JEE MAIN - Chemistry (2021 - 25th July Morning Shift - No. 9)
The ionic radii of K+, Na+, Al3+ and Mg2+ are in the order:
Na+ < K+ < Mg2+ < Al3+
Al3+ < Mg2+ < K+ < Na+
Al3+ < Mg2+ < Na+ < K+
K+ < Al3+ < Mg2+ < Na+
Explanation
Al3+, Mg2+ and Na+ are isoelectronic ionic species. For monoatomic ionic isoelectronic species as positive charge increases ionic size decreases.
The order of size of Na+ & K+ is Na+ < K+
$$\therefore$$ Order of ionic radii is : Al3+ < Mg2+ < Na+ < K+
The order of size of Na+ & K+ is Na+ < K+
$$\therefore$$ Order of ionic radii is : Al3+ < Mg2+ < Na+ < K+
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