Combustion of glucose $$(\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6)$$ produces $$\mathrm{CO}_2$$ and water. The amount of oxygen (in $$\mathrm{g}$$) required for the complete combustion of $$900 \mathrm{~g}$$ of glucose is :

[Molar mass of glucose in $$\mathrm{g} \mathrm{~mol}^{-1}=180$$]

Thiosulphate reacts differently with iodine and bromine in the reactions given below:

$$\begin{aligned} & 2 \mathrm{~S}_2 \mathrm{O}_3^{2-}+\mathrm{I}_2 \rightarrow \mathrm{S}_4 \mathrm{O}_6^{2-}+2 \mathrm{I}^{-} \\ & \mathrm{S}_2 \mathrm{O}_3^{2-}+5 \mathrm{Br}_2+5 \mathrm{H}_2 \mathrm{O} \rightarrow 2 \mathrm{SO}_4^{2-}+4 \mathrm{Br}^{-}+10 \mathrm{H}^{+} \end{aligned}$$

Which of the following statement justifies the above dual behaviour of thiosulphate?

Give below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: The stability order of +1 oxidation state of $$\mathrm{Ga}$$, In and $$\mathrm{Tl}$$ is Ga < In < Tl.

Reason R: The inert pair effect stabilizes the lower oxidation state down the group.

In the light of the above statements, choose the correct answer from the options given below:

Iron (III) catalyses the reaction between iodide and persulphate ions, in which

A. $$\mathrm{Fe}^{3+}$$ oxidises the iodide ion

B. $$\mathrm{Fe}^{3+}$$ oxidises the persulphate ion

C. $$\mathrm{Fe}^{2+}$$ reduces the iodide ion

D. $$\mathrm{Fe}^{2+}$$ reduces the persulphate ion

Choose the most appropriate answer from the options given below:

Which of the following are aromatic?

Among the following halogens

$$\mathrm{F}_2, \mathrm{Cl}_2, \mathrm{Br}_2 \text { and } \mathrm{I}_2$$

Which can undergo disproportionation reactions?

Which among the following compounds will undergo fastest S_N2 reaction.

Match List I with List II

	LIST I (Molecule)		LIST II (Shape)
A.	$$\mathrm{NH_3}$$	I.	Square pyramid
B.	$$\mathrm{BrF_5}$$	II.	Tetrahedral
C.	$$\mathrm{PCl_5}$$	III.	Trigonal pyramidal
D.	$$\mathrm{CH_4}$$	IV.	Trigonal bipyramidal

Choose the correct answer from the options given below:

Match List I with List II

	LIST I (Elements)		LIST II (Properties in their respective groups)
A.	$$\mathrm{Cl,S}$$	I.	Elements with highest electronegativity
B.	$$\mathrm{Ge,As}$$	II.	Elements with largest atomic size
C.	$$\mathrm{Fr,Ra}$$	III.	Elements which show properties of both metals and non-metal
D.	$$\mathrm{F,O}$$	IV.	Elements with highest negative electron gain enthalpy

Choose the correct answer from the options given below:

Match List I with List II

	LIST I (Name of the test)		LIST II (Reaction sequence involved) [M is metal]
A.	Borax bead test	I.	$$\mathrm{MCO}_3 \rightarrow \mathrm{MO} \xrightarrow[+\Delta]{\mathrm{Co}\left(\mathrm{NO}_3\right)_2} \mathrm{CoO} \cdot \mathrm{MO}$$
B.	Charcoal cavity test	II.	$$\mathrm{MCO}_3 \rightarrow \mathrm{MCl}_2 \rightarrow \mathrm{M}^{2+}$$
C.	Cobalt nitrate test	III.	$$\mathrm{MSO}_4 \xrightarrow[\Delta]{\mathrm{Na}_2 \mathrm{~B}_4 \mathrm{O}_7} \mathrm{M}\left(\mathrm{BO}_2\right)_2 \rightarrow \mathrm{MBO}_2 \rightarrow \mathrm{M}$$
D.	Flame test	IV.	$$\mathrm{MSO}_4 \xrightarrow[\Delta]{\mathrm{Na}_2 \mathrm{CO}_3} \mathrm{MCO}_3 \rightarrow \mathrm{MO} \rightarrow \mathrm{M}$$

Choose the correct answer from the options given below:

Number of Complexes with even number of electrons in $$\mathrm{t_{2 g}}$$ orbitals is -

$$\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+},\left[\mathrm{Cu}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+},\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$

For the given hypothetical reactions, the equilibrium constants are as follows :

$$\begin{aligned} & \mathrm{X} \rightleftharpoons \mathrm{Y} ; \mathrm{K}_1=1.0 \\ & \mathrm{Y} \rightleftharpoons \mathrm{Z} ; \mathrm{K}_2=2.0 \\ & \mathrm{Z} \rightleftharpoons \mathrm{W} ; \mathrm{K}_3=4.0 \end{aligned}$$

The equilibrium constant for the reaction $$\mathrm{X} \rightleftharpoons \mathrm{W}$$ is

An octahedral complex with the formula $$\mathrm{CoCl}_3 \cdot \mathrm{nNH}_3$$ upon reaction with excess of $$\mathrm{AgNO}_3$$ solution gives 2 moles of $$\mathrm{AgCl}$$. Consider the oxidation state of $$\mathrm{Co}$$ in the complex is '$$x$$'. The value of "$$x+n$$" is __________.

