JEE MAIN - Chemistry (2023 - 10th April Evening Shift - No. 11)

Match List I with List II

List - I List - II ($$\Delta_0$$)
A. 16 g of $$\mathrm{CH_4~(g)}$$ I. Weighs 28 g
B. 1 g of $$\mathrm{H_2~(g)}$$ II. $$60.2\times10^{23}$$ electrons
C. 1 mole of $$\mathrm{N_2~(g)}$$ III. Weighs 32 g
D. 0.5 mol of $$\mathrm{SO_2~(g)}$$ IV. Occupies 11.4 L volume of STP

Choose the correct answer from the options given below:

A-II, B-III, C-IV, D-I
A-II, B-IV, C-I, D-III
A-I, B-III, C-II, D-IV
A-II, B-IV, C-III, D-I

Explanation

A. 16 g of $\mathrm{CH_4~(g)}$

The molar mass of $\mathrm{CH_4}$ (Methane) is 16 g/mol. Therefore, 16 g of $\mathrm{CH_4}$ is equivalent to 1 mole of $\mathrm{CH_4}$. Furthermore, each molecule of $\mathrm{CH_4}$ has 10 electrons (6 from Carbon and 4 from Hydrogen). As a result, 1 mole of $\mathrm{CH_4}$ (or $6.022 \times 10^{23}$ molecules of $\mathrm{CH_4}$) would have $10 \times 6.022 \times 10^{23} = 60.2 \times 10^{23}$ electrons. This matches with (II).

B. 1 g of $\mathrm{H_2~(g)}$

The molar mass of $\mathrm{H_2}$ (Hydrogen) is 2 g/mol. Therefore, 1 g of $\mathrm{H_2}$ is equivalent to 0.5 moles of $\mathrm{H_2}$. The volume that a given quantity of gas occupies is proportional to the number of moles of gas. At standard temperature and pressure (STP), 1 mole of any ideal gas occupies 22.4 liters. Therefore, 0.5 moles of gas would occupy $0.5 \times 22.4 = 11.2$ liters. The closest match is (IV) with 11.4 liters (the small discrepancy may be due to rounding or slightly different conditions than STP).

C. 1 mole of $\mathrm{N_2~(g)}$

The molar mass of $\mathrm{N_2}$ (Nitrogen) is 28 g/mol. Therefore, 1 mole of $\mathrm{N_2}$ weighs 28 g. This matches with (I).

D. 0.5 mol of $\mathrm{SO_2~(g)}$

The molar mass of $\mathrm{SO_2}$ (Sulfur Dioxide) is 64 g/mol. Therefore, 0.5 moles of $\mathrm{SO_2}$ weigh $0.5 \times 64 = 32$ g. This matches with (III).

Thus, the correct matches are:

A - II

B - IV

C - I

D - III

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