JEE Advance - Chemistry (2009 - Paper 1 Offline - No. 19)
Match each of the diatomic molecules in Column I with its property/properties in Column II:
Column I | Column II | ||
---|---|---|---|
(A) | $${B_2}$$ | (P) | Paramagnetic |
(B) | $${N_2}$$ | (Q) | Undergoes oxidation |
(C) | $$O_2^ - $$ | (R) | Undergoes reduction |
(D) | $${O_2}$$ | (S) | Bond order $$\ge$$ 2 |
(T) | Mixing of $$s$$ and $$p$$ orbitals |
Explanation
(A) $${B_2} \to \sigma 1{s^2}\,\sigma * 1{s^2}\,\sigma 2{s^2}\,\sigma * 2{s^2}\pi 2p_x^1 = \pi 2p_y^1$$
It is paramagnetic due to two unpaired electrons. The bond order is
$${{{N_b} - {N_a}} \over 2} = {{6 - 4} \over 2} = 1$$
The gain of electron increases bond order, so reduction is possible.
(B) $${N_2} \to \sigma 1{s^2}\,\sigma * 1{s^2}\,\sigma 2{s^2}\,\sigma * 2{s^2}\pi 2p_x^2 = \pi 2p_y^2\sigma 2p_z^2$$
There are no unpaired electrons. Bond order is
$${{{N_b} - {N_a}} \over 2} = {{10 - 4} \over 2} = {6 \over 2} = 3$$
Mixing of 2s and 2p orbitals is possible because of similar energies.
(C) $$O_2^ - \to \sigma 1{s^2}\,\sigma * 1{s^2}\,\sigma 2{s^2}\,\sigma * 2{s^2}\sigma 2p_z^2\pi 2p_x^2 = \pi 2p_y^2\,\pi * 2p_x^2\,\pi * 2p_y^1$$
The molecule is paramagnetic due to presence of unpaired electron. Bond order is less than 2.
$${{{N_b} - {N_a}} \over 2} = {{10 - 7} \over 2} = {3 \over 2}$$
Loss of electron increases the bond order so oxidation is possible.
(D) $$O_2^{} \to \sigma 1{s^2}\,\sigma * 1{s^2}\,\sigma 2{s^2}\,\sigma * 2{s^2}\sigma 2p_z^2\pi 2p_x^2 = \pi 2p_y^2\,\pi * 2p_x^1\,\pi * 2p_y^1$$
The molecule is paramagnetic due to presence of unpaired electrons. Bond order is
$${{{N_b} - {N_a}} \over 2} = {{10 - 6} \over 2} = {4 \over 2} = 2$$
Loss of electron causes increase in bond order, so it undergoes oxidation.
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