JEE MAIN - Chemistry (2014 (Offline))

1
Resistance of 0.2 M solution of an electrolyte is 50 $$\Omega$$. The specific conductance of the solution is 1.4 S m-1. The resistance of 0.5 M solution of the same electrolyte is 280 $$\Omega$$. The molar conductivity of 0.5 M solution of the electrolyte in S m2 mol-1 is :
Answer
(C)
5 × 10-4
2
Consider separate solutions of 0.500 M C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250 M KBr(aq) and 0.125 M Na3PO4(aq) at 25oC. Which statement is true about these solutions, assuming all salts to be strong electrolytes?
Answer
(C)
They all have the same osmotic pressure
3
For the estimation of nitrogen, 1.4 g of organic compound was digested by Kjeldahl method and the evolved ammonia was absorbed in 60 mL of M/10 sulphuric acid. The unreacted acid required 20 ml of M/10 sodium hydroxide for complete neutralization. The percentage of nitrogen in the compound is:
Answer
(D)
10%
4
In which of the following reactions H2O2 acts as a reducing agent?
1. H2O2 + 2H+ + 2e- $$\to$$ 2H2O
2. H2O2 - 2e- $$\to$$ O2 + 2H+
3. H2O2 + 2e- $$\to$$ 2OH-
4. H2O2 + 2OH- - 2e- $$\to$$ O2 + 2H2O
Answer
(D)
2, 4
5
For the reaction SO2 (g) + $${1 \over 2} O_2(g) \leftrightharpoons$$ SO3(g).
if KP = KC(RT)x where the symbols have usual meaning then the value of x is: (assuming ideality)
Answer
(B)
-1/2
6
For complete combustion of ethanol, C2H5OH(l) + 3O2(g) $$\to$$ 2CO2(g) + 3H2O(l) the amount of heat produced as measured in bomb calorimeter, is 1364.47 kJ mol–1 at 25oC. Assuming ideality the Enthalpy of combustion, $$\Delta _CH$$, for the reaction will be : (R = 8.314 kJ mol–1)
Answer
(C)
– 1366.95 kJ mol–1
7
Given below are the half-cell reactions:

Mn2+ + 2e- $$\to$$ Mn; Eo = -1.18 V

2(Mn3+ + e- $$\to$$ Mn2+); Eo = +1.51 V

The Eo for 3Mn2+ $$\to$$ Mn + 2Mn3+ will be :
Answer
(C)
– 2.69 V; the reaction will not occur
8
The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 : 4. The ratio of number of their molecule is:
Answer
(D)
7 : 32
9
The major organic compound formed by the reaction of 1, 1, 1– trichloroethane with silver powder is:
Answer
(A)
2- Butyne
10
Sodium phenoxide when heated with $$C{O_2}$$ under pressure at $${125^ \circ }C$$ yields a product which on acetylation products $$C.$$

JEE Main 2014 (Offline) Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 215 English

The major product $$C$$ would be
Answer
(A)
JEE Main 2014 (Offline) Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 215 English Option 1
11
Which one of the following bases is not present in DNA?
Answer
(C)
Quinoline
12
Considering the basic strength of amines in aqueous solution, which one has the smallest pKb value?
Answer
(C)
(CH3)2NH
13
On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is:
Answer
(B)
an alkyl isocyanide
14
The most suitable reagent for the conversion of R - CH2 - OH $$\to$$ R - CHO is:
Answer
(B)
PCC (Pyridinium Chlorochromate)
15
In the reaction,
JEE Main 2014 (Offline) Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 221 English
the product C is:
Answer
(A)
Ethylene
16
In SN2 reactions, the correct order of reactivity for the following compounds:
CH3Cl, CH3CH 2Cl, (CH3)2CHCl and (CH3)3CCl is:
Answer
(D)
CH3Cl > CH3CH2Cl > (CH3)2CHCl > (CH3)3CCl
17
The equation which is balanced and represents the correct product(s) is :
Answer
(D)
[CoCl(NH3)5]+ + 5H+ $$\to$$ Co2+ + $$5NH_4^+$$ + Cl-
18
The octahedral complex of a metal ion M3+ with four monodentate ligands L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the four ligands is :
Answer
(D)
L1 < L3 < L2 < L4
19
Which series of reactions correctly represents chemical relations related to iron and its compound?
Answer
(D)
Fe $$\buildrel {{O_2},\,heat} \over \longrightarrow $$ Fe3O4 $$\buildrel {CO,\,{{600}^o}C} \over \longrightarrow $$ FeO $$\buildrel {CO,\,{{700}^o}C} \over \longrightarrow $$ Fe
20
The correct statement for the molecule, CsI3 is :
Answer
(D)
it contains Cs+ and $$I_3^-$$ ions
21
Which one of the following properties is not shown by NO?
Answer
(C)
It is diamagnetic in gaseous state
22
For the non – stoichiometre reaction 2A + B $$\to$$ C + D, the following kinetic data were obtained in three separate experiments, all at 298 K.
Initial Concentration (A) Initial Concentration (B) Initial rate of formation of C (mol L-1 s-1)
0.1 M 0.1 M 1.2 x 10-3
0.1 M 0.2 M 1.2 x 10-3
0.2 M 0.1 M 2.4 x 10-3
The rate law for the formation of C is:
Answer
(B)
$${{dc} \over {dt}} = k[A]$$
23
The equivalent conductance of NaCl at concentration C and at infinite dilution are $${\lambda _C}$$ and $${\lambda _\infty }$$, respectively. The correct relationship between $${\lambda _C}$$ and $${\lambda _\infty }$$ is given as: (where the constant B is positive)
Answer
(C)
$${\lambda _C} = {\lambda _\infty } - (B)\sqrt C$$
24
The correct set of four quantum numbers for the valence elections of rubidium atom (Z= 37) is:
Answer
(C)
5, 0, 0, + 1/2