JEE Advance - Chemistry (2009 - Paper 1 Offline)

1
The compound(s) formed upon combustion of sodium metal in excess air is (are)
Answer
A
B
2
Given that the abundances of isotopes 54Fe, 56Fe and 57Fe are 5%, 90% and 5%, respectively, the atomic mass of Fe is :
Answer
(B)
55.95
3
The term that corrects for the attractive forces present in a real gas in the van der Waals equation is
Answer
(B)
$${{a{n^2}} \over {{V^2}}}$$
4
Among the electrolytes Na$$_2$$SO$$_4$$, CaCl$$_2$$, Al$$_2$$(SO$$_4$$)$$_3$$ and NH$$_4$$Cl, the most effective coagulating agent for Sb$$_2$$S$$_3$$ sol is
Answer
(C)
Al$$_2$$(SO$$_4$$)$$_3$$
5
The Henry's law constant for the solubility of N$$_2$$ gas in water at 298 K is 1.0 $$\times$$ 10$$^5$$ atm. The mole fraction of N$$_2$$ in air is 0.8. The number of moles of N$$_2$$ from air dissolved in 10 moles of water at 298 K and 5 atm pressure is
Answer
(A)
4.0 $$\times$$ 10$$^{-4}$$
6
The reaction of P$$_4$$ with X leads selectively to P$$_4$$O$$_6$$. The X is
Answer
(B)
A mixture of O$$_2$$ and N$$_2$$.
7

The correct acidity order of the following is

IIT-JEE 2009 Paper 1 Offline Chemistry - Basics of Organic Chemistry Question 10 English

Answer
(A)
(III) > (IV) > (II) > (I)
8
Among cellulose, poly(vinyl chloride), nylon and natural rubber, the polymer in which the intermolecular force of attraction is weakest is
Answer
(D)
Natural Rubber
9

The IUPAC name of the following compound is

IIT-JEE 2009 Paper 1 Offline Chemistry - Basics of Organic Chemistry Question 9 English

Answer
(B)
2-Bromo-5-hydroxybenzonitrile
10
The correct statement(s) regarding defects in solids is (are)
Answer
B
C
11
The compound(s) that exhibit(s) geometrical isomerism is(are)
Answer
C
D
12
The correct statement(s) about the compound $$\mathrm{H_3C(HO)HC-CH=CH-CH(OH)CH_3~~(X)}$$ is (are)
Answer
A
D
13
The compound X is
Answer
(D)
Na$$_2$$S
14
The compound Y is
Answer
(C)
FeCl$$_3$$
15
The compound Z is
Answer
(B)
$$Fe[Fe{(CN)_6}]$$
16
The structure of the carbonyl compound P is
Answer
(B)
IIT-JEE 2009 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 19 English Option 2
17
The structures of the products Q and R, respectively, are
Answer
(A)
IIT-JEE 2009 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 20 English Option 1
18
The structure of the product S is
Answer
(B)
IIT-JEE 2009 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 18 English Option 2
19

Match each of the diatomic molecules in Column I with its property/properties in Column II:

Column I Column II
(A) $${B_2}$$ (P) Paramagnetic
(B) $${N_2}$$ (Q) Undergoes oxidation
(C) $$O_2^ - $$ (R) Undergoes reduction
(D) $${O_2}$$ (S) Bond order $$\ge$$ 2
(T) Mixing of $$s$$ and $$p$$ orbitals

Answer
(A)
$$\mathrm{(A)\to(P),(Q),(R),(T);(B)\to(S),(T);(C)\to(P),(Q);(D)\to(P),(Q),(S)}$$
20

Match each of the compounds in Column I with its characteristic reaction(s) in Column II.

Column I Column II
(A) $$C{H_3}C{H_2}C{H_2}CN$$ (P) Reduction with $$Pd - C/{H_2}$$
(B) $$C{H_3}C{H_2}OCOC{H_3}$$ (Q) Reduction with $$SnC{l_2}/HCl$$
(C) $$C{H_3} - CH = CH - C{H_2}OH$$ (R) Development of foul smell on treatment with chloroform and alcoholic KOH
(D) $$C{H_3}C{H_2}C{H_2}C{H_2}N{H_2}$$ (S) Reduction with diisobutylaluminium hydride (DIBAL-H)
(T) Alkaline hydrolysis

Answer
(D)
$$\mathrm{(A)\to(P),(Q),(S),(T);(B)\to(S),(T);(C)\to(P);(D)\to(R)}$$