JEE MAIN - Chemistry (2021 - 20th July Evening Shift - No. 7)

Spin only magnetic moment of an octahedral complex of Fe2+ in the presence of a strong field ligand in BM is :
4.89
2.82
0
3.46

Explanation

In presence of SFL $$\Delta$$0 > P means pairing occurs therefore

For Fe+2 $$\to$$ 3d6



$$\therefore$$ No of unpaired e-(s) = 0

$$\therefore$$ $$\mu$$ = $$\sqrt {n(n + 2)} $$BM = 0

[n = No of unpaired e$$-$$(s)]

In NiCl2, Ni+2 is having configuration 3d8

$$\therefore$$ Number of unpaired electron = 2

After formation of oxidised product

[Ni(CN)6]$$-$$2$$ \Rightarrow $$ Ni+4 is obtained

Ni+4 $$\Rightarrow$$ 3d6 and CN$$-$$ is strong field ligand

$$\therefore$$ Number of unpaired electrons = 0

$$\therefore$$ The charge is 2 $$-$$ 0 = 2

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