JEE MAIN - Chemistry (2025 - 3rd April Evening Shift)

1

Given below are two statements:

Statement I : Wet cotton clothes made of cellulose based carbohydrate takes comparatively longer time to get dried than wet nylon polymer based clothes.

Statement II : Intermolecular hydrogen bonding with water molecule is more in nylon-based clothes than in the case of cotton clothes.

In the light of above statements, choose the correct answer from the options given below

Answer
(D)
Statement I is true but Statement II is false
2

Fat soluble vitamins are:

A. Vitamin $\mathrm{B}_1$

B. Vitamin C

C. Vitamin E

D. Vitamin B 12

E. Vitamin K

Choose the correct answer from the options given below:

Answer
(C)
C & E Only
3
$$ \text { What is the correct IUPAC name of } $$

JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Basics of Organic Chemistry Question 3 English ?
Answer
(A)
3-Bromo-2-hydroxy-5-nitrobenzoic acid
4

Mass of magnesium required to produce 220 mL of hydrogen gas at STP on reaction with excess of dil. HCl is

Given: Molar mass of Mg is $24 \mathrm{~g} \mathrm{~mol}^{-1}$.

Answer
(D)
236 mg
5

Given below are two statements:

Statement I : When a system containing ice in equilibrium with water (liquid) is heated, heat is absorbed by the system and there is no change in the temperature of the system until whole ice gets melted.

Statement II : At melting point of ice, there is absorption of heat in order to overcome intermolecular forces of attraction within the molecules of water in ice and kinetic energy of molecules is not increased at melting point.

In the light of the above statements, choose the correct answer from the options given below

Answer
(C)
Both Statement I and Statement II are true
6

The correct orders among the following are

Atomic radius : $\mathrm{B}<\mathrm{Al}<\mathrm{Ga}<\mathrm{In}<\mathrm{Tl}$

Electronegativity : $\mathrm{Al}<\mathrm{Ga}<\mathrm{In}<\mathrm{Tl}<\mathrm{B}$

Density : $\mathrm{Tl}<\mathrm{In}<\mathrm{Ga}<\mathrm{Al}<\mathrm{B}$

1st Ionisation Energy : $\mathrm{In}<\mathrm{Al}<\mathrm{Ga}<\mathrm{Tl}<\mathrm{B}$

Choose the correct answer from the options given below:

Answer
(A)
B and D Only
7
10 mL of 2 M NaOH solution is added to 20 mL of 1 M HCl solution kept in a beaker. Now, 10 mL of this mixture is poured into a volumetric flask of 100 mL containing 2 moles of HCl and made the volume upto the mark with distilled water. The solution in this flask is :
Answer
(B)
20 M HCl solution
8

$$ \text {In the following series of reactions identify the major products } \mathrm{A} \& \mathrm{~B} \text { respectively } $$

JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 1 English
Answer
(B)
JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Haloalkanes and Haloarenes Question 1 English Option 2
9

Identify the diamagnetic octahedral complex ions from below ;

A. $\left[\mathrm{Mn}(\mathrm{CN})_6\right]^{3-}$

B. $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$

C. $\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-}$

D. $\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_3 \mathrm{~F}_3\right]$

Choose the correct answer from the options given below:

Answer
(A)
B and C Only
10

Given below are two statements:

Statement I : $\mathrm{CrO}_3$ is a stronger oxidizing agent than $\mathrm{MoO}_3$

Statement II : $\mathrm{Cr}(\mathrm{VI})$ is more stable than $\mathrm{Mo}(\mathrm{VI})$

In the light of the above statements, choose the correct answer from the options given below

Answer
(A)
Statement I is true but Statement II is false
11

Consider the following statements related to temperature dependence of rate constants.

Identify the correct statements.

A. The Arrhenius equation holds true only for an elementary homogenous reaction.

B. The unit of $A$ is same as that of $k$ in Arrhenius equation.

C. At a given temperature, a low activation energy means a fast reaction.

D. A and Ea as used in Arrhenius equation depend on temperature.

E. When $\mathrm{Ea} \gg \mathrm{RT}, \mathrm{A}$ and Ea become interdependent.

Choose the correct answer from the options given below:

Answer
(C)
B and C Only
12

Given below are two statements :

Statement I : Hyperconjugation is not a permanent effect.

