JEE MAIN - Chemistry (2021 - 24th February Evening Shift)

1
The correct order of the following compounds showing increasing tendency towards nucleophilic substitution reaction is :

JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Hydrocarbons Question 88 English
Answer
(D)
(i) < (ii) < (iii) < (iv)
2
The incorrect statement among the following is :
Answer
(D)
Red colour of ruby is due to the presence of Co3+
3
Which one of the following compounds is non-aromatic?
Answer
(D)
JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Basics of Organic Chemistry Question 161 English Option 4
4
According to Bohr's atomic theory :

(A) Kinetic energy of electron is $$ \propto {{{Z^2}} \over {{n^2}}}$$.

(B) The product of velocity (v) of electron and principal quantum number (n), $$'vn' \propto {Z^2}$$.

(C) Frequency of revolution of electron in an orbit is $$ \propto {{{Z^3}} \over {{n^3}}}$$.

(D) Coulombic force of attraction on the electron is $$ \propto {{{Z^3}} \over {{n^4}}}$$.

Choose the most appropriate answer from the options given below :
Answer
(D)
(A) and (D) only
5
Which one of the following carbonyl compounds cannot be prepared by addition of water on an alkyne in the presence of HgSO4 and H2SO4?
Answer
(C)
JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 146 English Option 3
6
The correct set from the following in which both pairs are in correct order of melting point is :
Answer
(D)
LiF > LiCl ; MgO > NaCl
7
What is the correct sequence of reagents used for converting nitrobenzene into m-dibromobenzene?

JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Compounds Containing Nitrogen Question 150 English
Answer
(C)
$$\stackrel{\mathrm{B} \mathrm{B}_{2} / \mathrm{Fe}}{\longrightarrow} / \stackrel{\mathrm{Sn} / \mathrm{HCl}}{\longrightarrow} / \stackrel{\mathrm{NaNO}_{2} / \mathrm{HCl}}{\longrightarrow} / \stackrel{\mathrm{CuBr} / \mathrm{HBr}}{\longrightarrow}$$
8
The calculated magnetic moments (spin only value) for species $${[FeC{l_4}]^{2 - }}$$, $${[Co{({C_2}{O_4})_3}]^{3 - }}$$ and $$MnO_4^{2 - }$$ respectively are :
Answer
(B)
4.90, 0 and 1.73 BM
9
JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 145 English
Which of the following reagent is suitable for the preparation of the product in the above reaction?
Answer
(B)
$$N{H_2} - N{H_2}/{C_2}{H_5}\mathop O\limits^\Theta \mathop N\limits^ \oplus a$$
10
What is the correct order of the following elements with respect to their density?
Answer
(C)
Zn < Cr < Fe < Co < Cu
11
Match List - I and List - II.

List I List II
(a) Valium (i) Antifertility drug
(b) Morphine (ii) Pernicious anaemia
(c) Norethindrone (iii) Analgesic
(d) Vitamin $${B_{12}}$$ (iv) Tranquilizer
Answer
(D)
(a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)
12
The correct shape and $$I - I - I$$ bond angles respectively in $$I_3^ - $$ ion are :
Answer
(A)
Linear; 180$$^\circ$$
13
The diazonium salt of which of the following compounds will form a coloured dye on reaction with $$\beta$$-Naphthol in NaOH?
Answer
(C)
JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Compounds Containing Nitrogen Question 151 English Option 3
14
Match List - I and List - II.

List-I List-II
(a) JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 147 English 1 (i) $$\mathrm{Br}_{2} / \mathrm{NaOH}$$
(b) JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 147 English 2 (ii) $$\mathrm{H}_{2} / \mathrm{Pd}-\mathrm{BaSO}_{4}$$
(c) JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 147 English 3 (iii) $$\mathrm{Zn}(\mathrm{Hg}) / \mathrm{H}$$ Conc. $$\mathrm{HCl}$$
(d) JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 147 English 4 (iv) $$\mathrm{Cl}_{2}$$ Red $$\mathrm{P}, \mathrm{H}_{2} \mathrm{O}$$


Choose the correct answer from the options given below :
Answer
(A)
(a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)
15
The formula of a gaseous hydrocarbon which requires 6 times of its own volume of O2 for complete oxidation and produces 4 times its own volume of CO2 is CxHy. The value of y is _____________.
Answer
8
16
The solubility product of PbI2 is 8.0 $$\times$$ 10$$-$$9. The solubility of lead iodide in 0.1 molar solution of lead nitrate is x $$\times$$ 10$$-$$6. mol/L. The value of x is __________. (Rounded off to the nearest integer) [Given $$\sqrt 2 $$ = 1.41]
Answer
141
17
1.86 g of aniline completely reacts to form acetanilide. 10% of the product is lost during purification. Amount of acetanilide obtained after purification (in g) is __________ $$\times$$ 10$$-$$2.
Answer
243
18
Assuming ideal behaviour, the magnitude of log K for the following reaction at 25$$^\circ$$C is x $$\times$$ 10$$-$$1. The value of x is ______________. (Integer answer)

$$3HC \equiv C{H_{(g)}} \rightleftharpoons {C_6}{H_{6(l)}}$$

[Given : $${\Delta _f}{G^o}(HC \equiv CH) = - 2.04 \times {10^5}$$ J mol$$-$$1 ; $${\Delta _f}{G^o}({C_6}{H_6}) = - 1.24 \times {10^5}$$ J mol$$-$$1 ; R = 8.314 J K-1 mol$$-$$1]
Answer
855
19
C6H6 freezes at 5.5$$^\circ$$C. The temperature at which a solution of 10g of C4H10 in 200g of C6H6 freeze is __________ $$^\circ$$C. (The molal freezing point depression constant of C6H6 is 5.12$$^\circ$$C/m.)
Answer
1
20
Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with a half-life of 3.33 h at 25$$^\circ$$C. After 9 h, the fraction of sucrose remaining is f. The value of $${\log _{10}}\left( {{1 \over f}} \right)$$ is ________ $$\times$$ 10$$-$$2. (Rounded off to the nearest integer)

[Assume : ln 10 = 2.303, ln 2 = 0.693]
Answer
81
21
The magnitude of the change in oxidising power of the $$MnO_4^ - /M{n^{2 + }}$$ couple is x $$\times$$ 10$$-$$4 V, if the H+ concentration is decreased from 1M to 10$$-$$4 M at 25$$^\circ$$C. (Assume concentration of $$MnO_4^ - $$ and $$M{n^{2 + }}$$ to be same on change in H+ concentration). The value of x is ___________. $$\left[ {Given\,:{{2.303RT} \over F} = 0.059} \right]$$
Answer
3776
22
The total number of amines among the following which can be synthesized by Gabriel synthesis is __________.

JEE Main 2021 (Online) 24th February Evening Shift Chemistry - Compounds Containing Nitrogen Question 149 English
Answer
3