To inhibit the growth of tumours, identify the compounds used from the following :

A. EDTA

B. Coordination Compounds of Pt

C. D - Penicillamine

D. Cis - Platin

Choose the correct answer from the option given below :

The major products 'A' and 'B', respectively, are

In the wet tests for identification of various cations by precipitation, which transition element cation doesn't belong to group IV in qualitative inorganic analysis?

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).

Assertion (A) : Ketoses give Seliwanoff's test faster than Aldoses.

Reason (R) : Ketoses undergo $$\beta$$-elimination followed by formation of furfural.

In the light of the above statements, choose the correct answer from the options given below :

What is the correct order of acidity of the protons marked $$\mathrm{A}-\mathrm{D}$$ in the given compounds ?

Which of the following is correct order of ligand field strength?

Which of the following compounds would give the following set of qualitative analysis ?

(i) Fehling's Test : Positive

(ii) Na fusion extract upon treatment with sodium nitroprusside gives a blood red colour but not prussian blue.

During the qualitative analysis of $$\mathrm{SO}_{3}^{2-}$$ using dilute $$\mathrm{H}_{2} \mathrm{SO}_{4}, \mathrm{SO}_{2}$$ gas is evolved which turns $$\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}$$ solution (acidified with dilute $$\mathrm{H}_{2} \mathrm{SO}_{4}$$) :

For $$\mathrm{OF}_{2}$$ molecule consider the following :

A. Number of lone pairs on oxygen is 2 .

B. FOF angle is less than $$104.5^{\circ}$$.

C. Oxidation state of $$\mathrm{O}$$ is $$-2$$.

D. Molecule is bent '$$\mathrm{V}$$' shaped.

E. Molecular geometry is linear.

correct options are:

Match List I with List II

	List I		List II
A.		I.	Fittig reaction
B.		II.	Wurtz Fittig reaction
C.		III.	Finkelstein reaction
D.	$$\mathrm{C_5H_5C1+NaI\to C_2H_5I+NaCl}$$	IV.	Sandemyer reaction

Choose the correct answer from the options given below :

Benzyl isocyanide can be obtained by :

A.

B.

C.

D.

Choose the correct answer from the options given below :

Match List I with List II

	List I (Atomic number)		List II (Block of periodic table)
A.	37	I.	p-block
B.	78	II.	d-block
C.	52	III.	f-block
D.	65	IV.	s-block

Choose the correct answer from the options given below :

Match List I with List II

	List I (molecules/ions)		List II (No. of lone pairs of e$$^-$$ on central atom)
A.	$$\mathrm{IF_7}$$	I.	Three
B.	$$\mathrm{ICl}$$$$_4^ - $$	II.	One
C.	$$\mathrm{XeF_6}$$	III.	Two
D.	$$\mathrm{XeF_2}$$	IV.	Zero

Choose the correct answer from the options given below :

Some amount of dichloromethane $$\left(\mathrm{CH}_{2} \mathrm{Cl}_{2}\right)$$ is added to $$671.141 \mathrm{~mL}$$ of chloroform $$\left(\mathrm{CHCl}_{3}\right)$$ to prepare $$2.6 \times 10^{-3} \mathrm{M}$$ solution of $$\mathrm{CH}_{2} \mathrm{Cl}_{2}(\mathrm{DCM})$$. The concentration of $$\mathrm{DCM}$$ is ___________ ppm (by mass).

Given :

atomic mass : C = 12

H = 1

Cl = 35.5

density of $$\mathrm{CHCl}_{3}=1.49 \mathrm{~g} \mathrm{~cm}^{-3}$$

If compound A reacts with B following first order kinetics with rate constant $$2.011 \times 10^{-3} \mathrm{~s}^{-1}$$. The time taken by $$\mathrm{A}$$ (in seconds) to reduce from $$7 \mathrm{~g}$$ to $$2 \mathrm{~g}$$ will be ___________. (Nearest Integer)

$$[\log 5=0.698, \log 7=0.845, \log 2=0.301]$$

$$600 \mathrm{~mL}$$ of $$0.01~\mathrm{M} ~\mathrm{HCl}$$ is mixed with $$400 \mathrm{~mL}$$ of $$0.01~\mathrm{M} ~\mathrm{H}_{2} \mathrm{SO}_{4}$$. The $$\mathrm{pH}$$ of the mixture is ___________ $$\times 10^{-2}$$. (Nearest integer)

[Given $$\log 2=0.30$$

$$\log 3=0.48$$

$$\log 5=0.69$$

$$\log 7=0.84$$

$$\log 11=1.04]$$

When 2 litre of ideal gas expands isothermally into vacuum to a total volume of 6 litre, the change in internal energy is ____________ J. (Nearest integer)

Consider the cell

$$\mathrm{Pt}_{(\mathrm{s})}\left|\mathrm{H}_{2}(\mathrm{~g}, 1 \mathrm{~atm})\right| \mathrm{H}^{+}(\mathrm{aq}, 1 \mathrm{M})|| \mathrm{Fe}^{3+}(\mathrm{aq}), \mathrm{Fe}^{2+}(\mathrm{aq}) \mid \operatorname{Pt}(\mathrm{s})$$

When the potential of the cell is $$0.712 \mathrm{~V}$$ at $$298 \mathrm{~K}$$, the ratio $$\left[\mathrm{Fe}^{2+}\right] /\left[\mathrm{Fe}^{3+}\right]$$ is _____________. (Nearest integer)

Given : $$\mathrm{Fe}^{3+}+\mathrm{e}^{-}=\mathrm{Fe}^{2+}, \mathrm{E}^{\theta} \mathrm{Fe}^{3+}, \mathrm{Fe}^{2+} \mid \mathrm{Pt}=0.771$$

$$ \frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.06 \mathrm{~V} $$

A trisubstituted compound '$$\mathrm{A}$$', $$\mathrm{C}_{10} \mathrm{H}_{12} \mathrm{O}_{2}$$ gives neutral $$\mathrm{FeCl}_{3}$$ test positive. Treatment of compound 'A' with $$\mathrm{NaOH}$$ and $$\mathrm{CH}_{3} \mathrm{Br}$$ gives $$\mathrm{C}_{11} \mathrm{H}_{14} \mathrm{O}_{2}$$, with hydroiodic acid gives methyl iodide and with hot conc. $$\mathrm{NaOH}$$ gives a compound $$\mathrm{B}, \mathrm{C}_{10} \mathrm{H}_{12} \mathrm{O}_{2}$$. Compound 'A' also decolorises alkaline $$\mathrm{KMnO}_{4}$$. The number of $$\pi$$ bond/s present in the compound '$$\mathrm{A}$$' is _____________.

The number of electrons involved in the reduction of permanganate to manganese dioxide in acidic medium is _____________.

A solution containing $$2 \mathrm{~g}$$ of a non-volatile solute in $$20 \mathrm{~g}$$ of water boils at $$373.52 \mathrm{~K}$$. The molecular mass of the solute is ___________ $$\mathrm{g} ~\mathrm{mol}^{-1}$$. (Nearest integer)

Given, water boils at $$373 \mathrm{~K}, \mathrm{~K}_{\mathrm{b}}$$ for water $$=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$

The energy of one mole of photons of radiation of frequency $$2 \times 10^{12} \mathrm{~Hz}$$ in $$\mathrm{J} ~\mathrm{mol}^{-1}$$ is ___________. (Nearest integer)

[Given : $$\mathrm{h}=6.626 \times 10^{-34} ~\mathrm{Js}$$

$$\mathrm{N}_{\mathrm{A}}=6.022 \times 10^{23} \mathrm{~mol}^{-1}$$]