JEE MAIN - Chemistry (2019 - 12th January Evening Slot - No. 16)
The aldehydes which will not form Grignard product with one equivalent Grignard reagents are -
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B and D
C and D
B, C and D
B and C
Explanation
Grignard product is that product which forms because of nucleophilic addition reaction.
Aldehydes on reaction with Grignard reagent gives Grignard product.
In Grignard reagent R$$-$$ is a very strong base, so it will react with acidic H+ of $$-$$COOH group first. As Grignard reagent is one equivalent, so no reagent will remain to react with aldehyde group.
Here also in alcohol functional group ($$-$$CH2OH) H+ is acidic so here acid base reaction will occur.
In option (A) only one functional group ($$-$$ CHO) present so it will give Grignard product by nucleofilic addition reaction.
In option (C) functional group ether ($$-$$ CH3) does not react with RMgX so aldehyde functional group will react with RMgX and give Grignard product.
_12th_January_Evening_Slot_en_16_4.png)
Aldehydes on reaction with Grignard reagent gives Grignard product.
_12th_January_Evening_Slot_en_16_2.png)
In Grignard reagent R$$-$$ is a very strong base, so it will react with acidic H+ of $$-$$COOH group first. As Grignard reagent is one equivalent, so no reagent will remain to react with aldehyde group.
_12th_January_Evening_Slot_en_16_3.png)
Here also in alcohol functional group ($$-$$CH2OH) H+ is acidic so here acid base reaction will occur.
In option (A) only one functional group ($$-$$ CHO) present so it will give Grignard product by nucleofilic addition reaction.
In option (C) functional group ether ($$-$$ CH3) does not react with RMgX so aldehyde functional group will react with RMgX and give Grignard product.
_12th_January_Evening_Slot_en_16_4.png)
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