JEE MAIN - Chemistry (2022 - 25th June Evening Shift - No. 10)

During halogen test, sodium fusion extract is boiled with concentrated HNO3 to
remove unreacted sodium
decompose cyanide or sulphide of sodium
extract halogen from organic compound
maintain the pH of extract.

Explanation

During test for halogen, if nitrogen or sulphur is also present in the compound, then sodium fusion extract is first boiled with concentrated nitric acid to decompose cyanide or sulphide of sodium formed during Lassaigne's test.

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