JEE MAIN - Chemistry (2021 - 20th July Evening Shift - No. 8)
Which one of the following species doesn't have a magnetic moment of 1.73 BM, (spin only value)?
O$$_2^ + $$
CuI
[Cu(NH3)4]Cl2
O$$_2^ - $$
Explanation
Species does not have a magnetic moment of 1.7 BM means species must not contain single unpaired electron.
(a) Molecular orbital configuration of O$$_2^ + $$ (15 electrons) is
$${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\sigma _{2p_z^2}}\,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,\pi _{2p_x^1}^ * \, = \,\pi _{2p_y^o}^ * $$
Unpaired electron = 1
$$\mu = \sqrt {n(n + 2)} = \sqrt {1(1 + 2)} = \sqrt 3 = 1.73$$
where n = no. of unpaired e$$-$$
$$\therefore$$ $$\mu$$ = 1.73 BM
(b) Cul $$\Rightarrow$$ Cu+ $$-$$[Ar]3d10, Unpaired electron = 0
I$$-$$ $$\to$$ [Xe], unpaired electron = 0
Therefore, $$\mu$$ = 0
(c) [Cu(NH3)4]Cl2
Cu2+ $$\to$$ [Ar]3d9
Unpaired electron = 1,
Therefore, $$\mu$$ = 1.73 BM
(d) Molecular orbital configuration of $$O_2^ - $$ (17 electrons) is
$${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\sigma _{2p_z^2}}\,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,\pi _{2p_x^2}^ * \, = \,\pi _{2p_y^1}^ * $$
Unpaired electron = 1
Therefore, $$\mu$$ = 1.73 BM
Therefore, Cul does not have magnetic moment of 1.73 BM.
(a) Molecular orbital configuration of O$$_2^ + $$ (15 electrons) is
$${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\sigma _{2p_z^2}}\,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,\pi _{2p_x^1}^ * \, = \,\pi _{2p_y^o}^ * $$
Unpaired electron = 1
$$\mu = \sqrt {n(n + 2)} = \sqrt {1(1 + 2)} = \sqrt 3 = 1.73$$
where n = no. of unpaired e$$-$$
$$\therefore$$ $$\mu$$ = 1.73 BM
(b) Cul $$\Rightarrow$$ Cu+ $$-$$[Ar]3d10, Unpaired electron = 0
I$$-$$ $$\to$$ [Xe], unpaired electron = 0
Therefore, $$\mu$$ = 0
(c) [Cu(NH3)4]Cl2
Cu2+ $$\to$$ [Ar]3d9
Unpaired electron = 1,
Therefore, $$\mu$$ = 1.73 BM
(d) Molecular orbital configuration of $$O_2^ - $$ (17 electrons) is
$${\sigma _{1{s^2}}}\,\sigma _{1{s^2}}^ * \,{\sigma _{2{s^2}}}\,\sigma _{2{s^2}}^ * \,{\sigma _{2p_z^2}}\,{\pi _{2p_x^2}}\, = \,{\pi _{2p_y^2}}\,\pi _{2p_x^2}^ * \, = \,\pi _{2p_y^1}^ * $$
Unpaired electron = 1
Therefore, $$\mu$$ = 1.73 BM
Therefore, Cul does not have magnetic moment of 1.73 BM.
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