JEE MAIN - Chemistry (2021 - 20th July Evening Shift - No. 7)
Spin only magnetic moment of an octahedral complex of Fe2+ in the presence of a strong field ligand in BM is :
4.89
2.82
0
3.46
Explanation
In presence of SFL $$\Delta$$0 > P means pairing occurs therefore
For Fe+2 $$\to$$ 3d6
$$\therefore$$ No of unpaired e-(s) = 0
$$\therefore$$ $$\mu$$ = $$\sqrt {n(n + 2)} $$BM = 0
[n = No of unpaired e$$-$$(s)]
In NiCl2, Ni+2 is having configuration 3d8
$$\therefore$$ Number of unpaired electron = 2
After formation of oxidised product
[Ni(CN)6]$$-$$2$$ \Rightarrow $$ Ni+4 is obtained
Ni+4 $$\Rightarrow$$ 3d6 and CN$$-$$ is strong field ligand
$$\therefore$$ Number of unpaired electrons = 0
$$\therefore$$ The charge is 2 $$-$$ 0 = 2
For Fe+2 $$\to$$ 3d6
_20th_July_Evening_Shift_en_7_2.png)
$$\therefore$$ No of unpaired e-(s) = 0
$$\therefore$$ $$\mu$$ = $$\sqrt {n(n + 2)} $$BM = 0
[n = No of unpaired e$$-$$(s)]
In NiCl2, Ni+2 is having configuration 3d8
$$\therefore$$ Number of unpaired electron = 2
After formation of oxidised product
[Ni(CN)6]$$-$$2$$ \Rightarrow $$ Ni+4 is obtained
Ni+4 $$\Rightarrow$$ 3d6 and CN$$-$$ is strong field ligand
$$\therefore$$ Number of unpaired electrons = 0
$$\therefore$$ The charge is 2 $$-$$ 0 = 2
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