JEE MAIN - Chemistry (2021 - 26th August Morning Shift)

1
Which one of the following complexes is violet in colour?
Answer
(D)
[Fe(CN)5NOS]4$$-$$
2
Which one of the following when dissolved in water gives coloured solution in nitrogen atmosphere?
Answer
(A)
CuCl2
3
The major products formed in the following reaction sequence A and B are :

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 115 English
Answer
(A)
JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 115 English Option 1
4
The major product formed in the following reaction is :

Answer
(C)
JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Compounds Containing Nitrogen Question 116 English Option 3
5
The major product formed in the following reaction is :

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Haloalkanes and Haloarenes Question 82 English
Answer
(A)
JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Haloalkanes and Haloarenes Question 82 English Option 1
6
Given below are two statements :

Statement I : The limiting molar conductivity of KCl (strong electrolyte) is higher compared to that of CH3COOH (weak electrolyte).

Statement II : Molar conductivity decreases with decrease in concentration of electrolyte.

In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(D)
Both Statement I and Statement II are false.
7
The correct options for the products A and B of the following reactions are :

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 92 English
Answer
(B)
JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Alcohols, Phenols and Ethers Question 92 English Option 2
8
Given below are two statements.

Statement I : In the titration between strong acid and weak base methyl orange is suitable as an indicator.

Statement II : For titration of acetic acid with NaOH phenolphthalein is not a suitable indicator.

In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(B)
Statement I is true but Statement II is false
9
Among the following compounds I-IV, which one forms a yellow precipitate on reacting sequentially with (i) NaOH (ii) dil. HNO3 (iii) AgNO3?

Answer
(B)
IV
10
Given below are two statements.

Statement I : According to Bohr's model of an atom, qualitatively the magnitude of velocity of electron increases with decrease in positive charges on the nucleus as there is no strong hold on the electron by the nucleus.

Statement II : According to Bohr's model of an atom, qualitatively the magnitude of velocity of electron increases with decrease in principal quantum number.

In the light of the above statements, choose the most appropriate answer from the options given below :
Answer
(C)
Statement I is false but Statement II is true
11
The correct sequential addition of reagents in the preparation of 3-nitrobenzoic acid from benzene is :
Answer
(D)
HNO3/H2SO4, Br2/AlBr3, Mg/ether, CO2, H3O+
12
Excess of isobutane on reaction with Br2 in presence of light at 125$$^\circ$$C gives which one of the following, as the major product?
Answer
(D)
JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Haloalkanes and Haloarenes Question 81 English Option 4
13
AB3 is an interhalogen T-shaped molecule. The number of lone pairs of electrons on A is __________. (Integer answer)
Answer
2
14
These are physical properties of an element

(A) Sublimation enthalpy

(B) Ionisation enthalpy

(C) Hydration enthalpy

(D) Electron gain enthalpy

The total number of above properties that affect the reduction potential is ____________ (Integer answer)
Answer
3
15
Of the following four aqueous solutions, total number of those solutions whose freezing point is lower than that of 0.10 M C2H5OH is __________ (Integer answer)

(i) 0.10 M Ba3(PO4)2

(ii) 0.10 M Na2SO4

(iii) 0.10 M KCl

(iv) 0.10 M Li3PO4
Answer
4
16
The OH$$-$$ concentration in a mixture of 5.0 mL of 0.0504 M NH4Cl and 2 mL of 0.0210 M NH3 solution is x $$\times$$ 10$$-$$6 M. The value of x is ___________. (Nearest integer)

[Given Kw = 1 $$\times$$ 10$$-$$14 and Kb = 1.8 $$\times$$ 10$$-$$5]
Answer
3
17
The number of 4f electrons in the ground statement electronic configuration of Gd2+ is ___________. [Atomic number of Gd = 64]
Answer
7
18
The ratio of number of water molecules in Mohr's salt and potash alum is ____________ $$\times$$ 10$$-$$1. (Integer answer)
Answer
5
19
The following data was obtained for chemical reaction given below at 975 K.

2NO(g) + 2H2(g) $$\to$$ N2(g) + 2H2O(g)

JEE Main 2021 (Online) 26th August Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 87 English

The order of the reaction with respect to NO is ___________. [Integer answer]
Answer
1
20
The Born-Haber cycle for KCl is evaluated with the following data :

$${\Delta _f}{H^\Theta }$$ for KCl = $$-$$436.7 kJ mol$$-$$1 ;

$${\Delta _{sub}}{H^\Theta }$$ for K = 89.2 kJ mol$$-$$1 ;

$${\Delta _{ionization}}{H^\Theta }$$ for K = 419.0 kJ mol$$-$$1 ;

$${\Delta _{electron\,gain}}{H^\Theta }$$ for Cl(g) = $$-$$348.6 kJ mol$$-$$1 ;

$${\Delta _{bond}}{H^\Theta }$$ for Cl2 = 243.0 kJ mol$$-$$1

The magnitude of lattice enthalpy of KCl in kJ mol$$-$$1 is _____________ (Nearest integer)
Answer
718
21
The total number of negative charge in the tetrapeptide, Gly-Glu-Asp-Tyr, at pH 12.5 will be ______________. (Integer answer)
Answer
4
22
An aqueous KCl solution of density 1.20 g mL$$-$$1 has a molality of 3.30 mol kg$$-$$1. The molarity of the solution in mol L$$-$$1 is ____________ (Nearest integer) [Molar mass of KCl = 74.5]
Answer
3