Number of complexes from the following with even number of unpaired "$$\mathrm{d}$$" electrons is ________ $$[\mathrm{V}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cr}(\mathrm{H}_2 \mathrm{O})_6]^{2+},[\mathrm{Fe}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Ni}(\mathrm{H}_2 \mathrm{O})_6]^{3+},[\mathrm{Cu}(\mathrm{H}_2 \mathrm{O})_6]^{2+}$$ [Given atomic numbers: $$\mathrm{V}=23, \mathrm{Cr}=24, \mathrm{Fe}=26, \mathrm{Ni}=28 \mathrm{Cu}=29$$]

What will be the decreasing order of basic strength of the following conjugate bases? $${ }^{-} \mathrm{OH}, \mathrm{R} \overline{\mathrm{O}}, \mathrm{CH}_3 \mathrm{CO} \overline{\mathrm{O}}, \mathrm{Cl}$$

Given below are two statements :

Statements I : Acidity of $$\alpha$$-hydrogens of aldehydes and ketones is responsible for Aldol reaction.

Statement II : Reaction between benzaldehyde and ethanal will NOT give Cross - Aldol product.

In the light of the above statements, choose the most appropriate answer from the options given below :

Match List I with List II :

	LIST I Mechanism steps		LIST II Effect
A.		I.	$$-$$ E effect
B.		II.	$$-$$ R effect
C.		III.	$$+$$ E effect
D.		IV.	$$+$$ R effect

Choose the correct answer from the options given below :

Identify B and C and how are A and C related?

Identify the correct set of reagents or reaction conditions '$$X$$' and '$$Y$$' in the following set of transformation.

In the precipitation of the iron group (III) in qualitative analysis, ammonium chloride is added before adding ammonium hydroxide to :

The element which shows only one oxidation state other than its elemental form is :

Which of the following is the correct structure of L-Glucose?

Identify the product in the following reaction:

Number of molecules/ions from the following in which the central atom is involved in $$\mathrm{sp}^3$$ hybridization is ________.

$$\mathrm{NO}_3^{-}, \mathrm{BCl}_3, \mathrm{ClO}_2^{-}, \mathrm{ClO}_3^{-}$$

The correct sequence of ligands in the order of decreasing field strength is :

The Molarity (M) of an aqueous solution containing $$5.85 \mathrm{~g}$$ of $$\mathrm{NaCl}$$ in $$500 \mathrm{~mL}$$ water is : (Given : Molar Mass $$\mathrm{Na}: 23$$ and $$\mathrm{Cl}: 35.5 \mathrm{~gmol}^{-1}$$)

Which among the following is incorrect statement?

One of the commonly used electrode is calomel electrode. Under which of the following categories, calomel electrode comes?

The correct order of first ionization enthalpy values of the following elements is :

(A) O

(B) N

(C) Be

(D) F

(E) B

Choose the correct answer from the options given below :

Which of the following nitrogen containing compound does not give Lassaigne's test ?

Which one of the following molecules has maximum dipole moment?

What pressure (bar) of $$\mathrm{H}_2$$ would be required to make emf of hydrogen electrode zero in pure water at $$25^{\circ} \mathrm{C}$$ ?

Number of elements from the following that CANNOT form compounds with valencies which match with their respective group valencies is ________. B, C, N, S, O, F, P, Al, Si

$$2.5 \mathrm{~g}$$ of a non-volatile, non-electrolyte is dissolved in $$100 \mathrm{~g}$$ of water at $$25^{\circ} \mathrm{C}$$. The solution showed a boiling point elevation by $$2^{\circ} \mathrm{C}$$. Assuming the solute concentration is negligible with respect to the solvent concentration, the vapor pressure of the resulting aqueous solution is _________ $$\mathrm{mm}$$ of $$\mathrm{Hg}$$ (nearest integer)

[Given : Molal boiling point elevation constant of water $\left(\mathrm{K}_{\mathrm{b}}\right)=0.52 \mathrm{~K} . \mathrm{kg} \mathrm{mol}^{-1}$, $$1 \mathrm{~atm}$$ pressure $$=760 \mathrm{~mm}$$ of $$\mathrm{Hg}$$, molar mass of water $$=18 \mathrm{~g} \mathrm{~mol}^{-1}]$$

Only $$2 \mathrm{~mL}$$ of $$\mathrm{KMnO}_4$$ solution of unknown molarity is required to reach the end point of a titration of $$20 \mathrm{~mL}$$ of oxalic acid $$(2 \mathrm{M})$$ in acidic medium. The molarity of $$\mathrm{KMnO}_4$$ solution should be ________ M.

Consider the following transformation involving first order elementary reaction in each step at constant temperature as shown below.

Some details of the above reactions are listed below.

Step	Rate constant (sec$$^{-1}$$)	Activation energy (kJ mol$$^{-1}$$)
1	$$\mathrm{k_1}$$	300
2	$$\mathrm{k_2}$$	200
3	$$\mathrm{k_3}$$	$$\mathrm{Ea_3}$$

If the overall rate constant of the above transformation (k) is given as $$\mathrm{k=\frac{k_1 k_2}{k_3}}$$ and the overall activation energy $$(\mathrm{E}_{\mathrm{a}})$$ is $$400 \mathrm{~kJ} \mathrm{~mol} \mathrm{~m}^{-1}$$, then the value of $$\mathrm{Ea}_3$$ is ________ integer)

The enthalpy of formation of ethane $$(\mathrm{C}_2 \mathrm{H}_6)$$ from ethylene by addition of hydrogen where the bond-energies of $$\mathrm{C}-\mathrm{H}, \mathrm{C}-\mathrm{C}, \mathrm{C}=\mathrm{C}, \mathrm{H}-\mathrm{H}$$ are $$414 \mathrm{~kJ}, 347 \mathrm{~kJ}, 615 \mathrm{~kJ}$$ and $$435 \mathrm{~kJ}$$ respectively is $$-$$ __________ $$\mathrm{kJ}$$

$$\mathrm{Xg}$$ of ethylamine is subjected to reaction with $$\mathrm{NaNO}_2 / \mathrm{HCl}$$ followed by water; evolved dinitrogen gas which occupied $$2.24 \mathrm{~L}$$ volume at STP. X is _________ $$\times 10^{-1} \mathrm{~g}$$.

The number of the correct reaction(s) among the following is _______.

The de-Broglie's wavelength of an electron in the $$4^{\text {th }}$$ orbit is ________ $$\pi \mathrm{a}_0$$. ($$\mathrm{a}_0=$$ Bohr's radius)

The number of different chain isomers for C$$_7$$H$$_{16}$$ is __________.

Number of molecules/species from the following having one unpaired electron is ________.

$$\mathrm{O}_2, \mathrm{O}_2^{-1}, \mathrm{NO}, \mathrm{CN}^{-1}, \mathrm{O}_2^{2-}$$

Consider the following reaction

$$\mathrm{MnO}_2+\mathrm{KOH}+\mathrm{O}_2 \rightarrow \mathrm{A}+\mathrm{H}_2 \mathrm{O} \text {. }$$

Product '$$\mathrm{A}$$' in neutral or acidic medium disproportionate to give products '$$\mathrm{B}$$' and '$$\mathrm{C}$$' along with water. The sum of spin-only magnetic moment values of $$\mathrm{B}$$ and $$\mathrm{C}$$ is ________ BM. (nearest integer) (Given atomic number of $$\mathrm{Mn}$$ is 25)