JEE MAIN - Chemistry (2021 - 17th March Evening Shift)

1
$${C_{12}}{H_{22}}{O_{11}} + {H_2}O\buildrel {Enzyme\,A} \over \longrightarrow \mathop {{C_6}{H_{12}}{O_6}}\limits_{Glu\cos e} + \mathop {{C_6}{H_{12}}{O_6}}\limits_{Fructose} $$

$$\mathop {{C_6}{H_{12}}{O_6}}\limits_{Glu\cos e} \buildrel {Enzyme\,B} \over \longrightarrow 2{C_2}{H_5}OH + 2C{O_2}$$

In the above reactions, the enzyme A and enzyme B respectively are :
Answer
(D)
Invertase and Zymase
2
Choose the correct statement regarding the formation of carbocations A and B given.

Answer
(C)
Carbocation B is more stable and formed relatively at faster rate
3
Nitrogen can be estimated by Kjeldahl's method for which of the following compound?
Answer
(D)
JEE Main 2021 (Online) 17th March Evening Shift Chemistry - Basics of Organic Chemistry Question 153 English Option 4
4
Amongst the following, the linear species is :
Answer
(C)
N$$_3^ - $$
5
The correct pair(s) of the ambident nucleophiles is(are)

(A) AgCN/KCN

(B) RCOOAg/RCOOK

(C) AgNO2/KNO2

(D) AgI/KI
Answer
(C)
(A) and (C) only
6
Given below are two statements :

Statement I : 2-methylbutane on oxidation with KMnO4 gives 2-methylbutan-2-ol.

Statement II : n-alkanes can be easily oxidised to corresponding alcohols with KMnO4.

Choose the correct option :
Answer
(C)
Statement I is correct but statement II is incorrect
7
During which of the following processes, does entropy decrease?

(A) Freezing of water to ice at 0$$^\circ$$C

(B) Freezing of water to ice at $$-$$10$$^\circ$$C

(C) N2(g) + 3H2(g) $$ \to $$ 2NH3(g)

(D) Adsorption of CO(g) on lead surface.

(E) Dissolution of NaCl in water

Choose the correct answer from the options given below :
Answer
(C)
(A), (B), (C) and (D) only
8
JEE Main 2021 (Online) 17th March Evening Shift Chemistry - Compounds Containing Nitrogen Question 138 English
In the above reaction, the structural formula of (A), ''X'' and ''Y'' respectively are :
Answer
(B)
JEE Main 2021 (Online) 17th March Evening Shift Chemistry - Compounds Containing Nitrogen Question 138 English Option 2
9
Primary, secondary and tertiary amines can be separated using:
Answer
(D)
para-Toluene sulphonyl chloride
10
Match List - I with List - II :

List - I
List - II
(a) $$[Co{(N{H_3})_6}][Cr{(CN)_6}]$$ (i) Linkage isomerism
(b) $$[Co{(N{H_3})_3}{(N{O_2})_3}]$$ (ii) Solvate isomerism
(c) $$[Cr{({H_2}O)_6}C{l_3}$$ (iii) Co-ordination isomerism
(d) $$cis - {[CrC{l_2}{(ox)_2}]^{3 - }}$$ (iv) Optical isomerism


Choose the correct answer from the options given below :
Answer
(B)
(a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)
11
Fructose is an example of :
Answer
(C)
Ketohexose
12
The common positive oxidation states for an element with atomic number 24, are :
Answer
(B)
+2 to +6
13
A KCl solution of conductivity 0.14 S m$$-$$1 shows a resistance of 4.19$$\Omega$$ in a conductivity cell. If the same cell is filled with an HCl solution, the resistance drops to 1.03$$\Omega$$. The conductivity of the HCl solution is ____________ $$\times$$ 10$$-$$2 S m$$-$$1. (Round off to the Nearest Integer).
Answer
57
14
On complete reaction of FeCl3 with oxalic acid in aqueous solution containing KOH, resulted in the formation of product A. The secondary valency of Fe in the product A is __________. (Round off to the Nearest Integer).
Answer
6
15
JEE Main 2021 (Online) 17th March Evening Shift Chemistry - Some Basic Concepts of Chemistry Question 132 English
Consider the above reaction. The percentage yield of amide product is __________. (Round off to the Nearest Integer).

(Given : Atomic mass : C : 12.0 u, H : 1.0 u, N : 14.0 u, O : 16.0 u, Cl : 35.5 u)
Answer
77
16
The reaction 2A + B2 $$ \to $$ 2AB is an elementary reaction.

For a certain quantity of reactants, if the volume of the reaction vessel is reduced by a factor of 3, the rate of the reaction increases by a factor of ____________. (Round off to the Nearest Integer).
Answer
27
17
Consider the reaction

$$N_{2}O_{4}\left( g\right) \rightleftharpoons 2NO_{2}\left( g\right) $$

The temperature at which KC = 20.4 and KP = 600.1, is ____________ K. (Round off to the Nearest Integer). [Assume all gases are ideal and R = 0.0831 L bar K$$-$$1 mol$$-$$1]
Answer
354
18
In the ground state of atomic Fe(Z = 26), the spin-only magnetic moment is ____________ $$\times$$ 10$$-$$1 BM. (Round off to the Nearest Integer). [Given : $$\sqrt 3 $$ = 1.73, $$\sqrt 2 $$ = 1.41 ]
Answer
49
19
A 1 molal K4Fe(CN)6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of another solution which contains 18.1 weight percent of a non electrolytic solute A. The molar mass of A is __________ u. (Round off to the Nearest Integer). [Density of water = 1.0 g cm$$-$$3 ]
Answer
85
20
The total number of C-C sigma bond/s in mesityl oxide (C6H10O) is __________. (Round off to the Nearest Integer).
Answer
5