A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is correct regarding the behaviour of the solution ?

The number of stereoisomers possible for a compound of the molecular formula CH₃ - CH = CH - CH(OH) - Me is :

The alkene that exhibits geometrical isomerism is :

The IUPAC name of neopentane is

Arrange the carbanions, $${(C{H_3})_3}\overline C $$, $$\overline C C{l_3}$$ , $${(C{H_3})_2}\overline C H$$, $${C_6}{H_5}\overline C H{}_2$$ in order of their decreasing stability :

Solid Ba(NO₃)₂ is gradually dissolved in a 1.0 $$\times$$ 10^-4 M Na₂CO₃ solution. At what concentration of Ba²⁺ will a precipitate begin to form ?
(K_sp for BaCO₃ = 5.1 $$\times$$ 10⁻⁹ )

On the basis of the following thermochemical data :
($$\Delta _fG^oH^+_{(aq)}$$ = 0)

H₂O(l) $$\to$$ H⁺(aq) + OH^-(aq); $$\Delta H$$ = 57.32 kJ
H₂(g) + $${1 \over 2} O_2(g) \to$$ H₂O(l); $$\Delta H$$ = -286.20 kJ

The value of enthalpy of formation of OH⁻ ion at 25^oC is :

Two liquids X and Y form an ideal solution. At 300K, vapour pressure of the solution containing 1 mol of X and 3 mol of Y is 550 mm Hg. At the same temperature, if 1 mol of Y is further added to this solution, vapour pressure of the solution increases by 10 mm Hg. Vapour pressure (in mm Hg) of X and Y in their pure states will be, respectively :

In Cannizzaro reaction given below
2PhCHO $$\buildrel {\mathop {:OH}\limits^{\left( - \right)} } \over \longrightarrow $$ PhCH₂OH + $$PhC\mathop O\limits^{..} $$₂^(-)
the slowest step is :

The set representing the correct order of ionic radius is :

The two functional groups present in a typical carbohydrate are

Which of the following on heating with aqueous KOH, produces acetaldehyde ?

A liquid was mixed with ethanol and a drop of concentrated H₂SO₄ was added. A compound with a fruity smell was formed. The liquid was :

The major product obtained on interaction of phenol with sodium hydroxide and carbon dioxide is :

Which of the following pairs represents linkage isomers ?

Which of the following has an optical isomer ?

In context with the transition elements, which of the following statements is incorrect ?

The half life period of a first order chemical reaction is 6.93 minutes. The time required for the completion of 99% of the chemical reaction will be (log 2=0.301) :

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
CH₃OH(l) + 3/2O₂ $$\to$$ CO₂ (g) + 2H₂O (l)
At 298K standard Gibb’s energies of formation for CH₃OH(l), H₂O(l) and CO₂ (g) are -166.2, -237.2 and -394.4 kJ mol⁻¹ respectively. If standard enthalpy of combustion of methanol is -726 kJ mol⁻¹, efficiency of the fuel cell will be

Given : $$E_{F{e^{3 + }}/Fe}^o$$ = -0.036V; $$E_{F{e^{2 + }}/Fe}^o$$ = -0.439 V
The value of standard electrode potential for the change,
Fe³⁺ (aq) + e^- $$\to$$ Fe²⁺ (aq) will be

Given : $$E_{F{e^{3 + }}/Fe}^o$$ = -0.036V; $$E_{F{e^{2 + }}/Fe}^o$$ = -0.439 V
The value of standard electrode potential for the change,
Fe³⁺ (aq) + e^- $$\to$$ Fe²⁺ (aq) will be

Using MO theory, predict which of the following species has the shortest bond length?

In which of the following arrangements, the sequence is not strictly according to the property written against it

In an atom, an electron is moving with a speed of 600 m/s with an accuracy of 0.005%. Certainity with which the position of the electron can be located is (h = 6.6 $$\times$$ 10^-34 kg m²s^-1, mass of electron, e_m = 9.1 $$\times$$ 10^-31 kg)

Calculate the wavelength (in nanometer) associated with a proton moving at 1.0 x 10³ ms⁻¹ (Mass of proton = 1.67 $$\times$$ 10^-27 kg and h = 6.63 $$\times$$ 10^-34 Js) :