JEE MAIN - Chemistry (2019 - 12th January Evening Slot - No. 23)

$$ \wedge _m^ \circ $$ for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm2 mol–1, respectively. If the conductivity of 0.001 M HA is-

5 $$ \times $$ 10–5 S cm–1, degree of dissociation of HA is -
0.50
0.125
0.25
0.75

Explanation

$$ \wedge _m^ \circ $$ (HA) = $$ \wedge _m^ \circ $$ (HCl) + $$ \wedge _m^ \circ $$ (NaA) $$-$$ $$ \wedge _m^ \circ $$ (NaCl)

= 425.9 + 100.5 $$-$$ 126.4

= 400 S cm2 . mol$$-$$1

    $$ \wedge _m^ c $$ = $${{K \times 1000} \over M}$$

= $${{5 \times {{10}^{ - 5}} \times 1000} \over {{{10}^{ - 3}}}}$$

= 50 S cm2 mol$$-$$1

$$\alpha $$ = $${{\Lambda _m^c} \over {\Lambda _m^o}}$$ = $${{50} \over {400}}$$ = 0.125

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