An organic compound 'A' C4H8 on treatment with KMnO4/H+ yields compound 'B' C3H6O.
Compound 'A' also yields compound 'B' an ozonolysis. Compound 'A' is :
Answer
(A)
2-Methylpropene
15
The number of sigma bonds in
is _______________.
Answer
10
16
Three moles of AgCl get precipitated when one mole of an octahedral co-ordination compound with empirical formula CrCl3.3NH3.3H2O reacts with excess of silver nitrate. The number of chloride ions satisfying the secondary valency of the metal ion is ______________.
Answer
0
17
A source of monochromatic radiation of wavelength 400 nm provides 1000 J of energy in 10 seconds. When this radiation falls on the surface of sodium, x $$\times$$ 1020 electrons are ejected per second. Assume that wavelength 400 nm is sufficient for ejection of electron from the surface of sodium metal. The value of x is ______________. (Nearest integer)
(h = 6.626 $$\times$$ 10$$-$$34 Js)
Answer
2
18
CO2 gas is bubbled through water during a soft drink manufacturing process at 298 K. If CO2 exerts a partial pressure of 0.835 bar then x m mol of CO2 would dissolve in 0.9 L of water. The value of x is ____________. (Nearest integer)
(Henry's law constant for CO2 at 298 K is 1.67 $$\times$$ 103 bar)
Answer
25
19
For the reaction
A + B $$\rightleftharpoons$$ 2C
the value of equilibrium constant is 100 at 298 K. If the initial concentration of all the three species is 1 M each, then the equilibrium concentration of C is x $$\times$$ 10$$-$$1 M. The value of x is ____________. (Nearest integer)
The fraction of total iron present as Fe3+ ion at the cell potential of 1.500 V is x $$\times$$ 10$$-$$2. The value of x is ______________. (Nearest integer)
At 298 K, the enthalpy of fusion of a solid (X) is 2.8 kJ mol$$-$$1 and the enthalpy of vaporisation of the liquid (X) is 98.2 kJ mol$$-$$1. The enthalpy of sublimation of the substance (X) in kJ mol$$-$$1 is _____________. (in nearest integer)
Answer
101
22
When 10 mL of an aqueous solution of Fe2+ ions was titrated in the presence of dil H2SO4 using diphenylamine indicator, 15 mL of 0.02 M solution of K2Cr2O7 was required to get the end point. The molarity of the solution containing Fe2+ ions is x $$\times$$ 10$$-$$2 M. The value of x is __________. (Nearest integer)
Answer
18
23
Consider the complete combustion of butane, the amount of butane utilized to produce 72.0 g of water is ___________ $$\times$$ 10$$-$$1 g. (in nearest integer)