JEE MAIN - Chemistry (2022 - 25th June Evening Shift)

1

The minimum energy that must be possessed by photons in order to produce the photoelectric effect with platinum metal is :

[Given : The threshold frequency of platinum is 1.3 $$\times$$ 1015 s$$-$$1 and h = 6.6 $$\times$$ 10$$-$$34 J s.]

Answer
(C)
8.58 $$\times$$ 10$$-$$19 J
2
At 25$$^\circ$$C and 1 atm pressure, the enthalpy of combustion of benzene (I) and acetylene (g) are $$-$$ 3268 kJ mol$$-$$1 and $$-$$1300 kJ mol$$-$$1, respectively. The change in enthalpy for the reaction 3 C2H2(g) $$\to$$ C6H6 (I), is :
Answer
(C)
$$-$$ 632 kJ mol$$-$$1
3

Solute A associates in water. When 0.7 g of solute A is dissolved in 42.0 g of water, it depresses the freezing point by 0.2$$^\circ$$C. The percentage association of solute A in water, is :

[Given : Molar mass of A = 93 g mol$$-$$1. Molal depression constant of water is 1.86 K kg mol$$-$$1.]

Answer
(D)
80%
4
The Ksp for bismuth sulphide (Bi2S3) is 1.08 $$\times$$ 10$$-$$73. The solubility of Bi2S3 in mol L$$-$$1 at 298 K is :
Answer
(A)
1.0 $$\times$$ 10$$-$$15
5
The correct order of electron gain enthalpies of Cl, F, Te and Po is
Answer
(B)
Po < Te < F < Cl
6

Given below are two statements one is labelled as Assertion A and the other is labelled as Reason R :

Assertion A : The amphoteric nature of water is explained by using Lewis acid/base concept.

Reason R : Water acts as an acid with NH3 and as a base with H2S.

In the light of the above statements choose the correct answer from the options given below :

Answer
(D)
A is false but R is true.
7

The correct order of reduction potentials of the following pairs is

A. Cl2/Cl$$-$$

B. I2/I$$-$$

C. Ag+/Ag

D. Na+/Na

E. Li+/Li

Choose the correct answer from the options given below.

Answer
(A)
A > C > B > D > E
8
The metal ion (in gaseous state) with lowest spin-only magnetic moment value is :
Answer
(B)
Ni2+
9

Given below are two statements : one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : A mixture contains benzoic acid and napthalene. The pure benzoic acid can be separated out by the use of benzene.

Reason R : Benzoic acid is soluble in hot water.

In the light of the above statements, choose the most appropriate answer from the options given below.

Answer
(D)
A is false but R is true.
10
During halogen test, sodium fusion extract is boiled with concentrated HNO3 to
Answer
(B)
decompose cyanide or sulphide of sodium
11

Amongst the following, the major product of the given chemical reaction is

JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 91 English

Answer
(A)
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 91 English Option 1
12

In the given reaction

JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 78 English

'A' can be

Answer
(B)
bromobenzene
13
Which of the following conditions or reaction sequence will NOT give acetophenone as the major product?
Answer
(C)
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 94 English Option 3
14

The major product formed in the following reaction, is

JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 77 English

Answer
(D)
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Alcohols, Phenols and Ethers Question 77 English Option 4
15
Which of the following ketone will NOT give enamine on treatment with secondary amines? [where t-Bu is $$-$$C(CH3)3]
Answer
(C)
JEE Main 2022 (Online) 25th June Evening Shift Chemistry - Compounds Containing Nitrogen Question 92 English Option 3
16
A protein 'A' contains 0.30% of glycine (molecular weight 75). The minimum molar mass of the protein 'A' is __________ $$\times$$ 103 g mol$$-$$1 [nearest integer]
Answer
25
17
Amongst BeF2, BF3, H2O, NH3, CCl4 and HCl, the number of molecules with non-zero net dipole moment is ____________.
Answer
3
18
At 345 K, the half life for the decomposition of a sample of a gaseous compound initially at 55.5 kPa was 340 s. When the pressure was 27.8 kPa, the half life was found to be 170 s. The order of the reaction is ____________. [integer answer]
Answer
0
19

A solution of Fe2(SO4)3 is electrolyzed for 'x' min with a current of 1.5 A to deposit 0.3482 g of Fe. The value of x is ___________. [nearest integer]

Given : 1 F = 96500 C mol$$-$$1

Atomic mass of Fe = 56 g mol$$-$$1

Answer
20
20
Amongst FeCl3.3H2O, K3[Fe(CN)6] and [Co(NH3)6]Cl3, the spin-only magnetic moment value of the inner-orbital complex that absorbs light at shortest wavelength is ____________ B.M. [nearest integer]
Answer
2
21

How many of the given compounds will give a positive Biuret test ____________ ?

Glycine, Glycylalanine, Tripeptide, Biuret

Answer
2
22

The neutralization occurs when 10 mL of 0.1M acid 'A' is allowed to react with 30 mL of 0.05 M base M(OH)2. The basicity of the acid 'A' is __________.

[M is a metal]

Answer
3