JEE MAIN - Chemistry (2021 - 25th February Morning Shift - No. 11)
The hybridization and magnetic nature of $${[Mn{(CN)_6}]^{4 - }}$$ and $${[Fe{(CN)_6}]^{3 - }}$$, respectively are :
sp3d2 and diamagnetic
d2sp3 and paramagnetic
sp3d2 and paramagnetic
d2sp3 and diamagnetic
Explanation
$${[Mn{(CN)_6}]^{4 - }}$$
Mn2+ = 3d5 4s0
CNā is a strong field ligand.
$$ \therefore $$ Pairing will occur.
_25th_February_Morning_Shift_en_11_1.png)
$${[Fe{(CN)_6}]^{3 - }}$$
Fe3+ = 3d54s0
CNā is a strong field ligand.
$$ \therefore $$ Pairing will occur.
_25th_February_Morning_Shift_en_11_2.png)
Mn2+ = 3d5 4s0
CNā is a strong field ligand.
$$ \therefore $$ Pairing will occur.
$${[Fe{(CN)_6}]^{3 - }}$$
Fe3+ = 3d54s0
CNā is a strong field ligand.
$$ \therefore $$ Pairing will occur.
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