Extraction of copper from copper pyrite (CuFeS₂) involves

For the following electrochemical cell at 298 K

Pt(s) | H₂ (g, 1 bar) | H⁺ (aq, 1 M) || M⁴⁺ (aq), M²⁺ (aq) | Pt (s)

E_cell = 0.092 V when $${{\left[ {{M^{2 + }}(aq)} \right]} \over {\left[ {{M^{4 + }}(aq)} \right]}}$$ = 10^x

Give, $$E_{{M^{4+}}/{M^{2 + }}}^o$$ = 0.151 V; 2.303 RT/F = 0.059 V

The value of x is

Mixture (s) showing positive deviation from Raoult’s law at 35^oC is (are)

The CORRECT statement(s) for cubic close packed (ccp) three dimensional structure is (are) :

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Thermal decomposition of gaseous X₂ to gaseous X at 298 K takes place according to the following equations:
X₂ (g) $$\leftrightharpoons$$ 2X (g)
The standard reaction Gibbs energy, $$\Delta _rG^o$$, of this reaction is positive. At the start of the reaction, there is one mole of X₂ and no X. As the reaction proceeds, the number of moles of X formed is given by $$\beta$$. Thus, $$\beta _{equilibrium}$$ is the number of moles of X formed at equilibrium. The reaction is carried out at a constant total pressure of 2 bar. Consider the gases to behave ideally. (Given R = 0.083 L bar K^-1 mol^-1)
Question
The INCORRECT statement among the following for this reaction, is

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Thermal decomposition of gaseous X₂ to gaseous X at 298 K takes place according to the following equations:
X₂ (g) $$\leftrightharpoons$$ 2X (g)
The standard reaction Gibbs energy, $$\Delta _rG^o$$, of this reaction is positive. At the start of the reaction, there is one mole of X₂ and no X. As the reaction proceeds, the number of moles of X formed is given by $$\beta$$. Thus, $$\beta _{equilibrium}$$ is the number of moles of X formed at equilibrium. The reaction is carried out at a constant total pressure of 2 bar. Consider the gases to behave ideally. (Given R = 0.083 L bar K^-1 mol^-1)
Question
The equilibrium constant K_p for this reaction at 298 K, in terms of $$\beta _{equilibrium}$$, is

According to Molecular Orbital Theory, which of the following statements is(are) correct?

The geometries of the ammonia complexes of Ni²⁺, Pt²⁺ and Zn²⁺, respectively, are

The correct order of acidity for the following compounds is

The major product of the following reaction sequence is:

In the following reaction, sequence in aqueous solution, the species X, Y and Z, respectively, are

$${S_2}O_3^{2 - }\buildrel {A{g^ + }} \over \longrightarrow \mathop X\limits_{Clear\,solution} \buildrel {A{g^ + }} \over \longrightarrow \mathop Y\limits_{White\,precipitate} \buildrel {With\,time} \over \longrightarrow \mathop Z\limits_{Black\,precipitate} $$

The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions of KCl, CH₃OH and CH₃(CH₂)₁₁ OSO$$_3^ - $$ Na⁺ at room temperature. The correct assignment of the sketches is

For "invert sugar", the correct statement(s) is(are)

(Given : specific rotations of (+)-sucrose, (+)-maltose, L-($$-$$)-glucose and L-(+)-fructose in aqueous solution are +66$$^\circ$$, +140$$^\circ$$, $$-$$52$$^\circ$$ and +92$$^\circ$$, respectively.)

Among the following reaction(s), which gives(give) tert-butyl benzene as the major product is(are)

Reagent(s) which can be used to bring about the following transformation is(are)

The nitrogen containing compound produced in the reaction of HNO₃ with P₄O₁₀

The compound R is

The compound T is