JEE MAIN - Chemistry (2019 - 12th January Evening Slot)
1
The magnetic moment of an octahedral homoleptic Mn(II) complex is 5.9 BM. The suitable ligand for this complex is -
Answer
(C)
NCS–
2
The major product of the following reaction is –
Answer
(A)
3
The correct statement (s) among I to III with respect to potassium ions that are abundant within the cell fluid
is /are
I. They activate many enzymes
II. They participate in the oxidation of glucose to produce ATP
III. Along with sodium ions they are responsible for the transmission of nerve signals
Answer
(D)
I, II and III only
4
The major product of the following reaction is –
Answer
(C)
5
The correct order of atomic radii is :
Answer
(D)
Eu > Ce > Ho > N
6
The major product of the following reaction is :
Answer
(A)
CH3CH2C$$ \equiv $$CH
7
The element that shows greater ability to form p$$\pi $$-p$$\pi $$ multiple bonds, is :
Answer
(C)
C
8
The correct structure of histidine in a strongly acidic solution (pH = 2) is -
Answer
(B)
9
If Ksp of Ag2CO3 is 8 $$ \times $$ 10–12, the molar solubility of Ag2CO3 in 0.1 M AgNO3 is -
Answer
(B)
8 $$ \times $$ 10–10 M
10
For a reaction consider the plot of $$\ell $$n k versus 1/T given in the figure. If the rate constant of this reaction at 400 K is 10–5 s–1, then the rate constant at 500 K is –
Answer
(A)
10$$-$$4 s$$-$$1
11
The increasing order of the reactivity of the following with LiAlH4 is
Answer
(D)
A < B < D < C
12
8 g of NaOH is dissolved in 18g of H2O. Mole fraction of NaOH in solution and molality (in mol kg–1) of the solution respectively are -
Answer
(C)
0.167, 11.11
13
The upper stratosphere consisting of the ozone layer protects us from sun's radiation that falls in the wavelength region of -
Answer
(A)
200-315 nm
14
Given
(i) C (graphite) + O2(g) $$ \to $$ CO2(g); $$\Delta $$rH$$^\Theta $$ = x kJ mol$$-$$1
(ii) C(graphite) + $${1 \over 2}$$O2(g) $$ \to $$ CO(g); $$\Delta $$rH$$^\Theta $$ = y kJ mol$$-$$1
Based on the above thermochemical equations, find out which one of the following algebraic relationships is correct?
Answer
(B)
x = y + z
15
If the de Broglie wavelength of the electron in nth Bohr orbit in a hydrogenic atom is equal to 1.5 $$\pi $$a0 (a0 is Bohr radius), then the value of n/z is -
Answer
(A)
0.75
16
The aldehydes which will not form Grignard product with one equivalent Grignard reagents are -
Answer
(A)
B and D
17
The element that does NOT show catenation is :
Answer
(D)
Pb
18
Molecules of benzoic acid (C6H5COOH) dimerise in benzene. 'w' g of the acid dissolved in 30 g of benzene shows a depression in freezing point equal to 2K. If the percentage association of the acid to form dimmer in the solution is 80, then w is – (Its given that Kf = 5 K kg mol–1, Molar mass of benzoic acid = 122 g mol–1)
Answer
(D)
2.4 g
19
The combination of plots which does not represent isothermal expansion of an ideal gas is –
Answer
(B)
B and D
20
The major product of the following reaction is –
Answer
(A)
21
The major product in the following conversion is –
Answer
(D)
22
The major product of the following reaction is –
Answer
(B)
23
$$ \wedge _m^ \circ $$ for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm2 mol–1, respectively. If the conductivity of 0.001 M HA is-
5 $$ \times $$ 10–5 S cm–1, degree of dissociation of HA is -