Match List I with List II:

	List I (molecule)		List II (hybridization ; shape)
(A)	XeO$$_3$$	(I)	sp$$^3$$d ; linear
(B)	XeF$$_2$$	(II)	sp$$^3$$ ; pyramidal
(C)	XeOF$$_4$$	(III)	sp$$^3$$d$$^3$$ ; distorted octahedral
(D)	XeF$$_6$$	(IV)	sp$$^3$$d$$^2$$ ; square pyramidal

Choose the correct answer from the options given below:

Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y, respectively in 1 kg of water. The ratio of depression in freezing points for A and B is found to be 1 : 4. The ratio of molar masses of X and Y is

$${K_{{a_1}}}$$, $${K_{{a_2}}}$$ and $${K_{{a_3}}}$$ are the respective ionization constants for the following reactions (a), (b) and (c).

(a) $${H_2}{C_2}{O_4} \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over {\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} {H^ + } + H{C_2}O_4^ - $$

(b) $$H{C_2}O_4^ - \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over {\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} {H^ + } + {C_2}O_4^{2 - }$$

(c) $${H_2}{C_2}O_4^{} \mathbin{\lower.3ex\hbox{$\buildrel\textstyle\rightarrow\over {\smash{\leftarrow}\vphantom{_{\vbox to.5ex{\vss}}}}$}} 2{H^ + } + {C_2}O_4^{2 - }$$

The relationship between $${K_{{a_1}}}$$, $${K_{{a_2}}}$$ and $${K_{{a_3}}}$$ is given as :

The molar conductivity of a conductivity cell filled with 10 moles of 20 mL NaCl solution is $${\Lambda _{m1}}$$ and that of 20 moles another identical cell heaving 80 mL NaCl solution is $${\Lambda _{m2}}$$. The conductivities exhibited by these two cells are same. The relationship between $${\Lambda _{m2}}$$ and $${\Lambda _{m1}}$$ is

The first ionization enthalpies of Be, B, N and O follow the order

The correct order of energy of absorption for the following metal complexes is :

A : [Ni(en)₃]²⁺ , B : [Ni(NH₃)₆]²⁺ , C : [Ni(H₂O)₆]²⁺

Match List I with List II:

	List I		List II
(A)	Sulphate	(I)	Pesticide
(B)	Fluoride	(II)	Bending of bones
(C)	Nicotine	(III)	Laxative effect
(D)	Sodium arsinite	(IV)	Herbicide

Choose the correct answer from the options given below :

Major product of the following reaction is

What is the major product of the following reaction?

Arrange the following in decreasing acidic strength.

$$C{H_3} - C{H_2} - CN\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{Ether}^{C{H_3}MgBr}} A\buildrel {{H_3}{O^ + }} \over \longrightarrow B\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{HCl}^{Zn - Hg}} C$$

The correct structure of C is

Glycosidic linkage between C₁ of $$\alpha$$-glucose and C₂ of $$\beta$$-fructose is found in

In base vs. acid titration, at the end point methyl orange is present as

56.0 L of nitrogen gas is mixed with excess hydrogen gas and it is found that 20 L of ammonia gas is produced. The volume of unused nitrogen gas is found to be _________ L.

When the excited electron of a H atom from n = 5 drops to the ground state, the maximum number of emission lines observed are _____________.

While performing a thermodynamics experiment, a student made the following observations.

HCl + NaOH $$\to$$ NaCl + H₂O $$\Delta$$H = $$-$$57.3 kJ mol^$$-$$1

CH₃COOH + NaOH $$\to$$ CH₃COONa + H₂O $$\Delta$$H = $$-$$55.3 kJ mol^$$-$$1

The enthalpy of ionization of CH₃COOH as calculated by the student is _____________ kJ mol^$$-$$1. (nearest integer)

For the decomposition of azomethane.

CH₃N₂CH₃(g) $$\to$$ CH₃CH₃(g) + N₂(g), a first order reaction, the variation in partial pressure with time at 600 K is given as

The half life of the reaction is __________ $$\times$$ 10^$$-$$5 s. [Nearest integer]

The sum of number of lone pairs of electrons present on the central atoms of XeO₃, XeOF₄ and XeF₆, is ______________

The spin-only magnetic moment value of M³⁺ ion (in gaseous state) from the pairs Cr³⁺ / Cr²⁺, Mn³⁺ / Mn²⁺, Fe³⁺ / Fe²⁺ and Co³⁺ / Co²⁺ that has negative standard electrode potential, is ____________ B.M. [Nearest integer]

A sample of 4.5 mg of an unknown monohydric alcohol, R-OH was added to methylmagnesium iodide. A gas is evolved and is collected and its volume measured to be 3.1 mL. The molecular weight of the unknown alcohol is __________ g/mol. [Nearest integer]

The separation of two coloured substances was done by paper chromatography. The distances travelled by solvent front, substance A and substance B from the base line are 3.25 cm, 2.08 cm and 1.05 cm, respectively. The ratio of R_f values of A to B is _____________.

The total number of monobromo derivatives formed by the alkanes with molecular formula C₅H₁₂ is (excluding stereo isomers) __________.