Given below are two statements :

Statement I : The decrease in first ionization enthalpy from B to Al is much larger than that from Al to Ga.

Statement II : The d orbitals in Ga are completely filled.

In the light of the above statements, choose the most appropriate answer from the options given below

Given below are two statements :

Statement I : Nickel is being used as the catalyst for producing syn gas and edible fats.

Statement II : Silicon forms both electron rich and electron deficient hydrides.

In the light of the above statements, choose the most appropriate answer from the options given below :

Which of the following relations are correct?

(A) $$\mathrm{\Delta U=q+p\Delta V}$$

(B) $$\mathrm{\Delta G=\Delta H-T\Delta S}$$

(C) $$\Delta \mathrm{S}=\frac{q_{rev}}{T}$$

(D) $$\mathrm{\Delta H=\Delta U-\Delta nRT}$$

Choose the most appropriate answer from the options given below :

A solution of $$\mathrm{Cr O_5}$$ in amyl alcohol has a __________ colour.

According to MO theory the bond orders for $$\mathrm{O}$$$$_2^{2 - }$$, $$\mathrm{CO}$$ and $$\mathrm{NO^+}$$ respectively, are

When a hydrocarbon A undergoes combustion in the presence of air, it requires 9.5 equivalents of oxygen and produces 3 equivalents of water. What is the molecular formula of A?

The set of correct statements is :

(i) Manganese exhibits +7 oxidation state in its oxide.

(ii) Ruthenium and Osmium exhibit +8 oxidation in their oxides.

(iii) Sc shows +4 oxidation state which is oxidizing in nature.

(iv) Cr shows oxidising nature in +6 oxidation state.

Correct order of spin only magnetic moment of the following complex ions is :

(Given At.no. Fe : 26, Co : 27)

Reaction of propanamide with $$\mathrm{Br_2/KOH(aq)}$$ produces :

Following tetrapeptide can be represented as

(F, L, D, Y, I, Q, P are one letter codes for amino acids)

Match List I with List II

	List I		List II
A.	van't Hoff factor, i	I.	Cryoscopic constant
B.	$$\mathrm{k_f}$$	II.	Isotonic solutions
C.	Solutions with same osmotic pressure	III.	$$\mathrm{\frac{Normal\,molar\,mass}{Abnormal\,molar\,mass}}$$
D.	Azeotropes	IV.	Solutions with same composition of vapour above it

Choose the correct answer from the options given below :

The one giving maximum number of isomeric alkenes on dehydrohalogenation reaction is (excluding rearrangement)

An indicator 'X' is used for studying the effect of variation in concentration of iodide on the rate of reaction of iodide ion with $$\mathrm{H_2O_2}$$ at room temp. The indicator 'X' forms blue coloured complex with compound 'A' present in the solution. The indicator 'X' and compound 'A' respectively are :

Find out the major product for the following reaction.

Find out the major products from the following reaction sequence.

The volume of HCl, containing 73 g L$$^{-1}$$, required to completely neutralise NaOH obtained by reacting 0.69 g of metallic sodium with water, is __________ mL. (Nearest Integer)

(Given : molar masses of Na, Cl, O, H, are 23, 35.5, 16 and 1 g mol$$^{-1}$$ respectively.)

The equilibrium constant for the reaction

$$\mathrm{Zn(s)+Sn^{2+}(aq)}$$ $$\rightleftharpoons$$ $$\mathrm{Zn^{2+}(aq)+Sn(s)}$$ is $$1\times10^{20}$$ at 298 K. The magnitude of standard electrode potential of $$\mathrm{Sn/Sn^{2+}}$$ if $$\mathrm{E_{Z{n^{2 + }}/Zn}^\Theta = - 0.76~V}$$ is __________ $$\times 10^{-2}$$ V. (Nearest integer)

Given : $$\mathrm{\frac{2.303RT}{F}=0.059~V}$$

At 298 K

$$\mathrm{N_2~(g)+3H_2~(g)\rightleftharpoons~2NH_3~(g),~K_1=4\times10^5}$$

$$\mathrm{N_2~(g)+O_2~(g)\rightleftharpoons~2NO~(g),~K_2=1.6\times10^{12}}$$

$$\mathrm{H_2~(g)+\frac{1}{2}O_2~(g)\rightleftharpoons~H_2O~(g),~K_3=1.0\times10^{-13}}$$

Based on above equilibria, then equilibrium constant of the reaction, $$\mathrm{2NH_3(g)+\frac{5}{2}O_2~(g)\rightleftharpoons~2NO~(g)+3H_2O~(g)}$$ is ____________ $$\times10^{-33}$$ (Nearest integer).

The denticity of the ligand present in the Fehling's reagent is ___________.

When 0.01 mol of an organic compound containing 60% carbon was burnt completely, 4.4 g of CO$$_2$$ was produced. The molar mass of compound is _____________ g mol$$^{-1}$$ (Nearest integer).

Total number of acidic oxides among

$$\mathrm{N_2O_3,NO_2,N_2O,Cl_2O_7,SO_2,CO,CaO,Na_2O}$$ and $$\mathrm{NO}$$ is ____________.

Assume that the radius of the first Bohr orbit of hydrogen atom is 0.6 $$\mathrm{\mathop A\limits^o }$$. The radius of the third Bohr orbit of He$$^+$$ is __________ picometer. (Nearest Integer)

For conversion of compound A $$\to$$ B, the rate constant of the reaction was found to be $$\mathrm{4.6\times10^{-5}~L~mol^{-1}~s^{-1}}$$. The order of the reaction is ____________.