JEE MAIN - Chemistry (2022 - 25th July Evening Shift - No. 5)

The first ionization enthalpies of Be, B, N and O follow the order
O < N < B < Be
Be < B < N < O
B < Be < N < O
B < Be < O < N

Explanation

The first ionization energy increase from left to right along $2^{\text {nd }}$ period with the following exceptions

$$\mathrm{IE}_{1}: \mathrm{Be}>\mathrm{B}$$ and $$\mathrm{N}>\mathrm{O}$$

This is due to stable configuration of $$\mathrm{Be}$$ in comparison to $$\mathrm{B}$$ and that of $$\mathrm{N}$$ in comparison to $$\mathrm{O}$$.

Hence the correct order is $$\mathrm{N}>\mathrm{O}>\mathrm{Be}>\mathrm{B}$$

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