JEE MAIN - Chemistry (2021 - 20th July Evening Shift)

1
Which one of the following pairs of isomers is an example of metamerism?
Answer
(D)
JEE Main 2021 (Online) 20th July Evening Shift Chemistry - Basics of Organic Chemistry Question 148 English Option 4
2
JEE Main 2021 (Online) 20th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 128 English
In the above reactions, product A and product B respectively are :
Answer
(D)
JEE Main 2021 (Online) 20th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 128 English Option 4
3
The major product (P) in the following reaction is :

Answer
(B)
JEE Main 2021 (Online) 20th July Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 123 English Option 2
4
A solution is 0.1 M in Cl$$-$$ and 0.001 M in CrO$$_4^{2 - }$$. Solid AgNO3 is gradually added to it. Assuming that the addition does not change in volume and Ksp(AgCl) = 1.7 $$\times$$ 10$$-$$10 M2 and Ksp(Ag2CrO4) = 1.9 $$\times$$ 10$$-$$12 M3.

Select correct statement from the following :
Answer
(D)
AgCl will precipitate first as the amount of Ag+ needed to precipitate is low.
5
Outermost electronic configuration of a group 13 element, E, is 4s2, 4p1. The electronic configuration of an element of p-block period-five placed diagonally to element, E is :
Answer
(D)
[Kr] 4d10 5s2 5p2
6
Metallic sodium does not react normally with :
Answer
(B)
But-2-yne
7
Spin only magnetic moment of an octahedral complex of Fe2+ in the presence of a strong field ligand in BM is :
Answer
(C)
0
8
Which one of the following species doesn't have a magnetic moment of 1.73 BM, (spin only value)?
Answer
(B)
CuI
9
Which one of the following statements is not true about enzymes?
Answer
(A)
Enzymes are non-specific for a reaction and substrate.
10
The hybridisations of the atomic orbitals of nitrogen in NO$$_2^ - $$, NO$$_2^ + $$ and NH$$_4^ + $$ respectively are.
Answer
(D)
sp2, sp and sp3
11
Benzene on nitration gives nitrobenzene in presence of HNO3 and H2SO4 mixture, where :
Answer
(D)
HNO3 acts as a base and H2SO4 acts as an acid
12

Consider the above reaction, compound B is :
Answer
(C)
JEE Main 2021 (Online) 20th July Evening Shift Chemistry - Compounds Containing Nitrogen Question 129 English Option 3
13

Major product P of above reaction, is :
Answer
(D)
JEE Main 2021 (Online) 20th July Evening Shift Chemistry - Hydrocarbons Question 76 English Option 4
14
Cu2+ salt reacts with potassium iodide to give
Answer
(C)
Cul
15
In Carius method, halogen containing organic compound is heated with fuming nitric acid in the presence of :
Answer
(B)
AgNO3
16
JEE Main 2021 (Online) 20th July Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 122 English
The correct order of their reactivity towards hydrolysis at room temperature is :
Answer
(A)
(A) > (B) > (C) > (D)
17
For a given chemical reaction A $$\to$$ B at 300 K the free energy change is $$-$$49.4 kJ mol$$-$$1 and the enthalpy of reaction is 51.4 kJ mol$$-$$1. The entropy change of the reaction is _____________ JK$$-$$1 mol$$-$$1.
Answer
336
18
The wavelength of electrons accelerated from rest through a potential difference of 40 kV is x $$\times$$ 10$$-$$12 m. The value of x is ___________. (Nearest integer)

Give : Mass of electron = 9.1 $$\times$$ 10$$-$$31 kg

Charge on an electron = 1.6 $$\times$$ 10$$-$$19 C

Planck's constant = 6.63 $$\times$$ 10$$-$$34 Js
Answer
6
19
The vapour pressures of A and B at 25$$^\circ$$C are 90 mm Hg and 15 mm Hg respectively. If A and B are mixed such that the mole fraction of A in the mixture is 0.6, then the mole fraction of B in the vapour phase is x $$\times$$ 10$$-$$1. The value of x is ___________. (Nearest integer)
Answer
1
20
4g equimolar mixture of NaOH and Na2CO3 contains x g of NaOH and y g of Na2CO3. The value of x is ____________ g. (Nearest integer)
Answer
1
21
When 0.15 g of an organic compound was analyzed using Carius method for estimation of bromine, 0.2397 g of AgBr was obtained. The percentage of bromine in the organic compound is ______________. (Nearest integer)

[Atomic mass : Silver = 108, Bromine = 80]
Answer
68
22
$$PC{l_5}(g) \to PC{l_3}(g) + C{l_2}(g)$$

In the above first order reaction the concentration of PCl5 reduces from initial concentration 50 mol L$$-$$1 to 10 mol L$$-$$1 in 120 minutes at 300 K. The rate constant for the reaction at 300 K is x $$\times$$ 10$$-$$2 min$$-$$1. The value of x is __________. [Given log5 = 0.6989]
Answer
1
23
An aqueous solution of NiCl2 was heated with excess sodium cyanide in presence of strong oxidizing agent to form [Ni(CN)6]2$$-$$. The total change in number of unpaired electrons on metal centre is _______________.
Answer
2
24
Potassium chlorate is prepared by electrolysis of KCl in basic solution as shown by following equation.

6OH$$-$$ + Cl$$-$$ $$\to$$ ClO3$$-$$ + 3H2O + 6e$$-$$

A current of xA has to be passed for 10h to produce 10.0g of potassium chlorate. The value of x is ____________. (Nearest integer)

(Molar mass of KClO3 = 122.6 g mol$$-$$1, F = 96500 C)
Answer
1