JEE MAIN - Chemistry (2023 - 24th January Evening Shift)
1
The number of s-electrons present in an ion with 55 protons in its unipositive state is
Answer
(A)
10
2
Find out the major products from the following reactions.
Answer
(B)
3
What is the number of unpaired electron(s) in the highest occupied molecular orbital of the following species : $$\mathrm{{N_2};N_2^ + ;{O_2};O_2^ + }$$ ?
Answer
(C)
0, 1, 2, 1
4
Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R
Assertion A : Benzene is more stable than hypothetical cyclohexatriene
Reason R : The delocalised $$\pi$$ electron cloud is attracted more strongly by nuclei of carbon atoms.
In the light of the above statements, choose the correct answer from the options given below:
Answer
(B)
Both A and R are correct and R is the correct explanation of A
5
Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.
Answer
(C)
6
Given below are two statements :
In the light of the above statements, choose the correct answer from the options given below:
Answer
(C)
Statement I is true but Statement II is false
7
Choose the correct colour of the product for the following reaction.
Answer
(C)
Red
8
Which one amongst the following are good oxidizing agents?
A. Sm$$^{2+}$$
B. Ce$$^{2+}$$
C. Ce$$^{4+}$$
D. Tb$$^{4+}$$
Choose the most appropriate answer from the options given below :
Answer
(A)
C and D only
9
A student has studied the decomposition of a gas AB$$_3$$ at 25$$^\circ$$C. He obtained the following data.
p (mm Hg)
50
100
200
400
relative t$$_{1/2}$$ (s)
4
2
1
0.5
The order of the reaction is
Answer
(A)
2
10
The hybridization and magnetic behaviour of cobalt ion in $$\mathrm{[Co(NH_3)_6]^{3+}}$$ complex, respectively is :
Answer
(C)
$$\mathrm{d^2sp^3}$$ and diamagnetic
11
$$\mathrm{K_2Cr_2O_7}$$ paper acidified with dilute $$\mathrm{H_2SO_4}$$ turns green when exposed to :
Answer
(A)
Sulphur dioxide
12
Which will undergo deprotonation most readily in the basic medium?
Answer
(A)
a only
13
Which of the following cannot be explained by crystal field theory?
Answer
(A)
The order of spectrochemical series
14
Given below are two statements:
Statement I : Pure Aniline and other arylamines are usually colourless.
Statement II : Arylamines get coloured on storage due to atmospheric reduction.
In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(B)
Statement I is correct but Statement II is incorrect
15
Total number of tripeptides possible by mixing of valine and proline is ___________
Answer
8
16
One mole of an ideal monoatomic gas is subjected to changes as shown in the graph. The magnitude of the work done (by the system or on the system) is __________ J (nearest integer)
Given ; $$\log2=0.3$$
$$\ln10=2.3$$
Answer
620
17
Maximum number of isomeric monochloro derivatives which can be obtained from 2,2,5,5-tetramethylhexane by chlorination is _____________
Answer
3
18
Following figure shows spectrum of an ideal black body at four different temperatures. The number of correct statement/s from the following is ____________.
A. $$\mathrm{T_4 > T_3 > T_2 > T_1}$$
B. The black body consists of particles performing simple harmonic motion.
C. The peak of the spectrum shifts to shorter wavelength as temperature increases.
E. The given spectrum could be explained using quantisation of energy.
Answer
2
19
Sum of $$\pi$$-bonds present in peroxodisulphuric acid and pyrosulphuric acid is ___________
Answer
8
20
The number of units, which are used to express concentration of solutions from the following is _________
Mass percent, Mole, Mole fraction, Molarity, ppm, Molality
Answer
5
21
The total pressure observed by mixing two liquids A and B is 350 mm Hg when their mole fractions are 0.7 and 0.3 respectively.
The total pressure becomes 410 mm Hg if the mole fractions are changed to 0.2 and 0.8 respectively for A and B. The vapour pressure of pure A is __________ mm Hg. (Nearest integer)
Consider the liquids and solutions behave ideally.
Answer
314
22
If the pKa of lactic acid is 5, then the pH of 0.005 M calcium lactate solution at 25$$^\circ$$C is ___________ $$\times$$ 10$$^{-1}$$ (Nearest integer)