JEE MAIN - Chemistry (2023 - 24th January Evening Shift - No. 4)

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Benzene is more stable than hypothetical cyclohexatriene

Reason R : The delocalised $$\pi$$ electron cloud is attracted more strongly by nuclei of carbon atoms.

In the light of the above statements, choose the correct answer from the options given below:

A is true but R is false
Both A and R are correct and R is the correct explanation of A
Both A and R are correct but R is NOT the correct explanation of A
A is false but R is true

Explanation

Benzene is more stable than hypothetical cyclohexatriene due to the delocalization of electrons in the π electron cloud of the aromatic ring. This delocalization of electrons leads to a more stable electronic configuration in benzene, as the electrons are shared more evenly between all six carbon atoms in the ring. This is in agreement with Assertion A.

Reason R is also correct, as the delocalized π electron cloud in the aromatic ring is attracted more strongly by the nuclei of the carbon atoms. This is due to the fact that the π electrons in the ring are more spread out and are not localized to a single atom, which makes them more attracted to the positively charged nuclei of the carbon atoms. This explanation supports Assertion A.

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