu2O
Answer
(C)
(a) > (d) > (c) > (b) > (e)
13
Which one of the following compounds will liberate CO2, when treated with NaHCO3 ?
Answer
(A)
$${(C{H_3})_3}\mathop {NH}\limits^ \oplus \mathop {Cl}\limits^\Theta $$
14
An organic compound 'A' C4H8 on treatment with KMnO4/H+ yields compound 'B' C3H6O.

Compound 'A' also yields compound 'B' an ozonolysis. Compound 'A' is :
Answer
(A)
2-Methylpropene
15
The number of sigma bonds in

JEE Main 2021 (Online) 25th July Morning Shift Chemistry - Hydrocarbons Question 72 English
is _______________.
Answer
10
16
Three moles of AgCl get precipitated when one mole of an octahedral co-ordination compound with empirical formula CrCl3.3NH3.3H2O reacts with excess of silver nitrate. The number of chloride ions satisfying the secondary valency of the metal ion is ______________.
Answer
0
17
A source of monochromatic radiation of wavelength 400 nm provides 1000 J of energy in 10 seconds. When this radiation falls on the surface of sodium, x $$\times$$ 1020 electrons are ejected per second. Assume that wavelength 400 nm is sufficient for ejection of electron from the surface of sodium metal. The value of x is ______________. (Nearest integer)

(h = 6.626 $$\times$$ 10$$-$$34 Js)
Answer
2
18
CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K. If CO2 exerts a partial pressure of 0.835 bar then x m mol of CO2 would dissolve in 0.9 L of water. The value of x is ____________. (Nearest integer)

(Henry's law constant for CO2 at 298 K is 1.67 $$\times$$ 103 bar)
Answer
25
19
For the reaction

A + B $$\rightleftharpoons$$ 2C

the value of equilibrium constant is 100 at 298 K. If the initial concentration of all the three species is 1 M each, then the equilibrium concentration of C is x $$\times$$ 10$$-$$1 M. The value of x is ____________. (Nearest integer)
Answer
25
20
Consider the cell at 25$$^\circ$$C

Zn | Zn2+ (aq), (1M) || Fe3+ (aq), Fe2+ (aq) | Pt(s)

The fraction of total iron present as Fe3+ ion at the cell potential of 1.500 V is x $$\times$$ 10$$-$$2. The value of x is ______________. (Nearest integer)

(Given : $$E_{F{e^{3 + }}/F{e^{2 + }}}^0 = 0.77V$$, $$E_{Z{n^{2 + }}/Zn}^0 = - 0.76V$$)
Answer
24
21
At 298 K, the enthalpy of fusion of a solid (X) is 2.8 kJ mol$$-$$1 and the enthalpy of vaporisation of the liquid (X) is 98.2 kJ mol$$-$$1. The enthalpy of sublimation of the substance (X) in kJ mol$$-$$1 is _____________. (in nearest integer)
Answer
101
22
When 10 mL of an aqueous solution of Fe2+ ions was titrated in the presence of dil H2SO4 using diphenylamine indicator, 15 mL of 0.02 M solution of K2Cr2O7 was required to get the end point. The molarity of the solution containing Fe2+ ions is x $$\times$$ 10$$-$$2 M. The value of x is __________. (Nearest integer)
Answer
18
23
Consider the complete combustion of butane, the amount of butane utilized to produce 72.0 g of water is ___________ $$\times$$ 10$$-$$1 g. (in nearest integer)
Answer
464