'A' in the given reaction is

When the hydrogen ion concentration [H$$^+$$] changes by a factor of 1000, the value of pH of the solution __________

Match List I with List II

	List I (Amines)		List II ($$\mathrm{pK_b}$$)
A.	Aniline	I.	3.25
B.	Ethanamine	II.	3.00
C.	N-Ethylethanamine	III.	9.38
D.	N, N-Diethylethanamine	IV.	3.29

Choose the correct answer from the options given below :

What is the mass ratio of ethylene glycol ($$\mathrm{C_2H_6O_2}$$, molar mass = 62 g/mol) required for making 500 g of 0.25 molal aqueous solution and 250 mL of 0.25 molar aqueous solution?

Find out the major product from the following reaction.

The isomeric deuterated bromide with molecular formula $$\mathrm{C_4H_8DBr}$$ having two chiral carbon atoms is

Match List I with List II

	List I Isomeric pairs		List II Type of isomers
A.	Propanamine and N-Methylethanamine	I.	Metamers
B.	Hexan-2-one and Hexan-3-one	II.	Positional isomers
C.	Ethanamide and Hydroxyethanimine	III.	Functional isomers
D.	o-nitrophenol and p-nitrophenol	IV.	Tautomers

Choose the correct answer from the options given below :

A. Ammonium salts produce haze in atmosphere.

B. Ozone gets produced when atmospheric oxygen reacts with chlorine radicals.

C. Polychlorinated biphenyls act as cleansing solvents.

D. 'Blue baby' syndrome occurs due to the presence of excess of sulphate ions in water.

Choose the correct answer from the options given below :

Statement I : Dipole moment is a vector quantity and by convention it is depicted by a small arrow with tail on the negative centre and head pointing towards the positive centre.

Statement II : The crossed arrow of the dipole moment symbolizes the direction of the shift of charges in the molecules.

In the light of the above statements, choose the most appropriate answer from the options given below :

Match List I with List II

	List I Coordination entity		List II Wavelength of light absorbed in nm
A.	$$\mathrm{[CoCl(NH_3)_5]^{2+}}$$	I.	310
B.	$$\mathrm{[Co(NH_3)_6]^{3+}}$$	II.	475
C.	$$\mathrm{[Co(CN)_6]^{3-}}$$	III.	535
D.	$$\mathrm{[Cu(H_2O)_4]^{2+}}$$	IV.	600

Choose the correct answer from the options given below :

A chloride salt solution acidified with dil.HNO$$_3$$ gives a curdy white precipitate, [A], on addition of AgNO$$_3$$. [A] on treatment with NH$$_4$$OH gives a clear solution B. A and B are respectively :

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R

Assertion A : Butylated hydroxy anisole when added to butter increases its shelf life.

Reason R : Butylated hydroxy anisole is more reactive towards oxygen than food.

In the light of the above statements, choose the most appropriate answer from the options given below

Potassium dichromate acts as a strong oxidizing agent in acidic solution. During this process, the oxidation state changes from :

28.0 L of CO$$_2$$ is produced on complete combustion of 16.8 L gaseous mixture of ethene and methane at 25$$^\circ$$C and 1 atm. Heat evolved during the combustion process is ___________ kJ.

Given : $$\mathrm{\Delta H_c~(CH_4)=-900~kJ~mol^{-1}}$$

$$\mathrm{\Delta H_c~(C_2H_4)=-1400~kJ~mol^{-1}}$$

The number of pairs of the solutions having the same value of the osmotic pressure from the following is _________.

(Assume 100% ionization)

A. 0.500 $$\mathrm{M~C_2H_5OH~(aq)}$$ and 0.25 $$\mathrm{M~KBr~(aq)}$$

B. 0.100 $$\mathrm{M~K_4[Fe(CN)_6]~(aq)}$$ and 0.100 $$\mathrm{M~FeSO_4(NH_4)_2SO_4~(aq)}$$

C. 0.05 $$\mathrm{M~K_4[Fe(CN)_6]~(aq)}$$ and 0.25 $$\mathrm{M~NaCl~(aq)}$$

D. 0.15 $$\mathrm{M~NaCl~(aq)}$$ and 0.1 $$\mathrm{M~BaCl_2~(aq)}$$

E. 0.02 $$\mathrm{M~KCl.MgCl_2.6H_2O~(aq)}$$ and 0.05 $$\mathrm{M~KCl~(aq)}$$

A first order reaction has the rate constant, $$\mathrm{k=4.6\times10^{-3}~s^{-1}}$$. The number of correct statement/s from the following is/are __________

Given : $$\mathrm{\log3=0.48}$$

A. Reaction completes in 1000 s.

B. The reaction has a half-life of 500 s.

C. The time required for 10% completion is 25 times the time required for 90% completion.

D. The degree of dissociation is equal to ($$\mathrm{1-e^{-kt}}$$)

E. The rate and the rate constant have the same unit.

$$Pt(s)|{H_2}(g)(1\,bar)|{H^ + }(aq)(1\,M)||{M^{3 + }}(aq),{M^ + }(aq)|Pt(s)$$

The $$\mathrm{E_{cell}}$$ for the given cell is 0.1115 V at 298 K when $${{\left[ {{M^ + }(aq)} \right]} \over {\left[ {{M^{3 + }}(aq)} \right]}} = {10^a}$$

The value of $$a$$ is ____________

Given : $$\mathrm{E_{{M^{3 + }}/{M^ + }}^\theta = 0.2}$$ V

$${{2.303RT} \over F} = 0.059V$$

The number of given orbitals which have electron density along the axis is _________

$$\mathrm{p_x,p_y,p_z,d_{xy},d_{yz},d_{xz},d_{z^2},d_{x^2-y^2}}$$

Total number of moles of AgCl precipitated on addition of excess of AgNO$$_3$$ to one mole each of the following complexes $$\mathrm{[Co(NH_3)_4Cl_2]Cl,[Ni(H_2O)_6]Cl_2,[Pt(NH_3)_2Cl_2]}$$ and $$\mathrm{[Pd(NH_3)_4]Cl_2}$$ is ___________.

Number of compounds giving (i) red colouration with ceric ammonium nitrate and also (ii) positive iodoform test from the following is ___________

Number of hydrogen atoms per molecule of a hydrocarbon A having 85.8% carbon is __________

(Given : Molar mass of A = 84 g mol$$^{-1}$$)