$$\mathrm{SO}_{2} \mathrm{Cl}_{2}$$ on reaction with excess of water results into acidic mixture

$$\mathrm{SO}_{2} \mathrm{Cl}_{2}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{H}_{2} \mathrm{SO}_{4}+2 \mathrm{HCl}$$

16 moles of $$\mathrm{NaOH}$$ is required for the complete neutralisation of the resultant acidic mixture. The number of moles of $$\mathrm{SO}_{2} \mathrm{Cl}_{2}$$ used is :

Which of the following sets of quantum numbers is not allowed?

The depression in freezing point observed for a formic acid solution of concentration $$0.5 \mathrm{~mL} \mathrm{~L}^{-1}$$ is $$0.0405^{\circ} \mathrm{C}$$. Density of formic acid is $$1.05 \mathrm{~g} \mathrm{~mL}^{-1}$$. The Van't Hoff factor of the formic acid solution is nearly : (Given for water $$\mathrm{k}_{\mathrm{f}}=1.86\, \mathrm{k} \,\mathrm{kg}\,\mathrm{mol}^{-1}$$ )

$$20 \mathrm{~mL}$$ of $$0.1\, \mathrm{M} \,\mathrm{NH}_{4} \mathrm{OH}$$ is mixed with $$40 \mathrm{~mL}$$ of $$0.05 \mathrm{M} \mathrm{HCl}$$. The $$\mathrm{pH}$$ of the mixture is nearest to :

(Given : $$\mathrm{K}_{\mathrm{b}}\left(\mathrm{NH}_{4} \mathrm{OH}\right)=1 \times 10^{-5}, \log 2=0.30, \log 3=0.48, \log 5=0.69, \log 7=0.84, \log 11= 1.04)$$

The IUPAC nomenclature of an element with electronic configuration [Rn] $$5 \mathrm{f}^{14} 6 \mathrm{d}^{1} 7 \mathrm{s}^{2}$$ is :

A compound ‘$$\mathrm{A}$$’ on reaction with ‘$$\mathrm{X}$$’ and ‘$$\mathrm{Y}$$’ produces the same major product but different by product '$$a$$' and '$$b^{\prime}$$. Oxidation of '$$a$$' gives a substance produced by ants.

'X' and 'Y' respectively are

Most stable product of the following reaction is:

Which one of the following reactions does not represent correct combination of substrate and product under the given conditions?

An organic compound 'A' on reaction with NH₃ followed by heating gives compound B. Which on further strong heating gives compound C (C₈H₅NO₂). Compound C on sequential reaction with ethanolic KOH, alkyl chloride and hydrolysis with alkali gives a primary amine. The compound A is :

During the denaturation of proteins, which of these structures will remain intact?

Given below are two statements :

Statement I : On heating with $$\mathrm{KHSO}_{4}$$, glycerol is dehydrated and acrolein is formed.

Statement II : Acrolein has fruity odour and can be used to test glycerol's presence.

Choose the correct option.

Among the following species

$$\mathrm{N}_{2}, \mathrm{~N}_{2}^{+}, \mathrm{N}_{2}^{-}, \mathrm{N}_{2}^{2-}, \mathrm{O}_{2}, \mathrm{O}_{2}^{+}, \mathrm{O}_{2}^{-}, \mathrm{O}_{2}^{2-}$$

the number of species showing diamagnesim is _______________.

The enthalpy of combustion of propane, graphite and dihydrogen at $$298 \mathrm{~K}$$ are $$-2220.0 \mathrm{~kJ} \mathrm{~mol}^{-1},-393.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and $$-285.8 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ respectively. The magnitude of enthalpy of formation of propane $$\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)$$ is _______________ $$\mathrm{kJ} \,\mathrm{mol}^{-1}$$. (Nearest integer)

The cell potential for $$\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{aq})\right|\left|\mathrm{Sn}^{x+}\right| \mathrm{Sn}$$ is $$0.801 \mathrm{~V}$$ at $$298 \mathrm{~K}$$. The reaction quotient for the above reaction is $$10^{-2}$$. The number of electrons involved in the given electrochemical cell reaction is ____________.

$$\left(\right.$$ Given $$: \mathrm{E}_{\mathrm{Zn}^{2+} \mid \mathrm{Zn}}^{\mathrm{o}}=-0.763 \mathrm{~V}, \mathrm{E}_{\mathrm{Sn}^{x+} \mid \mathrm{Sn}}^{\mathrm{o}}=+0.008 \mathrm{~V}$$ and $$\left.\frac{2.303 \mathrm{RT}}{\mathrm{F}}=0.06 \mathrm{~V}\right)$$

The half life for the decomposition of gaseous compound $$\mathrm{A}$$ is $$240 \mathrm{~s}$$ when the gaseous pressure was 500 Torr initially. When the pressure was 250 Torr, the half life was found to be $$4.0$$ min. The order of the reaction is ______________. (Nearest integer)

Consider the following metal complexes :

$$\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}$$

$$\left[\mathrm{CoCl}\left(\mathrm{NH}_{3}\right)_{5}\right]^{2+}$$

$$\left[\mathrm{Co}(\mathrm{CN})_{6}\right]^{3-}$$

$$\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{5}\left(\mathrm{H}_{2} \mathrm{O}\right)\right]^{3+}$$

The spin-only magnetic moment value of the complex that absorbes light with shortest wavelength is _____________ B. M. (Nearest integer)

Among Co³⁺, Ti²⁺, V²⁺ and Cr²⁺ ions, one if used as a reagent cannot liberate H₂ from dilute mineral acid solution, its spin-only magnetic moment in gaseous state is ___________ B.M. (Nearest integer)

While estimating the nitrogen present in an organic compound by Kjeldahl's method, the ammonia evolved from $$0.25 \mathrm{~g}$$ of the compound neutralized $$2.5 \mathrm{~mL}$$ of $$2 \,\mathrm{M} \,\mathrm{H}_{2} \mathrm{SO}_{4}$$. The percentage of nitrogen present in organic compound is ______________.

The number of sp³ hybridised carbons in an acyclic neutral compound with molecular formula C₄H₅N is ___________.

In the given reaction

The number of chiral carbon/s in product A is ___________.