JEE MAIN - Chemistry (2021 - 25th February Morning Shift)
1
The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is : [Assume : No cyano complex is formed; Ksp(AgCN) = 2.2 $$\times$$ 10$$-$$16 and Ka(HCN) = 6.2 $$\times$$ 10$$-$$10]
Answer
(A)
1.9 $$\times$$ 10$$-$$5
2
Which one of the following reactions will not form acetaldehyde?
The plots of radial distribution functions for various orbitals of hydrogen atom against 'r' are given below :
The correct plot for 3s orbital is :
Answer
(D)
(D)
4
Identify A in the given chemical reaction.
Answer
(D)
5
Given below are two statements :
Statement I : CeO2 can be used for oxidation of aldehydes and ketones.
Statement II : Aqueous solution of EuSO4 is a strong reducing agent.
In the light of the above statements, choose the correct answer from the options given below :
Answer
(D)
Both Statement I and Statement II are true
6
Compound(s) which will liberate carbon dioxide with sodium bicarbonate solution is/are :
Answer
(C)
B and C only
7
Identify A and B in the chemical reaction.
Answer
(A)
8
Which of the glycosidic linkage between galactose and glucose is present in lactose?
Answer
(C)
C-1 of galactose and C-4 of glucose
9
According to molecular orbital theory, the species among the following that does not exist is :
Answer
(B)
$$B{e_2}$$
10
Complete combustion of 1.80 g of an oxygen containing compound (CxHyOz) gave 2.64 g of CO2 and 1.08 g of H2O. The percentage of oxygen in the organic compound is :
Answer
(D)
53.33
11
The hybridization and magnetic nature of $${[Mn{(CN)_6}]^{4 - }}$$ and $${[Fe{(CN)_6}]^{3 - }}$$, respectively are :
Answer
(B)
d2sp3 and paramagnetic
12
The major product of the following chemical reaction is :
Answer
(A)
$$C{H_3}C{H_2}CHO$$
13
In which of the following pairs, the outer most electronic configuration will be the same?
Answer
(A)
Cr+ and Mn2+
14
Which of the following reaction/s will not give p-aminoazobenzene?
Answer
(D)
B only
15
Using the provided information in the following paper chromatogram :
Fig : Paper chromatography for compounds A and B.
the calculated Rf value of A ________$$\times$$ 10-1.
Answer
4
16
The reaction of cyanamide, NH2CN(s) with oxygen was run in a bomb calorimeter and $$\Delta$$U was found to be $$-$$742.24 kJ mol$$-$$1. The magnitude of $$\Delta$$H298 for the reaction
is _________ kJ. (Rounded off to the nearest integer) [Assume ideal gases and R = 8.314 J mol$$-$$1 K$$-$$1]
Answer
741
17
The ionization enthalpy of Na+ formation from Na(g) is 495.8 kJ mol$$-$$1, while the electron gain enthalpy of Br is $$-$$325.0 kJ mol$$-$$1. Given the lattice enthalpy of NaBr is $$-$$728.4 kJ mol$$-$$1. The energy for the formation of NaBr ionic solid is ($$-$$) ____________ $$\times$$ 10$$-$$1 kJ mol$$-$$1.
Answer
5576
18
0.4 g mixture of NaOH, Na2CO3 and some inert impurities was first titrated with $${N \over {10}}$$ HCl using phenolphthalein as an indicator, 17.5 mL of HCl was required at the end point. After this methyl orange was added and titrated. 1.5 mL of same HCl was required for the next end point. The weight percentage of Na2CO3 in the mixture is ________. (Rounded off to the nearest integer)
Answer
4
19
In basic medium $$Cr{O_4}^{2 - }$$ oxidises $${S_2}{O_3}^{2 - }$$ to form $$S{O_4}^{2 - }$$ and itself changes into $$Cr{(OH)_4}^ - $$. The volume of 0.154 M $$Cr{O_4}^{2 - }$$ required to react with 40 mL of 0.25 M $${S_2}{O_3}^{2 - }$$ is __________ mL. (Rounded off to the nearest integer)
Answer
173
20
Consider the following chemical reaction.
The number of sp2 hybridized carbon atom(s) present in the product is ________.
Answer
7
21
1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the solution at 1 atm is _________ K. (Rounded off to the nearest integer)
[Given Kb for (H2O) = 0.52 K kg mol$$-$$1]
Answer
375
22
Among the following, the number of halide(s) which is/are inert to hydrolysis is _________.
(A) BF3
(B) SiCl4
(C) PCl5
(D) SF6
Answer
1
23
For the reaction, aA + bB $$ \to $$ cC + dD, the plot of log k vs $${1 \over T}$$ is given below :
The temperature at which the rate constant of the reaction is 10-4 s-1 is _________ K. (Rounded off to the nearest integer)
[Given : The rate constant of the reaction is 10-5 s-1 at 500 K.]