The major product 'P' formed in the given reaction is:

The decreasing order of hydride affinity for following carbocations is:

Choose the correct answer from the options given below:

In the reaction given below:

The product 'X' is:

Given below are two statements: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A : The energy required to form $$\mathrm{Mg}^{2+}$$ from $$\mathrm{Mg}$$ is much higher than that required to produce $$\mathrm{Mg}^+$$

Reason $$\mathbf{R}: \mathrm{Mg}^{2+}$$ is small ion and carry more charge than $$\mathrm{Mg}^{+}$$

In the light of the above statements, choose the correct answer from the options given below.

Given below are two statements: one is labelled as Assertion $$\mathbf{A}$$ and the other is labelled as Reason $$\mathbf{R}$$

Assertion A : $$3.1500 \mathrm{~g}$$ of hydrated oxalic acid dissolved in water to make $$250.0 \mathrm{~mL}$$ solution will result in $$0.1 \mathrm{~M}$$ oxalic acid solution.

Reason $$\mathbf{R}$$ : Molar mass of hydrated oxalic acid is $$126 \mathrm{~g} \mathrm{~mol}^{-1}$$

In the light of the above statements, choose the correct answer from the options given below.

The correct order of the number of unpaired electrons in the given complexes is

A. $$\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}$$

B. $$\left[\mathrm{Fe} \mathrm{F}_{6}\right]^{3-}$$

C. $$\left[\mathrm{CoF}_{6}\right]^{3-}$$

D. $$\left.[\mathrm{Cr} \text { (oxalate})_{3}\right]^{3-}$$

E. $$\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]$$

Choose the correct answer from the options given below:

The correct order for acidity of the following hydroxyl compound is :

A. $$\mathrm{CH}_{3} \mathrm{OH}$$

B. $$\left(\mathrm{CH}_{3}\right)_{3} \mathrm{COH}$$

C.

D.

E.

Choose the correct answer from the options given below:

Incorrect method of preparation for alcohols from the following is:

Match List I with List II

	List - I Complex		List - II Crystal Field splitting energy ($$\Delta_0$$)
A.	$${[Ti{({H_2}O)_6}]^{2 + }}$$	I.	$$-1.2$$
B.	$${[V{({H_2}O)_6}]^{2 + }}$$	II.	$$-0.6$$
C.	$${[Mn{({H_2}O)_6}]^{3 + }}$$	III.	0
D.	$${[Fe{({H_2}O)_6}]^{3 + }}$$	IV.	$$-0.8$$

Choose the correct answer from the options given below:

In Carius tube, an organic compound '$$\mathrm{X}$$' is treated with sodium peroxide to form a mineral acid 'Y'.

The solution of $$\mathrm{BaCl}_{2}$$ is added to '$$\mathrm{Y}$$' to form a precipitate 'Z'. 'Z' is used for the quantitative estimation of an extra element. '$$\mathrm{X}$$' could be

Match List I with List II

	List - I		List - II ($$\Delta_0$$)
A.	16 g of $$\mathrm{CH_4~(g)}$$	I.	Weighs 28 g
B.	1 g of $$\mathrm{H_2~(g)}$$	II.	$$60.2\times10^{23}$$ electrons
C.	1 mole of $$\mathrm{N_2~(g)}$$	III.	Weighs 32 g
D.	0.5 mol of $$\mathrm{SO_2~(g)}$$	IV.	Occupies 11.4 L volume of STP

Choose the correct answer from the options given below:

An aqueous solution of volume $$300 \mathrm{~cm}^{3}$$ contains $$0.63 \mathrm{~g}$$ of protein. The osmotic pressure of the solution at $$300 \mathrm{~K}$$ is 1.29 mbar. The molar mass of the protein is ___________ $$\mathrm{g} ~\mathrm{mol}^{-1}$$

Given : R = 0.083 L bar K$$^{-1}$$ mol$$^{-1}$$

The number of molecules from the following which contain only two lone pair of electrons is ________

$$\mathrm{H}_{2} \mathrm{O}, \mathrm{N}_{2}, \mathrm{CO}, \mathrm{XeF}_{4}, \mathrm{NH}_{3}, \mathrm{NO}, \mathrm{CO}_{2}, \mathrm{~F}_{2}$$

For a metal ion, the calculated magnetic moment is $$4.90 ~\mathrm{BM}$$. This metal ion has ___________ number of unpaired electrons.

In alkaline medium, the reduction of permanganate anion involves a gain of __________ electrons.

The number of incorrect statement/s from the following is ___________

A. The successive half lives of zero order reactions decreases with time.

B. A substance appearing as reactant in the chemical equation may not affect the rate of reaction

C. Order and molecularity of a chemical reaction can be a fractional number

D. The rate constant units of zero and second order reaction are $$\mathrm{mol} ~\mathrm{L}^{-1} \mathrm{~s}^{-1}$$ and $$\mathrm{mol}^{-1} \mathrm{~L} \mathrm{~s}^{-1}$$ respectively

The electron in the $$\mathrm{n}^{\text {th }}$$ orbit of $$\mathrm{Li}^{2+}$$ is excited to $$(\mathrm{n}+1)$$ orbit using the radiation of energy $$1.47 \times 10^{-17} \mathrm{~J}$$ (as shown in the diagram). The value of $$\mathrm{n}$$ is ___________

Given: $$\mathrm{R}_{\mathrm{H}}=2.18 \times 10^{-18} \mathrm{~J}$$

The number of endothermic process/es from the following is ______________.

A. $$\mathrm{I}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{I}(\mathrm{g})$$

B. $$\mathrm{HCl}(\mathrm{g}) \rightarrow \mathrm{H}(\mathrm{g})+\mathrm{Cl}(\mathrm{g})$$

C. $$\mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{H}_{2} \mathrm{O}(\mathrm{g})$$

D. $$\mathrm{C}(\mathrm{s})+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow \mathrm{CO}_{2}(\mathrm{~g})$$

E. Dissolution of ammonium chloride in water

$$\mathrm{A}(g) \rightleftharpoons 2 \mathrm{~B}(g)+\mathrm{C}(g)$$

For the given reaction, if the initial pressure is $$450 \mathrm{~mm} ~\mathrm{Hg}$$ and the pressure at time $$\mathrm{t}$$ is $$720 \mathrm{~mm} ~\mathrm{Hg}$$ at a constant temperature $$\mathrm{T}$$ and constant volume $$\mathrm{V}$$. The fraction of $$\mathrm{A}(\mathrm{g})$$ decomposed under these conditions is $$x \times 10^{-1}$$. The value of $$x$$ is ___________ (nearest integer)

The specific conductance of $$0.0025 ~\mathrm{M}$$ acetic acid is $$5 \times 10^{-5} \mathrm{~S} \mathrm{~cm}^{-1}$$ at a certain temperature. The dissociation constant of acetic acid is __________ $$\times ~10^{-7}$$ (Nearest integer)

Consider limiting molar conductivity of $$\mathrm{CH}_{3} \mathrm{COOH}$$ as $$400 \mathrm{~S} \mathrm{~cm}^{2} \mathrm{~mol}^{-1}$$