Statement II : In general, greater the number of alkyl groups attached to a positively charged Catom, greater is the hyperconjugation interaction and stabilization of the cation.

In the light of the above statements, choose the correct answer from the options given below

Answer
(A)
Statement I is false but Statement II is true
13
The sequence from the following that would result in giving predominantly $3,4,5-$ Tribromoaniline is :
Answer
(C)
JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Compounds Containing Nitrogen Question 1 English Option 3
14

$$ \text { Match the LIST-I with LIST-II } $$

LIST-I
(Family)
LIST-II
(Symbol of Element)
A. Pnictogen (group 15) I Ts
B Chalcogen II Og
C Halogen III Lv
D Noble gas IV Mc
Choose the correct answer from the options given below:
Answer
(B)
A-IV, B-III, C-I, D-II
15

$$ \text {The major product }(\mathrm{P}) \text { in the following reaction is : } $$

JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 1 English
Answer
(C)
JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 1 English Option 3
16

The standard cell potential $\left(\mathrm{E}_{\text {cell }}^{\ominus}\right)$ of a fuel cell based on the oxidation of methanol in air that has been used to power television relay station is measured as 1.21 V . The standard half cell reduction potential for $\mathrm{O}_2\left(\mathrm{E}_{\mathrm{O}_2 / \mathrm{H}_2 \mathrm{O}}^{\circ}\right)$ is 1.229 V .

Choose the correct statement :

Answer
(C)
The standard half cell reduction potential for the reduction of $\mathrm{CO}_2\left(\mathrm{E}_{\mathrm{CO}_2 / \mathrm{CH}_3 \mathrm{OH}}^{\circ}\right)$ is 19 mV
17
For electrons in ' 2 s ' and ' 2 p ' orbitals, the orbital angular momentum values, respectively are :
Answer
(B)
0 and $\sqrt{2} \frac{h}{2 \pi}$
18

Compounds that should not be used as primary standards in titrimetric analysis are :

A. $\mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7$

B. Oxalic acid

C. NaOH

D. $\mathrm{FeSO}_4 \cdot 6 \mathrm{H}_2 \mathrm{O}$

E. Sodium tetraborate

Choose the most appropriate answer from the options given below:

Answer
(D)
A, C and D Only
19

40 mL of a mixture of $\mathrm{CH}_3 \mathrm{COOH}$ and HCl (aqueous solution) is titrated against 0.1 M NaOH solution conductometrically. Which of the following statement is correct?

JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Ionic Equilibrium Question 1 English
Answer
(B)
The concentration of HCl in the original mixture is 0.005 M
20
In Dumas' method for estimation of nitrogen 0.4 g of an organic compound gave 60 mL of nitrogen collected at 300 K temperature and 715 mm Hg pressure. The percentage composition of nitrogen in the compound is (Given : Aqueous tension at $300 \mathrm{~K}=15 \mathrm{~mm} \mathrm{Hg}$ )
Answer
(A)
$15.71 \%$
21

X g of nitrobenzene on nitration gave 4.2 g of m -dinitrobenzene. X = __________g. (nearest integer)

[Given : molar mass (in $\left.\left.\mathrm{g} \mathrm{mol}^{-1}\right) \mathrm{C}: 12, \mathrm{H}: 1, \mathrm{O}: 16, \mathrm{~N}: 14\right]$

Answer
3
22
The total number of structural isomers possible for the substituted benzene derivatives with the molecular formula $\mathrm{C}_9 \mathrm{H}_{12}$ is________.
Answer
8
23
Among, $\mathrm{Sc}, \mathrm{Mn}, \mathrm{Co}$ and Cu , identify the element with highest enthalpy of atomisation. The spin only magnetic moment value of that element in its +2 oxidation state is__________BM (in nearest integer).
Answer
4
24

A perfect gas ( 0.1 mol ) having $\overline{\mathrm{C}}_v=1.50 \mathrm{R}$ (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is $(-)$___________$J$ (nearest integer)

[Given: $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ ]

JEE Main 2025 (Online) 3rd April Evening Shift Chemistry - Thermodynamics Question 3 English
Answer
304
25
A sample of n -octane $(1.14 \mathrm{~g})$ was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is $5 \mathrm{~kJ} \mathrm{~K}^{-1}$. As a result of combustion reaction, the temperature of the calorimeter is increased by 5 K . The magnitude of the heat of combustion of octane at constant volume is__________ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer).
Answer
2500