In which of the following processes, the bond order increases and paramagnetic character changes to diamagnetic one ?

Which of the following statements are not correct?

A. The electron gain enthalpy of $$\mathrm{F}$$ is more negative than that of $$\mathrm{Cl}$$.

B. Ionization enthalpy decreases in a group of periodic table.

C. The electronegativity of an atom depends upon the atoms bonded to it.

D. $$\mathrm{Al}_{2} \mathrm{O}_{3}$$ and $$\mathrm{NO}$$ are examples of amphoteric oxides.

Choose the most appropriate answer from the options given below :

In the following reaction 'X' is

In the reaction given below

'A' is

The mismatched combinations are

A. Chlorophyll - Co

B. Water hardness - EDTA

C. Photography $$-\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]^{-}$$

D. Wilkinson catalyst $$-\left[\left(\mathrm{Ph}_{3} \mathrm{P}\right)_{3} \mathrm{RhCl}\right]$$

E. Chelating ligand - D-Penicillamine

Choose the correct answer from the options given below :

$$\mathrm{ClF}_{5}$$ at room temperature is a:

Among the following compounds, the one which shows highest dipole moment is

2-Methyl propyl bromide reacts with $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{O}^{-}$$ and gives 'A' whereas on reaction with $$\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}$$ it gives 'B'. The mechanism followed in these reactions and the products 'A' and 'B' respectively are :

The pair of lanthanides in which both elements have high third - ionization energy is :

In the reaction given below

'B' is

In the above reaction, left hand side and right hand side rings are named as '$$\mathrm{A}$$' and 'B' respectively. They undergo ring expansion. The correct statement for this process is:

The products formed in the above reaction are

The energy of an electron in the first Bohr orbit of hydrogen atom is $$-2.18 \times 10^{-18} \mathrm{~J}$$. Its energy in the third Bohr orbit is ____________.

$$\mathrm{KMnO}_{4}$$ is titrated with ferrous ammonium sulphate hexahydrate in presence of dilute $$\mathrm{H}_{2} \mathrm{SO}_{4}$$. Number of water molecules produced for 2 molecules of $$\mathrm{KMnO}_{4}$$ is ___________.

An organic compound gives $$0.220 \mathrm{~g}$$ of $$\mathrm{CO}_{2}$$ and $$0.126 \mathrm{~g}$$ of $$\mathrm{H}_{2} \mathrm{O}$$ on complete combustion. If the $$\%$$ of carbon is 24 then the $$\%$$ of hydrogen is __________ $$\times 10^{-1}$$. ( Nearest integer)

$$\mathrm{t}_{87.5}$$ is the time required for the reaction to undergo $$87.5 \%$$ completion and $$\mathrm{t}_{50}$$ is the time required for the reaction to undergo $$50 \%$$ completion. The relation between $$\mathrm{t}_{87.5}$$ and $$\mathrm{t}_{50}$$ for a first order reaction is $$\mathrm{t}_{87.5}=x \times \mathrm{t}_{50}$$ The value of $$x$$ is ___________. (Nearest integer)

For the given reaction

The total number of possible products formed by tertiary carbocation of A is ____________.

$$20 \mathrm{~mL}$$ of calcium hydroxide was consumed when it was reacted with $$10 \mathrm{~mL}$$ of unknown solution of $$\mathrm{H}_{2} \mathrm{SO}_{4}$$. Also $$20 \mathrm{~mL}$$ standard solution of $$0.5 ~\mathrm{M} ~\mathrm{HCl}$$ containing 2 drops of phenolphthalein was titrated with calcium hydroxide, the mixture showed pink colour when burette displayed the value of $$35.5 \mathrm{~mL}$$ whereas the burette showed $$25.5 \mathrm{~mL}$$ initially. The concentration of $$\mathrm{H}_{2} \mathrm{SO}_{4}$$ is _____________ M. (Nearest integer)

Solution of $$12 \mathrm{~g}$$ of non-electrolyte (A) prepared by dissolving it in $$1000 \mathrm{~mL}$$ of water exerts the same osmotic pressure as that of $$0.05 ~\mathrm{M}$$ glucose solution at the same temperature. The empirical formula of $$\mathrm{A}$$ is $$\mathrm{CH}_{2} \mathrm{O}$$. The molecular mass of $$\mathrm{A}$$ is __________ g. (Nearest integer)

A metal surface of $$100 \mathrm{~cm}^{2}$$ area has to be coated with nickel layer of thickness $$0.001 \mathrm{~mm}$$. A current of $$2 \mathrm{~A}$$ was passed through a solution of $$\mathrm{Ni}\left(\mathrm{NO}_{3}\right)_{2}$$ for '$$\mathrm{x}$$' seconds to coat the desired layer. The value of $$\mathrm{x}$$ is __________. (Nearest integer) ( $$\rho_{\mathrm{Ni}}$$ (density of Nickel) is $$10 \mathrm{~g} \mathrm{~mL}$$, Molar mass of Nickel is $$60 \mathrm{~g} \mathrm{~mol}^{-1}$$ $$\left.\mathrm{F}=96500 ~\mathrm{C} ~\mathrm{mol}^{-1}\right)$$

$$\mathrm{A}_{2}+\mathrm{B}_{2} \rightarrow 2 \mathrm{AB} . \Delta H_{f}^{0}=-200 \mathrm{~kJ} \mathrm{~mol}^{-1}$$

$$\mathrm{AB}, \mathrm{A}_{2}$$ and $$\mathrm{B}_{2}$$ are diatomic molecules. If the bond enthalpies of $$\mathrm{A}_{2}, \mathrm{~B}_{2}$$ and $$\mathrm{AB}$$ are in the ratio $$1: 0.5: 1$$, then the bond enthalpy of $$\mathrm{A}_{2}$$ is ____________ $$\mathrm{kJ} ~\mathrm{mol}^{-1}$$ (Nearest integer)

$$25.0 \mathrm{~mL}$$ of $$0.050 ~\mathrm{M} ~\mathrm{Ba}\left(\mathrm{NO}_{3}\right)_{2}$$ is mixed with $$25.0 \mathrm{~mL}$$ of $$0.020 ~\mathrm{M} ~\mathrm{NaF} . \mathrm{K}_{\mathrm{Sp}}$$ of $$\mathrm{BaF}_{2}$$ is $$0.5 \times 10^{-6}$$ at $$298 \mathrm{~K}$$. The ratio of $$\left[\mathrm{Ba}^{2+}\right]\left[\mathrm{F}^{-}\right]^{2}$$ and $$\mathrm{K}_{\mathrm{sp}}$$ is ___________.

(Nearest integer)