JEE MAIN - Chemistry (2022 - 26th June Morning Shift - No. 18)
On complete combustion 0.30 g of an organic compound gave 0.20 g of carbon dioxide and 0.10 g of water. The percentage of carbon in the given organic compound is _____________. (Nearest integer)
Answer
18
Explanation
$${C_x}{H_y} + \left( {x + {y \over 4}} \right){O_2} \to x\,C{O_2} + {y \over 2}{H_2}O$$
Given organic compound CxHy= 0.3 gm
Produced carbon dioxide (CO2) = 0.2 gm
Produced water (H2O) = 0.1 gm
Moles of CO2 = $${{0.2} \over {44}}$$
$$\therefore$$ Moles of C atom = $${{0.2} \over {44}}$$
$$\therefore$$ Mass of C atom = $${{0.2} \over {44}}$$ $$\times$$ 12 = 0.0545
Moles of H2O = $${{0.1} \over {18}}$$
$$\therefore$$ Moles of H atoms = $${{0.1} \over {18}}$$ $$\times$$ 2
$$\therefore$$ Mass of H atoms = $${{0.1} \times2\over {18}}$$ $$\times$$ 1 = 0.0111
$$\therefore$$ % of C atom = $${{0.0545} \over {0.3}}$$ $$\times$$ 100 = 18%
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