In the given compound, the number of 2$$^\circ$$ carbon atom/s is ________.

Identify the major products A and B respectively in the following set of reactions.

Identify the product (P) in the following reaction:

Given below are two statements :

In the light of the above statements, choose the most appropriate answer from the options given below:

Given below are two statements:

Statement I: $$\mathrm{N}\left(\mathrm{CH}_3\right)_3$$ and $$\mathrm{P}\left(\mathrm{CH}_3\right)_3$$ can act as ligands to form transition metal complexes.

Statement II: As N and P are from same group, the nature of bonding of $$\mathrm{N}\left(\mathrm{CH}_3\right)_3$$ and $$\mathrm{P}\left(\mathrm{CH}_3\right)_3$$ is always same with transition metals.

In the light of the above statements, choose the most appropriate answer from the options given below:

The incorrect statement regarding the given structure is

Match List I with List II

	LIST I (Compound)		LIST II (Colour]
A.	$$\mathrm{Fe}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]_3 \cdot \mathrm{xH_2O}$$	I.	Violet
B.	$$\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]^{4-}$$	II.	Blood Red
C.	$$[\mathrm{Fe}(\mathrm{SCN})]^{2+}$$	III.	Prussian Blue
D.	$$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4\cdot12 \mathrm{MoO}_3$$	IV.	Yellow

Choose the correct answer from the options given below:

If $$279 \mathrm{~g}$$ of aniline is reacted with one equivalent of benzenediazonium chloride, the maximum amount of aniline yellow formed will be ________ g. (nearest integer)

(consider complete conversion).

Consider the following reaction

$$\mathrm{A}+\mathrm{B} \rightarrow \mathrm{C}$$

The time taken for A to become $$1 / 4^{\text {th }}$$ of its initial concentration is twice the time taken to become $$1 / 2$$ of the same. Also, when the change of concentration of B is plotted against time, the resulting graph gives a straight line with a negative slope and a positive intercept on the concentration axis.

The overall order of the reaction is ________.

Major product B of the following reaction has ________ $$\pi$$-bond.

A hypothetical electromagnetic wave is show below.

The frequency of the wave is $$\mathrm{x} \times 10^{19} \mathrm{~Hz}$$.

$$\mathrm{x}=$$ _________ (nearest integer)

Consider the figure provided.

$$1 \mathrm{~mol}$$ of an ideal gas is kept in a cylinder, fitted with a piston, at the position A, at $$18^{\circ} \mathrm{C}$$. If the piston is moved to position $$\mathrm{B}$$, keeping the temperature unchanged, then '$$\mathrm{x}$$' $$\mathrm{L}$$ atm work is done in this reversible process.

$$\mathrm{x}=$$ ________ $$\mathrm{L}$$ atm. (nearest integer)

[Given : Absolute temperature $$={ }^{\circ} \mathrm{C}+273.15, \mathrm{R}=0.08206 \mathrm{~L} \mathrm{~atm} \mathrm{~mol}{ }^{-1} \mathrm{~K}^{-1}$$]

A solution containing $$10 \mathrm{~g}$$ of an electrolyte $$\mathrm{AB}_2$$ in $$100 \mathrm{~g}$$ of water boils at $$100.52^{\circ} \mathrm{C}$$. The degree of ionization of the electrolyte $$(\alpha)$$ is _________ $$\times 10^{-1}$$. (nearest integer)

[Given : Molar mass of $$\mathrm{AB}_2=200 \mathrm{~g} \mathrm{~mol}^{-1}, \mathrm{~K}_{\mathrm{b}}$$ (molal boiling point elevation const. of water) $$=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$, boiling point of water $$=100^{\circ} \mathrm{C} ; \mathrm{AB}_2$$ ionises as $$\mathrm{AB}_2 \rightarrow \mathrm{A}^{2+}+2 \mathrm{~B}^{-}]$$

Number of molecules from the following which are exceptions to octet rule is _________.

$$\mathrm{CO}_2, \mathrm{NO}_2, \mathrm{H}_2 \mathrm{SO}_4, \mathrm{BF}_3, \mathrm{CH}_4, \mathrm{SiF}_4, \mathrm{ClO}_2, \mathrm{PCl}_5, \mathrm{BeF}_2, \mathrm{C}_2 \mathrm{H}_6, \mathrm{CHCl}_3, \mathrm{CBr}_4$$

The number of optical isomers in following compound is : __________.

The 'spin only' magnetic moment value of $$\mathrm{MO}_4{ }^{2-}$$ is ________ BM. (Where M is a metal having least metallic radii. among $$\mathrm{Sc}, \mathrm{Ti}, \mathrm{V}, \mathrm{Cr}, \mathrm{Mn}$$ and $$\mathrm{Zn}$$ ).

(Given atomic number: $$\mathrm{Sc}=21, \mathrm{Ti}=22, \mathrm{~V}=23, \mathrm{Cr}=24, \mathrm{Mn}=25$$ and $$\mathrm{Zn}=30$$)

Number of amine compounds from the following giving solids which are soluble in $$\mathrm{NaOH}$$ upon reaction with Hinsberg's reagent is _________.