The correct decreasing order of energy for the orbitals having, following set of quantum numbers :

(A) n = 3, l = 0, m = 0

(B) n = 4, l = 0, m = 0

(C) n = 3, l = 1, m = 0

(D) n = 3, l = 2, m = 1

is :

Match List - I with List - II.

	List - I		List - II
(A)	$$\psi_{\mathrm{MO}}=\psi_{\mathrm{A}}-\psi_{\mathrm{B}}$$	(I)	Dipole moment
(B)	$$\mu=Q \times r$$	(II)	Bonding molecular orbital
(C)	$$\frac{\mathrm{N}_{\mathrm{b}}-\mathrm{N}_{\mathrm{a}}}{2}$$	(III)	Anti-bonding molecular orbital
(D)	$$\psi_{\mathrm{MO}}=\psi_{\mathrm{A}}+\psi_{\mathrm{B}}$$	(IV)	Bond order

Choose the correct answer from the options given below :

The plot of $$\mathrm{pH}$$-metric titration of weak base $$\mathrm{NH}_{4} \mathrm{OH}$$ vs strong acid HCl looks like :

Given below are two statements :

Statement I : For KI, molar conductivity increases steeply with dilution

Statement II : For carbonic acid, molar conductivity increases slowly with dilution

In the light of the above statements, choose the correct answer from the options given below :

Outermost electronic configurations of four elements A, B, C, D are given below :

(A) $$3 s^{2}$$

(B) $$3 s^{2} 3 p^{1}$$

(C) $$3 s^{2} 3 p^{3}$$

(D) $$3 s^{2} 3 p^{4}$$

The correct order of first ionization enthalpy for them is :

In neutral or alkaline solution, $$\mathrm{MnO}_{4}^{-}$$ oxidises thiosulphate to :

Low oxidation state of metals in their complexes are common when ligands :

The structure of A in the given reaction is :

Major product '$$\mathrm{B}$$' of the following reaction sequence is :

Match List - I with List - II.

	List - I		List - II
(A)		(I)	Gatterman Koch reaction
(B)	$$C{H_3} - CN\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{{H_3}{O^ + }}^{SnC{l_2}/HCl}} C{H_3} - CHO$$	(II)	Etard reaction
(C)		(III)	Stephen reaction
(D)		(IV)	Rosenmund reaction

Choose the correct answer from the options given below :

An organic compound $$'\mathrm{A}'$$ contains nitrogen and chlorine. It dissolves readily in water to give a solution that turns litmus red. Titration of compound $$'\mathrm{A}'$$ with standard base indicates that the molecular weight of $$'\mathrm{A}'$$ is $$131 \pm 2$$. When a sample of $$'\mathrm{A}'$$ is treated with aq. $$\mathrm{NaOH}$$, a liquid separates which contains $$\mathrm{N}$$ but not $$\mathrm{Cl}$$. Treatment of the obtained liquid with nitrous acid followed by phenol gives orange precipitate. The compound $$'\mathrm{A}'$$ is :

Match List - I with Match List - II.

	List - I		List - II
(A)	Glucose + HI	(I)	Gluconic acid
(B)	Glucose + Br$$_2$$ water	(II)	Glucose pentacetate
(C)	Glucose + acetic anhydride	(III)	Saccharic acid
(D)	Glucose + HNO$$_3$$	(IV)	Hexane

Choose the correct answer from the options given below:

Match List - I with List - II.

	List - I (Mixture)		List - II (Purification Process)
(A)	Chloroform & Aniline	(I)	Steam distillation
(B)	Benzoic acid & Napthalene	(II)	Sublimation
(C)	Water & Aniline	(III)	Distillation
(D)	Napthalene & Sodium chloride	(IV)	Crystallisation

Choose the correct answer from the options given below :

$$\mathrm{Fe}^{3+}$$ cation gives a prussian blue precipitate on addition of potassium ferrocyanide solution due to the formation of :

The normality of $$\mathrm{H}_{2} \mathrm{SO}_{4}$$ in the solution obtained on mixing $$100 \mathrm{~mL}$$ of $$0.1 \,\mathrm{M} \,\mathrm{H}_{2} \mathrm{SO}_{4}$$ with $$50 \mathrm{~mL}$$ of $$0.1 \,\mathrm{M}\, \mathrm{NaOH}$$ is _______________ $$\times 10^{-1} \mathrm{~N}$$. (Nearest Integer)

A gas (Molar mass = 280 $$\mathrm{~g} \mathrm{~mol}^{-1}$$) was burnt in excess $$\mathrm{O}_{2}$$ in a constant volume calorimeter and during combustion the temperature of calorimeter increased from $$298.0 \mathrm{~K}$$ to $$298.45$$ $$\mathrm{K}$$. If the heat capacity of calorimeter is $$2.5 \mathrm{~kJ} \mathrm{~K}^{-1}$$ and enthalpy of combustion of gas is $$9 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ then amount of gas burnt is _____________ g. (Nearest Integer)

When a certain amount of solid A is dissolved in $$100 \mathrm{~g}$$ of water at $$25^{\circ} \mathrm{C}$$ to make a dilute solution, the vapour pressure of the solution is reduced to one-half of that of pure water. The vapour pressure of pure water is $$23.76 \,\mathrm{mmHg}$$. The number of moles of solute A added is _____________. (Nearest Integer)

$$\matrix{ {[A]} & \to & {[B]} \cr {{\mathop{\rm Reactant}\nolimits} } & {} & {{\mathop{\rm Product}\nolimits} } \cr } $$

If formation of compound $$[\mathrm{B}]$$ follows the first order of kinetics and after 70 minutes the concentration of $$[\mathrm{A}]$$ was found to be half of its initial concentration. Then the rate constant of the reaction is $$x \times 10^{-6} \mathrm{~s}^{-1}$$. The value of $$x$$ is ______________. (Nearest Integer)

The number of molecule(s) or ion(s) from the following having non-planar structure is ____________.

$$\mathrm{NO}_{3}^{-}, \mathrm{H}_{2} \mathrm{O}_{2}, \mathrm{BF}_{3}, \mathrm{PCl}_{3}, \mathrm{XeF}_{4}, \mathrm{SF}_{4}, \mathrm{XeO}_{3}, \mathrm{PH}_{4}^{+}, \mathrm{SO}_{3},\left[\mathrm{Al}(\mathrm{OH})_{4}\right]^{-}$$

The spin only magnetic moment of the complex present in Fehling's reagent is __________ B.M. (Nearest integer).

In the above reaction, $$5 \mathrm{~g}$$ of toluene is converted into benzaldehyde with $$92 \%$$ yield. The amount of benzaldehyde produced is ______________ $$\times 10^{-2} \mathrm{~g}$$. (Nearest integer)