The calculated magnetic moments (spin only value) for species $${[FeC{l_4}]^{2 - }}$$, $${[Co{({C_2}{O_4})_3}]^{3 - }}$$ and $$MnO_4^{2 - }$$ respectively are :
Answer
(B)
4.90, 0 and 1.73 BM
9
Which of the following reagent is suitable for the preparation of the product in the above reaction?
$$\mathrm{Cl}_{2}$$ Red $$\mathrm{P}, \mathrm{H}_{2} \mathrm{O}$$
Choose the correct answer from the options given below :
Answer
(A)
(a)-(ii), (b)-(iv), (c)-(i), (d)-(iii)
15
The formula of a gaseous hydrocarbon which requires 6 times of its own volume of O2 for complete oxidation and produces 4 times its own volume of CO2 is CxHy. The value of y is _____________.
Answer
8
16
The solubility product of PbI2 is 8.0 $$\times$$ 10$$-$$9. The solubility of lead iodide in 0.1 molar solution of lead nitrate is x $$\times$$ 10$$-$$6. mol/L. The value of x is __________. (Rounded off to the nearest integer) [Given $$\sqrt 2 $$ = 1.41]
Answer
141
17
1.86 g of aniline completely reacts to form acetanilide. 10% of the product is lost during purification. Amount of acetanilide obtained after purification (in g) is __________ $$\times$$ 10$$-$$2.
Answer
243
18
Assuming ideal behaviour, the magnitude of log K for the following reaction at 25$$^\circ$$C is x $$\times$$ 10$$-$$1. The value of x is ______________. (Integer answer)
C6H6 freezes at 5.5$$^\circ$$C. The temperature at which a solution of 10g of C4H10 in 200g of C6H6 freeze is __________ $$^\circ$$C. (The molal freezing point depression constant of C6H6 is 5.12$$^\circ$$C/m.)
Answer
1
20
Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with a half-life of 3.33 h at 25$$^\circ$$C. After 9 h, the fraction of sucrose remaining is f. The value of $${\log _{10}}\left( {{1 \over f}} \right)$$ is ________ $$\times$$ 10$$-$$2. (Rounded off to the nearest integer)
[Assume : ln 10 = 2.303, ln 2 = 0.693]
Answer
81
21
The magnitude of the change in oxidising power of the $$MnO_4^ - /M{n^{2 + }}$$ couple is x $$\times$$ 10$$-$$4 V, if the H+ concentration is decreased from 1M to 10$$-$$4 M at 25$$^\circ$$C. (Assume concentration of $$MnO_4^ - $$ and $$M{n^{2 + }}$$ to be same on change in H+ concentration). The value of x is ___________. $$\left[ {Given\,:{{2.303RT} \over F} = 0.059} \right]$$
Answer
3776
22
The total number of amines among the following which can be synthesized by Gabriel synthesis is __________.