JEE MAIN - Chemistry (2022 - 26th June Morning Shift)
1
A commercially sold conc. HCl is 35% HCl by mass. If the density of this commercial acid is 1.46 g/mL, the molarity of this solution is:
(Atomic mass : Cl = 35.5 amu, H = 1 amu)
Answer
(C)
14.0 M
2
If the radius of the 3rd Bohr's orbit of hydrogen atom is r3 and the radius of 4th Bohr's orbit is r4. Then :
Answer
(B)
$${r_4} = {16 \over {9}}{r_3}$$
3
Consider the ions/molecule
O$$_2^ + $$, O2, O$$_2^ - $$, O$$_2^ {2-} $$
For increasing bond order the correct option is :
Answer
(A)
O$$_2^ {2-} $$ < O$$_2^ - $$ < O2 < O$$_2^ + $$
4
The $${\left( {{{\partial E} \over {\partial T}}} \right)_P}$$ of different types of half cells are as follows:
A
B
C
D
$$1 \times {10^{ - 4}}$$
$$2 \times {10^{ - 4}}$$
$$0.1 \times {10^{ - 4}}$$
$$0.2 \times {10^{ - 4}}$$
(Where E is the electromotive force)
Which of the above half cells would be preferred to be used as reference electrode?
Answer
(C)
C
5
Choose the correct stability order of group 13 elements in their + 1 oxidation state :
Answer
(A)
Al < Ga < In < Tl
6
Given below are two statements :
Statement I : In 'Lassaigne's Test', when both nitrogen and sulphur are present in an organic compound, sodium thiocyanate is formed.
Statement II : If both nitrogen and sulphur are present in an organic compound, then the excess of sodium used in sodium fusion will decompose the sodium thiocyanate formed to give NaCN and Na2S.
In the light of the above statements, choose the most appropriate answer from the options given below :
the amount of heat produced as measured by bomb calorimeter is 726 kJ mol$$-$$1 at 27$$^\circ$$C. The enthalpy of combustion for the reaction is $$-$$x kJ mol$$-$$1, where x is ___________. (Nearest integer)
(Given : R = 8.3 JK$$-$$1 mol$$-$$1)
Answer
727
13
A 0.5 percent solution of potassium chloride was found to freeze at $$-$$0.24$$^\circ$$C. The percentage dissociation of potassium chloride is ______________. (Nearest integer)
(Molal depression constant for water is 1.80 K kg mol$$-$$1 and molar mass of KCl is 74.6 g mol$$-$$1)
Answer
98
14
50 mL of 0.1 M CH3COOH is being titrated against 0.1 M NaOH. When 25 mL of NaOH has been added, the pH of the solution will be _____________ $$\times$$ 10$$-$$2. (Nearest integer)
(Given : pKa (CH3COOH) = 4.76)
log 2 = 0.30
log 3 = 0.48
log 5 = 0.69
log 7 = 0.84
log 11 = 1.04
Answer
476
15
A flask is filled with equal moles of A and B. The half lives of A and B are 100 s and 50 s respectively and are independent of the initial concentration. The time required for the concentration of A to be four times that of B is ___________ s.
(Given : ln 2 = 0.693)
Answer
200
16
The spin-only magnetic moment value of the most basic oxide of vanadium among V2O3, V2O4 and V2O5 is _____________ B.M. (Nearest integer)
Answer
3
17
The spin-only magnetic moment value of an octahedral complex among CoCl3.4NH3, NiCl2.6H2O and PtCl4.2HCl, which upon reaction with excess of AgNO3 gives 2 moles of AgCl is ___________ B.M. (Nearest integer)
Answer
3
18
On complete combustion 0.30 g of an organic compound gave 0.20 g of carbon dioxide and 0.10 g of water. The percentage of carbon in the given organic compound is _____________. (Nearest integer)
Answer
18
19
Compound 'P' on nitration with dil. HNO3 yields two isomers (A) and (B). These isomers can be separated by steam distillation. Isomers (A) and (B) show the intramolecular and intermolecular hydrogen bonding respectively. Compound (P) on reaction with conc. HNO3 yields a yellow compound 'C', a strong acid. The number of oxygen atoms is present in compound 'C' _____________.
Answer
7
20
The number of oxygens present in a nucleotide formed from a base, that is present only in RNA is ___________.